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Heat transfer in the combustion chamber of s.i. engines operating under knocking conditions has been detected and analyzed. Measurements have been carried out, cycle by cycle, on a CFR laboratory engine by means of a dedicated instrument and an original method. The relationship between heat transfer and knock intensity has been analyzed on a statistical basis, emphasizing knock intensity influence on heat transfer distribution. Moreover, the share of heat transfer more closely related to knock intensity has been highlighted: heat transfer is shown not to be significantly affected by knock intensity under light-to-medium knock conditions; on the contrary, the influence becomes evident under medium-to-heavy knock conditions. Eventually, heat transfer indexes influenced by knock intensity have been evaluated, allowing a comparison of knock-related thermal properties of fuels.

An experimental investigation on a group of unleaded gasolines of different chemical composition has been carried out, in order to analyze their knock behaviour in a mass-produced engine at high revolution speed, to highlight possible inconsistencies with their standard Research and Motor octane numbers and to try to discover explanations for the abovementioned inconsistencies. The investigation has been focused on fuels containing oxygenated compounds, such as alcohols (methanol and ethanol) and ethers (MTBE), with the aim of pointing out the influence of the fuel composition on the octane rating, especially as far as the variation in the stoichiometric air/fuel ratio (due to oxygenated compounds blending) is concerned. In particular, the rating of all the fuels under the same relative air/fuel ratio has shown to be a mandatory condition in order to obtain a proper estimate of antiknock performances. The evaluations obtained are consistent with the standard Motor octane numbers.