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This paper presents a method for analysing the characteristics of nano-scale particles emitted from a 1.6 Litre, 4-stroke, gasoline direct injection (GDI) and turbocharged spark ignition engine fitted with a three-way catalytic converter. Ensemble Empirical Mode Decomposition (EEMD) is employed in this work to decompose the nano-scale particle size spectrums obtained using a differential mobility spectrometer (DMS) into Intrinsic Mode Functions (IMF). Fast Fourier Transform (FFT) is then applied to each IMF to compute its frequency content. The results show a strong correlation between the IMFs of specific particle ranges and the IMFs of the total particle count at various speed and load operating conditions. Hence, it is possible to characterise the influence of specific nano-scale particle ranges on the total particulate matter signal by analysing the frequency components of its IMFs using the EEMD-FFT method.

Engine research has increasingly focused on emission of sub 23 nm particulates in recent years. Likewise, current legislative efforts are being made for particulate number (PN) emission limits to include this previously omitted size range. In Europe, PN measurement equipment and procedures for regulatory purposes are defined by the particle measurement programme (PMP). Latest regulation drafts for sub 23 nm measurements specify counting efficiencies with a 65% cut-off size at 10 nm (d65) and a minimum of 90% above 15 nm (d90). Even though alternative instruments, such as differential mobility spectrometers (DMS), are widely used in laboratory environments, the interpretation of their sub 23 nm measurements has not yet been widely discussed. For this study, particulate emissions of a 1.0L gasoline direct injection (GDI) engine have been measured with a DMS system for low to medium speeds with two load steps.

Formula 1 has always played a major role in technological advancements within the automotive and motorsport sectors. The adaptive changes introduced for the Power Unit (PU) in 2014 forced constructors, in collaboration with industry partners, to invent technologies for exceeding 50% brake thermal efficiency within a short span of time, demonstrating that technology-forcing regulations through motorsport is the favorable route to achieve transformative changes within the automotive sector. Therefore, in an attempt to address arising global warming and health concerns, the present work analytically examines the ambient air quality in track stadia during F1 race events to identify potential PU exhaust emission targets. It models the volume of air contained within the circuits located near heavily built-up areas assuming stagnant air conditions and uniform mixing.

Characterization of soot nanoparticle morphology can be used to develop understanding of nanoparticle interaction with engine lubricant oil and its additives. It can be used to help direct modelling of soot-induced thickening, and in a more general sense for combatting reductions in engine efficiency that occur with soot-laden oils. Traditional 2D transmission electron microscopy (TEM) characterization possesses several important shortcomings related to accuracy that have prompted development of an alternative 3D characterization technique utilizing electron tomography, known as 3D-TEM. This work details progress made towards facilitating semi-automated image acquisition and processing for location of structures of interest on the TEM grid. Samples were taken from a four cylinder 1.4 L gasoline turbocharged direct injection (GTDI) engine operated in typically extra-urban driving conditions for 20,284 km, with automatic cylinder deactivation enabled.

Morphology plays an important role in determining behaviour and impact of soot nanoparticles, including effect on human health, atmospheric optical properties, contribution to engine wear, and role in marine ecology. However, its nanoscopic size has limited the ability to directly measure useful morphological parameters such as surface area and effective volume. Recently, 3D morphology characterization of soot nanoparticles via electron tomography has been the subject of several introductory studies. So-called ‘3D-TEM’ has been posited as an improvement over traditional 2D-TEM characterization due to the elimination of the error-inducing information gap that exists between 3-dimensional soot structures and 2-dimensional TEM projections. Little follow-up work has been performed due to difficulties with developing methodologies into robust high-throughput techniques.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

Environmental authorities such as EPA, VCA have enforced stringent emissions legislation governing air pollutants released into the atmosphere. Of particular interest is the challenge introduced by the limit on particulate number (PN) counting (#/km) and real driving emissions (RDE) testing; with new emissions legislation being shortly introduced for the gasoline direct injection (GDI) engines, gasoline particulate filters (GPF) are considered the most immediate solution. While engine calibration and testing over the Worldwide harmonized Light vehicles Test Cycle (WLTC) allow for the limits to be met, real driving emission and cold start constitute a real challenge. The present work focuses on an experimental durability study on road under real world driving conditions. Two sets of experiments were carried out. The first study analyzed a gasoline particulate filter (GPF) (2.4 liter, diameter 5.2” round) installed in the underfloor (UF) position and driven up to 200k km.

Onboard diagnostic regulations require performance monitoring of diesel particulate filters used in vehicle aftertreatment systems. Delphi has developed a particulate matter (PM) sensor to perform this function. The objective of this sensor is to monitor the soot (PM) concentration in the exhaust downstream of the diesel particulate filter which provides a means to calculate filter efficiency. The particulate matter sensor monitors the deposition of soot on its internal sensing element by measuring the resistance of the deposit. Correlations are established between the soot resistance and soot mass deposited on the sensing element. Currently, the sensor provides the time interval between sensor regeneration cycles, which, with the knowledge of the exhaust gas flow parameters, is correlated to the average soot concentration.

Stringent emission norms introduced by the legislators over the decades has forced automotive manufacturers to improve the fuel economy and emission levels of their engines continuously. Therefore, the emission levels of modern engines are significantly lower than pre-1990 engines. However, the improvement in fuel economy is marginal when compared to that of emission levels. For example, approximately 30% of total energy in the fuel is being wasted through the cooling systems in the modern engines. Therefore, thermal management systems are being developed to reduce these losses and offer new opportunities for improving the fuel economy of the vehicles. One of the new emerging technologies for thermal management is the use of nanofluids as coolant. Nanofluids are a mixture of nano-sized particles added to a base fluid to improve its thermal characteristics.

The focus of this study is to analyse changes in soot particle size along the predicted pathlines as they pass through different in-cylinder combustion histories obtained from Kiva-3v CFD simulation with a series of Matlab routines. 3500 locations representing soot particles were selected inside the cylinder at 8° CA ATDC as soot was formed in high concentration at this CA. The dominant soot particle size was recorded within the size range of 20-50 nm at earlier CA and shifted to 10-20 nm after 20° CA ATDC. Soot particle quantities reduce sharply until 20° CA ATDC after which they remain steady at around 1500 particles. Soot particles inside the bowl region tend to stick to the bowl walls and those remaining in the bowl experience an increase in size. Soot particles that move to the upper bowl and squish regions were observed to experience a decrease in size.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

The influence of size and concentration of carbon nanoparticle on the viscosity of an SAE 5W-30 lubricant oil has been investigated experimentally. Data were collected for oil samples drawn from sump of light duty automotive diesel engines. The average size of soot particles in the used oil samples was in the range of 180-320nm with concentrations ranging from 0 to 2 percentage by weight (wt. %.). A Brookfield DV-II Pro rotary viscometer was used to measure dynamic viscosity at low shear rates and temperatures of 40°C and 90°C. Nanoparticle concentration and particle size distribution were evaluated using Thermo-Gravimetric Analysis (TGA) and Dynamic Light Scattering (DLS) respectively. The viscosity of suspensions of graphite powder in lubricant oil was also investigated for concentrations ranging from 0 to 2 wt. %. The results show that dynamic viscosity increases with increasing soot content and decreasing temperature.

This work investigates the effect of a three-way catalytic converter and sampling dilution ratio on nano-scale exhaust particulate matter emissions from a gasoline direct-injection engine during cold-start and warm-up transients. Experimental results are presented from a four cylinder in-line, four stroke, wall-guided direct-injection, turbo-charged and inter-cooled 1.6 litre gasoline engine. A fast-response particulate spectrometer for exhaust nano-particle measurement up to 1000 nm was utilised. It was observed that the three-way catalytic converter had a significant effect on particle number density, reducing the total particle number by up to 65 % over the duration of the cold-start test. The greatest change in particle number density occurred for particles less than 23 nm diameter, with reductions of up to 95 % being observed, whilst the number density for particles above 50 nm diameter exhibited a significant increase.

This work investigates the effect of engine operating conditions and exhaust sampling conditions (i.e. dilution ratio) on engine-out, nano-scale, particulate matter emissions from a gasoline direct-injection engine during cold-start and warm-up transients. The engine used for this research was an in-line four cylinder, four stroke, wall-guided direct-injection, turbo-charged and inter-cooled 1.6 l gasoline engine. A fast-response particulate spectrometer for exhaust nano-particle measurement up to 1000 nm was utilized, along with a spark-plug mounted pressure transducer for combustion analysis. It was observed that the total particle count decreases during the cold-start transient, and has a distinct relationship with the engine body temperature. Tests have shown that the engine body temperature may be used as a control strategy for engine-out particulate emissions.

Soot formation and distribution inside the cylinder of a light-duty direct injection diesel engine, have been predicted using Kiva-3v CFD software. Pathlines of soot particles traced from specific in-cylinder locations and crank angle instants have been explored using the results for cylinder charge motion predicted by the Kiva-3v code. Pathlines are determined assuming soot particles are massless and follow charge motion. Coagulation and agglomeration have not been taken into account. High rates of soot formation dominate during and just after the injection. Oxidation becomes dominant after the injection has terminated and throughout the power stroke. Computed soot pathlines show that soot particles formed just below the fuel spray axis during the early injection period are more likely to travel to the cylinder wall boundary layer. Soot particles above the fuel spray have lesser tendency to be conveyed to the cylinder wall.

The effect of compression ratio on sensitivity to changes in start of injection and air-fuel ratio has been investigated on a single-cylinder DI diesel engine at fixed low and medium speeds and loads. Compression ratio was set to 17.9:1 or 13.7:1 by using pistons with different bowl sizes. Injection timing and air-to-fuel ratio were swept around a nominal map point at which gross IMEP and NOx values were matched for the two compression ratios. It was found that CO, HC and ISFC were higher at low compression ratio, but the soot/NOx trade-off improved and this could be exploited to reduce the fuel economy penalty. Sensitivity to inputs is generally similar, but high compression ratio tended to have steeper response gradients. Reducing compression ratio to 13.7 gave rise to a marked degradation of performance at light load, producing high CO emissions and a fall in combustion efficiency. This could be eased by reducing rail pressure, but the advantage in smoke emission was lost.

This work attempted to correlate the ultra fine particulate count to the flame propagation time, in-cylinder peak pressure, and in-cylinder ageing time (the time the particulates stay inside the cylinder) of a throttle body gasoline injected engine. The engine was tested at different loads and speeds ranging from 20 Nm to 100 Nm and 2000 to 3400 rpm respectively. A fast particle spectrometer, a mass spectrometer, and an in-cylinder pressure measurement system were used to characterize the particulate emission. This work identified the correlation between the nucleation of particulates and rate of burning, the particulate count for particles size greater than 200 nm and the in-cylinder ageing time. It identified that an increase in engine load at constant speed increased the particle number density of the 10 nm diameter particles; the effect was less significant on the particles of diameter greater than 50 nm and almost absent on particles of diameter greater than 200 nm.

This study attempted to identify the correlation between the gaseous species and nano-scale exhaust particles from a gasoline engine using simultaneous particulate and gaseous measurement. A fast particle spectrometer for particulates and a quadrupole mass spectrometer for gaseous species were employed in this work. Two commercially available super unleaded gasoline fuels were used in this study to establish a link between the gaseous species and nano-scale particulates. The possible correlations between the gaseous species such as acetylene, 1, 5 hexadyne, toluene, benzene and furaldehyde and nano-scale particles were identified and are detailed in this paper.

Recent developments in measurement techniques enabled researchers to measure ultra-fine particulates of nano-scale range and provided more evidence that the smaller particulates typically emitted from gasoline engines may have more severe impacts on human respiratory system than the bigger particulates from diesel engines. The knowledge of the characteristics of particulates from gasoline engines, especially, the effect of fuel borne additives is sparse. This work presents the findings from a study into the effect of aftermarket additives on nano-scale particulates. Four commercially available fuel borne additives used in gasoline engines mainly by private vehicle owners in the United Kingdom were selected for this study. The combustion and emission performance of the additive fuels were compared against that of commercially available gasoline fuel using a 4-stroke, throttle body injected gasoline engine.

In a context of global warming and our needs to reduce CO2 emissions, building envelopes will play an important role. A new imperative has been put forth to architects and engineers to develop innovative materials, components and systems, in order to make building envelopes adaptive and responsive to variable and extreme climate conditions. Envelopes serve multiple functions, from shielding the interior environment to collecting, storing and generating energy. Perhaps a more recent concern of terrestrial habitats is permeability and leakages within the building envelope. Such air tight and concealed envelopes with zero particle exchange are a necessity and already exist in regard to space capsules and habitats. This paper attempts to acknowledge existing and visionary envelope concepts and their functioning in conjunction with maintaining a favourable interior environment. It introduces several criteria and requirements of advanced façades along with interior pressurization control.