Search Results

The chemical mechanism responsible for controlling ignition timing by using additives in HCCI has been investigated. Dimethyl ether (DME) and methanol were used as the main fuel and the additive, respectively. Fuel consumption and intermediate formation in the first stage (cool ignition) were measured with crank angle resolved pulse-valve sampling and exhaust gas analysis, where HCHO, HCOOH, CO, H2O2 and other species were detected as the intermediate. The effect of methanol addition retarding ignition is represented by an analytical model in which the growth rate of the chain reaction is reduced by the methanol addition.

Autoignition in the homogeneous charge compression ignition (HCCI) process typically exhibits heat release in two stages called cool flame and thermal flame. The mechanisms governing these two stages were investigated using a DME-fueled HCCI engine and numerical simulations. Composition analysis after cool flame showed that the cool flame is explained by a chain reaction mechanism in which the chain terminator is the intermediate species formed in cool flame. In the case of thermal flame, although the chain reaction mechanism is complex, the behavior is clearly described by thermal explosion theory in which the rate-determining reaction is H2O2 decomposition.