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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Development of Benchmarking Methods for Electric Vehicle Drive Units

2024-04-09
2024-01-2270
As part of the U.S. Environmental Protection Agency’s (EPA’s) continuing assessment of advanced light-duty automotive technologies in support of regulatory and compliance programs, a development project was started to study various test methods to benchmark Electric Drive Units (EDUs) consisting of an electric motor, inverter and a speed-reduction gearset. Several test methods were identified for consideration, including both in-vehicle testing of the complete EDU and stand-alone testing of the EDU and its subcomponents after removal from the vehicle. In all test methods explored, sweeps of speed and torque test points were conducted while collecting key EDU data required to determine efficiency, including motor torque and speed, direct current (DC) battery voltage and current into the inverter, and three-phase alternating current (AC) phase voltages and currents out of the inverter and into the electric motor.
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

Post-Mortem Analysis of DAAAC and Conventionally Aged Aftertreatment Systems

2023-10-31
2023-01-1656
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.
Technical Paper

An Approach for Incorporating Learning into System Design: System Level Assessment Methodology

2023-09-05
2023-01-1517
Shafaat and Kenley in 2015 identified the opportunity to improve System Engineering Standards by incorporating the design principle of learning. The System Level Assessment (SLA) Methodology is an approach that fulfills this need by efficiently capturing the learnings of a team of subject matter experts in the early stages of product system design. By gathering expertise, design considerations are identified that when used with market and business requirements improve the overall quality of the product system. To evaluate the effectiveness of this approach, the methodology has been successfully applied over 400 times within each realm of the New Product Introduction process, including most recently to a Technology Development program (in the earliest stages of the design process) to assess the viability of various electrification technologies under consideration by an automotive Tier 1 supplier.
Journal Article

Low Ambient Temperature Impact on a Low NOX Demonstration System

2023-04-11
2023-01-0361
In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part II: Chemical and Microscopic Characterization of Aged DPFs

2023-04-11
2023-01-0296
This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part I: Accelerated Ash Loading and DPF Performance Evaluation

2023-04-11
2023-01-0297
The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.
Technical Paper

DAAAC Protocol for Durability Demonstration of Diesel Aftertreatment Systems: Emissions Performance Validation

2022-08-30
2022-01-1015
Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.
Technical Paper

Unregulated Emissions Characterization and Comparison for Two Off-Road Applications: A DPF and Non-DPF Engine

2022-03-29
2022-01-0587
As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.
Journal Article

Development of Steady State NO2:NOX Control via an Independent Nitric Decomposition System for the Exhaust Composition Transient Operation Laboratory

2022-03-29
2022-01-0548
Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.
Technical Paper

Development of an Intake Valve Deposit Test with a GM LE9 2.4L Engine

2021-09-21
2021-01-1186
The U.S. Environmental Protection Agency (EPA) certifies gasoline deposit control additives for intake valve deposit (IVD) control utilizing ASTM D5500, a vehicle test using a1985 BMW 318i. Concerns with the age of the test fleet, its relevance in the market today, and the availability of replacement parts led the American Chemistry Council’s (ACC) Fuel Additive Task Group (FATG) to begin a program to develop a replacement. General Motors suggested using a 2.4L LE9 test engine mounted on a dynamometer and committed to support the engine until 2030. Southwest Research Institute (SwRI®) was contracted to run the development program in four Phases. In Phase I, the engine test stand was configured, and a test fuel selected. In Phase II, a series of tests were run to identify a cycle that would build an acceptable level of deposits on un-additized fuel. In Phase III, the resultant test cycle was examined for repeatability.
Technical Paper

Combination of Mixed Metal Oxides with Cu-Zeolite for Enhanced Soot Oxidation on an SCRoF

2021-09-05
2021-24-0071
A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.
Technical Paper

A Novel Methodology to Characterize the Thermal Behavior of Automotive Seats

2021-04-06
2021-01-0204
An automobile seat’s thermal performance can be challenging to quantify since it requires comprehensive human subject testing. Seat manufacturers must rely on subjective ratings to understand how the construction of a seat and its underlying heating and cooling technology may compare to other seats. Other factors may influence seat ratings published by global marketing information services companies (e.g., JD Power and Associates). In particular, occupants may be biased by the vehicle class in which a seat is installed and by how much the contribution of a specific vehicle’s HVAC system performance affects the perception of seat thermal comfort. Therefore, there is a need for an objective testing methodology that does not rely on human participants but is still capable of producing a thermal performance rating in terms of established thermal comfort scales.
Technical Paper

Impact of Selective Catalytic Reduction Process on Nonvolatile Particle Emissions

2021-04-06
2021-01-0624
Particulate matter (PM) and NOX are two major pollutants generated by diesel engines. Modern diesel aftertreatment systems include selective catalytic reduction (SCR) technology that helps reduce tailpipe NOX emissions when coupled with diesel exhaust fluid (DEF/urea) injection. However, this process also results in the formation of urea derived byproducts that can influence non-volatile particle number (PN) measurement conducted in accordance with the European Union (EU) Particle Measurement Program (PMP) protocol. In this program, an experimental investigation of the impact of DEF injection on tailpipe PN and its implications for PMP compliant measurements was conducted using a 2015 model year 6.7 L diesel engine equipped with a diesel oxidation catalyst, diesel particulate filter and SCR system. Open access to the engine controller was available to manually override select parameters.
Journal Article

Increasing the Effective AKI of Fuels Using Port Water Injection (Part I)

2021-04-06
2021-01-0470
Anti-knock index (AKI) is a metric that can be used to quantify the anti-knock performance of a fuel and is the metric used in the United States. AKI is the average of Research Octane Number (RON) and Motor Octane Number (MON), which are calculated for every fuel on a Cooperative Fuel Research (CFR) engine under controlled conditions according to ASTM test procedures. Fuels with higher AKI have better knock mitigating properties and can be run with a combustion phasing closer to MBT in the knock limited operating region of a gasoline engine. However, fuels with higher AKI tend to be costlier and less environmentally friendly to produce. As an alternative, the anti-knock characteristics of lower AKI fuels can be improved with water injection. In this sense, the water injection increases the ‘effective AKI’ of the fuel.
Technical Paper

Assessment of In-Use Solid Particle Number Measurement Systems against Laboratory Systems

2020-10-01
2020-01-5074
Euro VI regulations in Europe and its adaptors recently extended the regulation to include Particle Number (PN) for in-use conformity testing. However, the in-use PN Portable Emissions Measurement System (PEMS) is still evolving and has higher measurement uncertainty when compared against laboratory-grade PN systems. The PN systems for laboratory require a condensation particle counter (CPC). Thus, in this study, a CPC-based Horiba PN-PEMS was selected for performance evaluation against the laboratory-grade PN systems. This study was divided into four phases. The first two phases’ measurements were conducted from the Constant Volume Sampler (CVS) tunnel where the brake-specific particle number (BSPN) levels of 1010-12 and 1013 (#/bhp-h) were measured from the engines equipped with diesel particulate filter (DPF) and without DPF, respectively. In comparison against PN systems, PN-PEMS, on average, reported 14% lower BSPN from 82 various tests for the BSPN levels of 1010-11.
Technical Paper

The Diesel Aftertreatment Accelerated Aging Cycle Protocol: An Advanced Aftertreatment Case Study

2020-09-15
2020-01-2210
As agencies and governing bodies evaluate the feasibility of reduced emission standards, additional focus has been placed on technology durability. This is seen in proposed updates, which would require Original Equipment Manufacturers (OEMs) to certify engine families utilizing a full useful life (FUL) aftertreatment system. These kinds of proposed rulings would place a heavy burden on the manufacturer to generate FUL components utilizing traditional engine aging methods. Complications in this process will also increase the product development effort and will likely limit the amount of aftertreatment durability testing. There is also uncertainty regarding the aging approach and the representative impact compared to field aged units. Existing methodologies have evolved to account for several deterioration mechanisms that, when controlled, can be utilized to create a flexible aging protocol. As a result, these methodologies provide the necessary foundation for continued development.
Technical Paper

Impact of Using Low Thermal Mass Turbine Housing on Exhaust Temperature with Implication on Aftertreatment Warm-Up Benefit for Emissions Reduction

2020-09-02
2020-01-5083
The present study examines the impact of using low thermal mass (LTM) turbine housing designs on the transient characteristics of the turbine outlet temperature for a light-duty diesel standard certification cycle (FTP75). For a controlled exhaust flow, the turbine outlet temperature will directly determine the impact on an aftertreatment system warm-up from a cold state, typical of engine-off and engine idling conditions. The performance of the aftertreatment system such as a Selective Catalytic Reduction (SCR) system is highly dependent on how quickly it warms up to its desirable temperature to be able to convert the harmful oxides of Nitrogen (NOx) to gaseous Nitrogen. Previous works have focused on mostly insulating the exhaust manifold and turbine housing to conserve the heat going into the aftertreatment system. The use of LTM turbine housing has not been previously considered as a means for addressing this requirement.
Technical Paper

A Controls Overview on Achieving Ultra-Low NOx

2020-04-14
2020-01-1404
The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.
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