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One of the problems in HCCI combustion is a knocking in higher load conditions. It governs the high load limit, and it is suggested that the knock increases heat loss[1], because it breaks the thermal boundary layer. But it is not clear how much knock affects on heat loss in the HCCI combustion in various conditions, such as ignition timing and load. The motivation of this study is to clarify the ratio of heat loss caused by knock in HCCI engines. The heat loss from zero-dimensional calculations with modified heat transfer coefficient, which is considering the effect of knock by adding a term of cylinder pressure rising rate dp/dt, agreed well with the results from the thermodynamic analysis in various conditions. And the results show that it is possible to avoid heat loss by knock by controlling the ignition timing at appropriate timing after T.D.C. and it will be possible to expand the load range if knock can be avoided.

Thermodynamic characteristics of premixed compression ignition combustions were clarified quantitatively by heat balance estimation. Heat balance was calculated from temperature, mole fractions of intake and exhaust gases, mass and properties of fuels. Heat balance estimation was conducted for three types of combustion; a conventional diesel combustion, a homogeneous charge compression ignition (HCCI) combustion; fuel is provided and mixed with air in an intake pipe in this case, and an extremely early injection type PREmixed lean DIesel Combustion (PREDIC). The results show that EGR should be applied for premixed compression ignition combustion to complete combustion at lower load conditions and to control ignition timing at higher load conditions. With an application of EGR, both HCCI and PREDIC showed low heat loss characteristics at lower load conditions up to 1/2 load.

The concentrations of soot, NO and the other combustion products were measured by incylinder gas sampling in a DI diesel engine. The effects of injection timing, swirl ratio, and combustion chamber geometry on the formation and emission processes of soot and NO were studied. The following results were obtained: (1) Soot is promptly formed in the flame during the early combustion period where the equivalence ratio in the flame is high over 1.0. Thereafter almost all the formed soot is swiftly burnd up by oxidation during the middle combustion period. This process mainly determines the exhaust soot concentration. (2) NO is formed in the flame during the early and middle combustion period where the flame temperature is high over 2000 K. The highest NO concentration is observed at the flame tip swept by the air swirl. Though the concentration of the formed NO decreases by dilusion it nearly constant during the later combustion period.