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Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

Dual fuel engines have shown significant potential as high efficiency powerplants. In one example, SwRI® has run a high EGR, dual-fuel engine using gasoline as the main fuel and diesel as the ignition source, achieving high thermal efficiencies with near zero NOx and smoke emissions. However, assuming a tank size that could be reasonably packaged, the diesel fuel tank would need to be refilled often due to the relatively high fraction of diesel required. To reduce the refill interval, SwRI investigated various alternative fluids as potential ignition sources. The fluids included: Ultra Low Sulfur Diesel (ULSD), Biodiesel, NORPAR (a commercially available mixture of normal paraffins: n-pentadecane (normal C15H32), and n-hexadecane (normal C16H34)) and ashless lubrication oil. Lubrication oil was considered due to its high cetane number (CN) and high viscosity, hence high ignitability.