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Flame speed data reported in most literature are acquired in conventional apparatus such as the spherical combustion bomb and counterflow burner, and are limited to atmospheric pressure and ambient or slightly elevated unburnt temperatures. As such, these data bear little relevance to internal combustion engines and gas turbines, which operate under typical pressures of 10-50 bar and unburnt temperature up to 900K or higher. These elevated temperatures and pressures not only modify dominant flame chemistry, but more importantly, they inevitably facilitate pre-ignition reactions and hence can change the upstream thermodynamic and chemical conditions of a regular hot flame leading to modified flame properties. This study focuses on how auto-ignition chemistry affects flame propagation, especially in the negative-temperature coefficient (NTC) regime, where dimethyl ether (DME), n-heptane and iso-octane are chosen for study as typical fuels exhibiting low temperature chemistry (LTC).

Lithium-ion (Li-ion) batteries and issues related to their thermal management and safety have been attracting extensive research interests. In this work, based on a recent thermal chemistry model, the phenomena of thermal runaway induced by a transient internal heat source are computationally investigated using a three-dimensional (3D) model built in COMSOL Multiphysics 5.3. Incorporating the anisotropic heat conductivity and typical thermal chemical parameters available from literature, temperature evolution subject to both heat transfer from an internal source and the activated internal chemical reactions is simulated in detail. This paper focuses on the critical runaway behavior with a delay time around 10s. Parametric studies are conducted to identify the effects of the heat source intensity, duration, geometry, as well as their critical values required to trigger thermal runaway.