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Journal Article

Laser-Based In-Exhaust Gas Sensor for On-Road Vehicles

2022-03-29
2022-01-0535
A novel laser-absorption gas sensing apparaOn-vehicle Testing at VERtus capable of measuring NO directly within vehicle exhaust was developed and tested. The sensor design was enabled by key advances in the construction of optical probes that are sufficiently compact for deployment in real-world exhaust systems and can survive the harsh, high-temperature, and strongly vibrating environment typical of exhaust streams. Prototype test campaigns were conducted at high-temperature flow facilities intended to simulate exhaust gas conditions and within the exhaust of vehicles mounted on a chassis dynamometer. Results from these tests demonstrated that the sensor prototype is fundamentally free of cross-interference with competing species in the exhaust stream, can achieve a 1 ppmv NO detection limit, and can be operated across the full range of thermodynamic conditions expected for typical vehicle exhausts.
Journal Article

Graphene Coating as a Corrosion Protection Barrier for Metallic Terminals in Automotive Environments

2021-04-06
2021-01-0354
Inside an automobile, hundreds of connectors and electrical terminals in various locations experience different corrosive environments. These connectors and electrical terminals need to be corrosion-proof and provide a good electrical contact for a vehicle’s lifetime. Saltwater and sulfuric acid are some of the main corrosion concerns for these electrical terminals. Currently, various thin metallic layers such as gold (Au), silver (Ag), or tin (Sn) are plated with a nickel (Ni) layer on copper alloy (Cu) terminals to ensure reliable electrical conduction during service. Graphene due to its excellent chemical stability can serve as a corrosion protective layer and prevent electrochemical oxidation of metallic terminals. In this work, effects of thin graphene layers grown by plasma-enhanced chemical vapor deposition (PECVD) on Au and Ag terminals and thin-film devices were investigated. Various mechanical, thermal/humidity, and electrical tests were performed.
Technical Paper

How Well Can mPEMS Measure Gas Phase Motor Vehicle Exhaust Emissions?

2020-04-14
2020-01-0369
“Real world emissions” is an emerging area of focus in motor vehicle related air quality. These emissions are commonly recorded using portable emissions measurement systems (PEMS) designed for regulatory application, which are large, complex and costly. Miniature PEMS (mPEMS) is a developing technology that can significantly simplify on-board emissions measurement and potentially promote widespread use. Whereas full PEMS use analyzers to record NOx, CO, and HCs similar to those in emissions laboratories, mPEMS tend to use electrochemical sensors and compact optical detectors for their small size and low cost. The present work provides a comprehensive evaluation of this approach. It compares measurements of NOx, CO, CO2 and HC emissions from five commercial mPEMS to both laboratory and full regulatory PEMS analyzers. It further examines the use of vehicle on-board diagnostics data to calculate exhaust flow, as an alternative to on-vehicle exhaust flow measurement.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Technical Paper

R744 Parallel Compression Cycle for Automotive Climate Control

2017-03-28
2017-01-0175
The natural refrigerant, R744 (CO2), remains a viable solution to replace the high GWP refrigerant R134a which is to be phased out in light-duty vehicles in EU and US market. In this study, thermodynamic analysis is performed on a R744 parallel compression system to evaluate its potential in automotive climate control. The model adopts a correlation of isentropic efficiency as a function of compression ratio based on a prototype R744 MAC compressor and accounts for the operating limits defined in the latest DIN specifications. Optimization is run over typical MAC operating conditions which covers both transcritical and subcritical domain. Comparing to the conventional single compression cycle, effectiveness of parallel compression is found most pronounced in low evaporating temperature and high ambient conditions, with up to 21% increase in COP and 5.3 bar reduction in discharge pressure observed over the considered parametric range.
Technical Paper

Modeling Ignition and Premixed Combustion Including Flame Stretch Effects

2017-03-28
2017-01-0553
Objective of this work is the incorporation of the flame stretch effects in an Eulerian-Lagrangian model for premixed SI combustion in order to describe ignition and flame propagation under highly inhomogeneous flow conditions. To this end, effects of energy transfer from electrical circuit and turbulent flame propagation were fully decoupled. The first ones are taken into account by Lagrangian particles whose main purpose is to generate an initial burned field in the computational domain. Turbulent flame development is instead considered only in the Eulerian gas phase for a better description of the local flow effects. To improve the model predictive capabilities, flame stretch effects were introduced in the turbulent combustion model by using formulations coming from the asymptotic theory and recently verified by means of DNS studies. Experiments carried out at Michigan Tech University in a pressurized, constant-volume vessel were used to validate the proposed approach.
Technical Paper

Virtual Exhaust Gas Temperature Measurement

2017-03-28
2017-01-1065
Exhaust temperature models are widely used in the automotive industry to estimate catalyst and exhaust gas temperatures and to protect the catalyst and other vehicle hardware against over-temperature conditions. Modeled exhaust temperatures rely on air, fuel, and spark measurements to make their estimate. Errors in any of these measurements can have a large impact on the accuracy of the model. Furthermore, air-fuel imbalances, air leaks, engine coolant temperature (ECT) or air charge temperature (ACT) inaccuracies, or any unforeseen source of heat entering the exhaust may have a large impact on the accuracy of the modeled estimate. Modern universal exhaust gas oxygen (UEGO) sensors have heaters with controllers to precisely regulate the oxygen sensing element temperature. These controllers are duty cycle based and supply more or less current to the heating element depending on the temperature of the surrounding exhaust gas.
Technical Paper

A Modeling Analysis of Fibrous Media for Gasoline Particulate Filters

2017-03-28
2017-01-0967
With an emerging need for gasoline particulate filters (GPFs) to lower particle emissions from gasoline direct injection (GDI) engines, studies are being conducted to optimize GPF designs in order to balance filtration efficiency, backpressure penalty, filter size, cost and other factors. Metal fiber filters could offer additional designs to the GPF portfolio, which is currently dominated by ceramic wall-flow filters. However, knowledge on their performance as GPFs is still limited. In this study, modeling on backpressure and filtration efficiency of fibrous media was carried out to determine the basic design criteria (filtration area, filter thickness and size) for different target efficiencies and backpressures at given gas flow conditions. Filter media with different fiber sizes (8 - 17 μm) and porosities (80% - 95%) were evaluated using modeling to determine the influence of fiber size and porosity.
Technical Paper

Computational Aeroacoustics of Mufflers for Exhaust Air Rush Prediction and Experimental Validation

2017-03-28
2017-01-1311
Air rush noise is exhaust gas driven flow-induced noise in the frequency range of 500-6500 Hz. It is essential to understand the flow physics of exhaust gases within the mufflers in order to identify any counter measures that can attenuate this error state. This study is aimed at predicting the flow physics and air rush noise of exhaust mufflers in the aforementioned frequency range at a typical exhaust flow rate and temperature. The study is performed on two different muffler designs which show a significant air rush noise level difference when tested on the vehicle. The transient computational study was performed using DES with 2nd order spatial discretization and 2nd order implicit scheme for temporal discretization in StarCCM+. To compare with test data, a special flow test stand is designed so that all high and low frequency contents emanating from the engine are attenuated before the flow enters the test part.
Technical Paper

Numerical Study on Evaporation of Spherical Droplets Impinging on the Wall Using Volume of Fluid (VOF) Model

2017-03-28
2017-01-0852
This paper aims to extend the existing Volume of Fluid (VOF) model by implementing an evaporation sub-model in an open source Computational Fluid Dynamics (CFD) software, OpenFOAM. The paper applies the new model to numerically study the evaporation of spherical n-heptane droplets impinging on a hot wall at atmospheric pressure and a temperature above the Leidenfrost temperature. Volume of Fluid (VOF) method is chosen to track the liquid gas interface and the capability of VOF method implemented in interDyMFoam solver of OpenFOAM to simulate hydrodynamics during droplet-droplet interaction and droplet-film interaction is explored. Firstly, the in-built solver is used to simulate problems in isothermal conditions and the simulation results are compared qualitatively with the published results to validate the solver. A numerical method for modeling heat and mass transfer during evaporation is implemented in conjunction with the VOF.
Technical Paper

Investigation into Occurrence of Megaknock and Auto-Ignition in GTDI Engines

2017-03-28
2017-01-0690
The performance of boosted gasoline engines is limited at high loads by knock, stochastic Low Speed Pre-Ignition, and Megaknock. An investigation has been carried out on the occurrence of abnormal combustion and megaknock in a 1.6 L GTDI engine with the aim to determine the causes of such phenomena. A classification of abnormal combustion events and causes is presented in order to facilitate a consistent terminology. The experiments specifically focus on the effects of exhaust residual gas on occurrence of megaknock in multi-cylinder engines. The results showed that while a misfire will not lead to megaknock, a very late combustion in one cycle, in one cylinder may lead to megaknock in the following cycle in the same or adjacent cylinder. Additionally, a recently developed multi-zone model was used to analyze the role of residual gas on auto-ignition.
Journal Article

Ultra-Trace Real Time VOC Measurements by SIFT-MS for VIAQ

2017-03-28
2017-01-0989
Vehicle interior air quality (VIAQ) measurements are currently conducted using the offline techniques GC/MS and HPLC. To improve throughput, speed of analysis, and enable online measurement, specialized instruments are being developed. These instruments promise to reduce testing cost and provide shortened analysis times at comparable accuracy to the current state of the art offline instruments and methods. This work compares GCMS/HPLC to the Voice200ultra, a specialized real-time instrument utilizing the technique selected ion flow tube mass spectrometry (SIFT-MS). The Voice200ultra is a real-time mass spectrometer that measures volatile organic compounds (VOCs) in air down to the parts-per-trillion level by volume (pptv). It provides instantaneous, quantifiable results with high selectivity and sensitivity using soft chemical ionization.
Technical Paper

Methods to Improve the Surface Quality of Microcellular Injection Molded Parts - A Review

2016-10-25
2016-36-0224
The microcellular foam injection molding process is being widely applied by the thermoplastics industry. This process consists in a melted polymer injection mixed with a processing solvent, that is an inert gas in the supercritical state, usually CO2 or N2 producing a microcellular foam. This technique offers many advantages such as weight reduction, dimensional uniformization and less warpage. Besides that, it offers a satisfactory property like acoustic and thermal insulation. On the other hand, the parts from this process have an inferior mechanical property like ductility and toughness if compared with solid injection molded parts. Nevertheless, the main issue for this process is the poor appearance quality. This paper presents a review of some existing methods for surface quality improvement as Co-injection process, where a skin is injected over the microcellular part, and Heat & Cool that consists in a control of mold temperature.
Journal Article

Analysis of High Mileage Gasoline Exhaust Particle Filters

2016-04-05
2016-01-0941
The purpose of this work was to examine gasoline particle filters (GPFs) at high mileages. Soot levels for gasoline direct injection (GDI) engines are much lower than diesel engines; however, noncombustible material (ash) can cause increased backpressure, reduced power, and lower fuel economy. In this study, a post mortem was completed of two GPFs, one at 130,000 mi and the other at 150,000 mi, from two production 3.5L turbocharged GDI vehicles. The GPFs were ceramic wall-flow filters containing three-way catalytic washcoat and located downstream of conventional three-way catalysts. The oil consumption was measured to be approaching 23,000 mpqt for one vehicle and 30,000 mpqt for the other. The ash contained Ca, P, Zn, S, Fe, and catalytic washcoat. Approximately 50 wt% of the collected ash was non-lubricant derived. The filter capture efficiency of lubricant-derived ash was about 50% and the non-lubricant metal (mostly Fe) deposition rate was 0.9 to 1.2 g per 10,000 mi.
Journal Article

Exhaust Manifold Durability Subject to Splash Quenching

2015-04-14
2015-01-1735
Exhaust manifold design is one of the more challenging tasks for the engine engineer due to the harsh thermal and severe vibration environment. Extremely high exhaust gas temperatures and dynamic loading combine to subject the manifold to high cyclic stress when the material has reduced fatigue strength due to the high temperature. A long service life before a fatigue failure is the objective in exhaust manifold design. Accumulation of fatigue damage can occur from dynamic loading and thermal loading combined. Thermal mechanical fatigue (TMF) is a primary mechanism for accumulating fatigue damage. TMF typically occurs when a vehicle driving cycle has operating conditions that repeatedly change the exhaust gas temperature between hot and cold. Another way to experience temperature cycling is through splash quenching. Splash quenching was analyzed and found to rapidly accumulate fatigue damage.
Technical Paper

Automotive Interior Injection Molded Parts Using Microcellular Foaming Technology

2014-09-30
2014-36-0172
The microcellular foam injection molding process for thermoplastic materials provides design flexibility and cost savings opportunities not found in conventional injection molding. This process allows for plastic part design with material wall thickness optimized for functionality. The combination of density reduction and design for functionality can result in material and weight savings of up to 20%. With the correct equipment configuration, mold design, and processing conditions, these microcellular voids are uniform in size and distribution. The use of microcellular foam molding provides significant reductions in cycle time, material consumption, injection pressure, and clamp tonnage. In this work, a physical foam molding process, MuCell, is applied to a polypropylene (PP) composite.
Technical Paper

Schlieren and Mie Scattering Visualization for Single-Hole Diesel Injector under Vaporizing Conditions with Numerical Validation

2014-04-01
2014-01-1406
This paper reports an experimental and numerical investigation on the spatial and temporal liquid- and vapor-phase distributions of diesel fuel spray under engine-like conditions. The high pressure diesel spray was investigated in an optically-accessible constant volume combustion vessel for studying the influence of the k-factor (0 and 1.5) of a single-hole axial-disposed injector (0.100 mm diameter and 10 L/d ratio). Measurements were carried out by a high-speed imaging system capable of acquiring Mie-scattering and schlieren in a nearly simultaneous fashion mode using a high-speed camera and a pulsed-wave LED system. The time resolved pair of schlieren and Mie-scattering images identifies the instantaneous position of both the vapor and liquid phases of the fuel spray, respectively. The studies were performed at three injection pressures (70, 120, and 180 MPa), 23.9 kg/m3 ambient gas density, and 900 K gas temperature in the vessel.
Technical Paper

Influence of the Nozzle Geometry of a Diesel Single-Hole Injector on Liquid and Vapor Phase Distributions at Engine-Like Conditions

2013-09-08
2013-24-0038
The paper describes an experimental activity on the spatial and temporal liquid- and vapor-phase distributions of diesel fuel at engine-like conditions. The influence of the k-factor (0 and 1.5) of a single-hole axial-disposed injector (0.100 mm diameter and 10 L/d ratio) has been studied by spraying fuel in an optically-accessible constant-volume combustion vessel. A high-speed imaging system, capable of acquiring Mie-scattering and Schlieren images in a near simultaneous fashion mode along the same line of sight, has been developed at the Michigan Technological University using a high-speed camera and a pulsed-wave LED system. The time resolved pair of schlieren and Mie-scattering images identifies the instantaneous position of both the vapor and liquid phases of the fuel spray, respectively. The studies have been performed at three injection pressures (70, 120 and 180 MPa), 23.9 kg/m3 ambient gas density and 900 K gas temperature in the vessel.
Technical Paper

Investigation of Diesel Liquid Spray Penetration Fluctuations under Vaporizing Conditions

2012-04-16
2012-01-0455
Diesel combustion and emissions formation is largely spray and mixing controlled and hence understanding spray parameters, specifically vaporization, is key to determine the impact of fuel injector operation and nozzle design on combustion and emissions. In this study, an eight-hole common rail piezoelectric injector was tested in an optically accessible constant volume combustion vessel at charge gas conditions typical of full load boosted engine operation. Liquid penetration of the eight sprays was determined via processing of images acquired from Mie back scattering under vaporizing conditions by injecting into a charge gas at elevated temperature with 0% oxygen. Conditions investigated included a charge temperature sweep of 800 to 1300 K and injection pressure sweep of 1034 to 2000 bar at a constant charge density of 34.8 kg/m₃.
Technical Paper

Catalyst Performance Evaluation on E0 and E85 Fuels

2011-04-12
2011-01-0904
The differences in hydrocarbons (HCs) emitted by gasoline (E0) and ethanol (EtOH) blend fuels from flex-fuel capable engines can lead to differences in the performance of aftertreatment devices. Vehicle emission results have shown either better performance on E0 compared to E85 or vice versa, dependent on the vehicle calibration. In order to separate the impact of the vehicle and the catalyst, a laboratory study was conducted to evaluate performance on a pulse-flame (pulsator) reactor and compare reactivity towards E0 and E85 (85% EtOH-15% E0) exhaust. The catalysts evaluated were substrate-only, washcoat-only and fully formulated catalysts that had been aged either on a pulsator reactor or dynamometer engine. Catalyst performance was evaluated with light-off tests utilizing both slow and fast temperature ramp rates.
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