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The purpose of this paper is to present a prediction method for the refrigerator performance of an automotive air conditioner (A/C). In order to predict the refrigerator performance in arbitrary situations, we consider the thermal equilibrium of the refrigeration cycle through A/C components, as the compressor, the evaporator and the condenser. These components are affected by the thermal property of the refrigerant. Influences of circumstantial flow and temperature field in the engine compartment also are reflected upon, because the cooling performance of the condenser is sensitive to that. In this paper, we try to derive algebraic models for the major components with regard to the thermal equilibrium in the refrigeration cycle. Furthermore, we use a Computational Fluid Dynamics analysis (CFD) for the prediction of cooling airflow temperature in the engine compartment, which is another essential factor in determining the state of the refrigeration cycle.