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Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.

According to the Annual Energy Outlook 2022 (AEO2022) report, almost 30% of the transport sector will still use internal combustion engines (ICE) until 2050. The transportation sector has been actively seeking different methods to reduce the CO2 emissions footprint of fossil fuels. The use of lower carbon-intensity fuels such as Renewable Diesel (RD) can enable a pathway to decarbonize the transport industry. This suggests the need for experimental or advanced numerical studies of RD to gain an understanding of its combustion and emissions performance. This work presents a numerical modeling approach to study the combustion and emissions of RD. The numerical model utilized the development of a reduced chemical kinetic mechanism for RD’s fuel chemistry. The final reduced mechanism for RD consists of 139 species and 721 reactions, which significantly shortened the computational time from using the detailed mechanism.

Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.

Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.

Dedicated-EGR™ (D-EGR™) is a concept where the exhaust of one dedicated cylinder (D-Cyl) is routed into the intake thus producing EGR to be used by the whole engine. The D-Cyl operates rich of stochiometric which produces syngas that enhances the EGR stream permitting faster combustion and greater knock mitigation. Operating an engine using D-EGR improves the knock resistance which can permit a higher compression ratio (CR) thereby increasing efficiency. One challenge of traditional D-EGR is that the D-Cyl combustion becomes unstable operating with both rich and EGR dilute conditions. Therefore, the ‘Split Intake D-EGR’ concept seeks to resolve this problem by feeding fresh air to the D-Cyl, thus allowing even richer operation in the D-Cyl which further increases the H2 and CO yield thereby enhancing the efficiency benefits.

A physics-based spark ignition model was developed and integrated into a commercial CFD code. The model predicted the spark discharge process based on the electrical parameters of the secondary ignition circuit, tracked the spark motion as it was stretched by in-cylinder gas motion, and determined the resulting energy deposition to the gas. In concert with the existing kinetic solver in the CFD code, the resulting ignition and flame propagation processes were simulated. The model results have been validated against both imaging rig experiments of the spark in moving air and against engine experimental data. The model was able to replicate the key features of the spark and to capture the cyclic variability of high-dilution combustion when multiple engine cycles were simulated.

This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement.

In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.

Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

The automotive sector is rapidly transitioning to decarbonized, electric vehicles solutions. However, due to challenges with such rapid adoption, Internal combustion engines (ICE) are expected to be used for decades to come. In this transition period it is important to continue to improve ICE efficiency. A key design parameter to increase ICE efficiency is the compression ratio. For gasoline engines, the compression ratio is limited so as to avoid knock. Engine designers can employ several strategies to mitigate knock and enable higher compression ratios. In this study, a new methodology has been developed to compare various knock mitigation strategies. By comparing the knock limited load at a given combustion phasing the expected compression ratio increase can be inferred.

Interaction between a diesel spray and piston plays a significant role in overall combustion and emissions performance in compression-ignition engines. It is essential to design the lip feature respective to spray targeting and the following charge motion for combustion systems that rely on spray-piston interaction strongly, such as a stepped-lip piston. This study used a numerical campaign using computational fluid dynamics (CFD) simulation to optimize a stepped-lip combustion system at a 22:1 compression ratio (CR) for both performance and emissions. This is a substantial step up in CR from the stock value of 17:1 for the same engine platform. A machine learning model was used to identify the best combination of features from a design space involving hundreds of potential piston designs and injector nozzle configurations. This study provides a discussion on the general combustion characteristics of the stepped-lip combustion system and the sensitivity of the design parameters.

Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.

The commercial vehicle industry continues to move in the direction of improving brake thermal efficiency while meeting more stringent diesel engine emission requirements. This study focused on demonstrating future emissions by using an exhaust burner upstream of a conventional aftertreatment system. This work highlights system results over the low load cycle (LLC) and many other pertinent cycles (Beverage Cycle, and Stay Hot Cycle, New York Bus Cycle). These efforts complement previous works showing system performance over the Heavy-Duty FTP and World Harmonized Transient Cycle (WHTC). The exhaust burner is used to raise and maintain the Selective Catalytic Reduction (SCR) catalyst at its optimal temperature over these cycles for efficient NOX reduction. This work showed that tailpipe NOX is significantly improved over these cycles with the exhaust burner.

Simulating high amounts of exhaust gas recirculation in spark ignited engines to predict combustion using the currently available CFD modeling approaches is a challenge and does not always give reasonable matches with experimental observations. One of the reasons for the mismatch lies with the secondary circuit treatment of the ignition coil and the resulting energy deposition or a complete lack of it thereof. An ignition modeling approach is developed in this work which predicts the energy transfer from the electrical circuit to the gases in the combustion chamber leading to flame kernel growth under high EGR and high gas flow velocity conditions. Secondary circuit sub-model includes secondary side of the coil, spark plug and spark gap. The sub-model calculates the delivered energy to the gas based on given circuit properties and total initial electrical energy.

Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.

The dedicated exhaust gas recirculation (D-EGR®) concept developed by Southwest Research Institute (SwRI) has demonstrated a thermal efficiency increase on several spark-ignited engines at both low and high-load conditions. Syngas (H2+CO) is produced by the dedicated cylinder (D-cyl) which operates at a rich air-fuel ratio. The syngas helps to stabilize combustion under highly dilute conditions at low loads as well as mitigating knock at high loads. The D-cyl produces all the EGR for the engine at a fixed rate of approximately 25% EGR for a four-cylinder engine and 33% EGR for a six-cylinder engine. The D-cyl typically runs up to an equivalence ratio of 1.4 for gasoline-fueled engines, beyond which the combustion becomes unstable due to the decreasing laminar burning velocity caused by rich conditions. Conventional active-fueled and passive pre-chambers have benefits of inducing multi-site ignition and enhancing turbulence in the main chamber.

The size and distribution of a vehicle’s tailpipe particulate emissions can have a strong impact on human health, especially if the particles are small enough to enter the human respiratory system. Gasoline direct injection (GDI) has been adopted widely to meet stringent fuel economy and CO2 regulations across the globe for recent engine architectures. However, the introduction of GDI has led to challenges concerning the particulate matter (PM) and particle number (PN) emissions from such engines. This study aimed to compare the particulate emissions of three SI combustion strategies: conventional SI, conventional stoichiometric low-pressure exhaust gas recirculation (LP-EGR), and Dedicated-EGR (D-EGR) at four specific test conditions. It was shown that the engine-out PM/PN for both the EGR strategies was lower than the conventional SI combustion under normal operating conditions. The test conditions were chosen to represent the WLTC test conditions.

Detailed characterization of particle emissions from three different engine technologies were performed, two of which were advanced technology engines. One of the engines was a nonroad Tier 4 Final emission regulation compliant 6.8L John Deere PSS 6068 diesel engine operated with its production calibration strategy. The other two engine platforms were advanced engine technologies whose controllers were developed by Southwest Research Institute (SwRI). These included a dual fuel Navistar MaxxForce 13L natural gas-diesel engine and a Cummins ISX 15L diesel engine. The dual fuel engine was operated in two distinct modes, conventional dual fuel (CDF) mode and low temperature reactivity controlled compression ignition (RCCI) mode. The Cummins ISX engine was operated using a “hot” or low EGR combustion strategy. For each engine technology, the test campaign involved steady-state test modes ranging from low speed low load to high speed high load conditions.

Commercial vehicles require fast aftertreatment heat-up in order to move the SCR catalyst into the most efficient temperature range to meet upcoming NOX regulations. Today’s diesel aftertreatment systems require on the order of 10 minutes to heat up during a cold FTP cycle. The focus of this paper is to heat up the aftertreatment system as quickly as possible during cold starts and maintain a high temperature during low load, while minimizing fuel consumption. A system solution is demonstrated using a heavy-duty diesel engine with an end-of-life aged aftertreatment system targeted for 2027 emission levels using various levels of controls. The baseline layer of controls includes cylinder deactivation to raise the exhaust temperature more than 100° C in combination with elevated idle speed to increase the mass flowrate through the aftertreatment system. The combination yields higher exhaust enthalpy through the aftertreatment system.

With the advancement of engine technologies and combustion strategies, aftertreatment architectures are expected to evolve as they continue to be the primary emissions mitigation hardware. Some of the engine approaches offer unique challenges and benefits that are not well understood beyond criteria pollutant emissions. As such, there continues to be a need to quantify engine emissions characteristics in pursuit of catalyst technology development and the use of advanced simulation tools. The following study discusses results from an extensive engine emissions assessment for current state-of-the-art technology and novel combustion regimes. The engines tested include a Tier 4 final compliant 6.8 L John Deere PSS 6068 diesel engine, a modified 15 L diesel engine, and a dual fuel 13 L natural gas-diesel engine. The dual fuel engine could operate in conventional positive ignition mode (CDF) or low temperature reactivity-controlled compression ignition mode (RCCI).