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With the aim of decarbonizing the vehicles fleet, the use of hydrogen is promising solution. Hydrogen is an energy carrier, carbon-free, with high calorific value and with no CO2 and HC emissions burning in ICE. Hydrogen use in spark ignition engines has already been extensively investigated and optimized. On the other hand, its use in compression ignition engines has been little developed and, therefore, there is a lack of information regarding the combustion in ultra-lean conditions, typical of diesel engines. Several applications employ dual fuel combustion for the easy management of the PFI injection system to be applied in addition to the DI Common Rail system. However, this mode suffers from several problems regarding the management of the maximum flow rate of hydrogen into the intake. In particular, to avoid throwing hydrogen into the exhaust, injection must be started after the valve crossing.

In this work, an ozone/air/gasoline mixture has been used as an alternative strategy to achieve a stable combustion in a spark ignition (SI) single cylinder PFI research engine. The air intake manifold has been modified to include four cells to produce ozone with different concentrations. In the research engine, various operating parameters have been monitored such as the in-cylinder pressure, temperature and composition of the exhaust gases, pressure and temperature of the mixture in the intake manifold, engine power and torque and specific fuel consumption. Experimental tests have been carried out under stoichiometric mixture conditions to observe the influence of ozone addition on the combustion process. The results show an advance and an increase of the in-cylinder pressure compared to the reference test-case, where a gasoline/air mixture is used. It is worth noting that, especially under stoichiometric condition, ozone concentration induces auto-ignition and knock.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.