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For fuel economy improvement by lean-burn gasoline engines, extension of their lean operation range to higher loads is desirable as more fuel is consumed during acceleration. Urgently needed therefore is development of emission control systems having as high NOx conversion efficiency as three-way catalysts (TWC) even with more frequent lean operation. The authors conducted a study using catalysts loaded with potassium (K) as the only NOx trapping agent in an emission control system of a lean-burn gasoline engine.

A new state of the art DOC (Diesel Oxidation Catalyst) having superior light-off and exothermic activity for forced regeneration compared to conventional Pt base passive DOC, was investigated for LDD application. The DOC uses the latest Pt/Pd technology resulting cost effective DPF system. The newly developed DOC demonstrated improved catalytic activities from Pt only DOC in model gas or engine bench tests. In this study, DOC at early development stage showed excellent light-off activity in model gas and engine bench test compared to conventional Pt only DOC, however, it showed “extinction” phenomenon which is one of the deactivation mode while the post injection and it was observed when post injection operation was done at lower DOC inlet temperatures, e.g. below 250 C. Temperature profiles along diameter and length into DOC bed while active regeneration suggested extinction would be caused by fouling of supplied hydrocarbons derived from diesel fuel.