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Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this, but a practical concern is the flammability of the headspace vapours in the vehicle fuel tank. Gasoline is much more volatile than diesel so, at most ambient temperatures, the headspace vapours in the tank are too rich to burn. A gasoline/diesel mixture in a fuel tank therefore can result in a flammable headspace, particularly at cold ambient temperatures. A mathematical model is presented that predicts the flammability of the headspace vapours in a tank containing mixtures of gasoline and diesel fuel. Fourteen hydrocarbons and ethanol represent the volatile components. Heavier components are treated as non-volatile diluents in the liquid phase.

The influence of gasoline quality on exhaust emissions has been evaluated using four modern European gasoline cars with advanced features designed to improve fuel economy and CO2 emissions, including stoichiometric direct injection, lean direct injection and MPI with variable valve actuation. Fuel effects studied included sulphur content, evaluated over a range from 4 to 148 mg/kg, and other gasoline properties, including aromatics content, olefins content, volatility and final boiling point (FBP). All four cars achieved very low emissions levels, with some clear differences between the vehicle technologies. Even at these low emissions levels, all four cars showed very little short-term sensitivity to gasoline sulphur content. The measured effects of the other gasoline properties were small and often conflicting, with differing directional responses for different vehicles and emissions.