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Technical Paper

Diesel Oxidation Catalyst Performance with Biodiesel Formulations

2024-04-09
2024-01-2711
Biodiesel (i.e., mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats) is a renewable diesel fuel providing life-cycle greenhouse gas emission reductions relative to petroleum-derived diesel. With the expectation that there would be widespread use of biodiesel as a substitute for ultra-low sulfur diesel (ULSD), there have been many studies looking into the effects of biodiesel on engine and aftertreatment, particularly its compatibility to the current aftertreatment technologies. The objective of this study was to generate experimental data to measure the effectiveness of a current technology diesel oxidation catalysts (DOC) to oxidize soy-based biodiesel at various blend levels with ULSD. Biodiesel blends from 0 to 100% were evaluated on an engine using a conventional DOC.
Technical Paper

Improved Combustion Efficiency in Methanol/Renewable Diesel Dual Fuel Combustion by Advanced Injection Timing and Increased Intake Temperature: Single-Cylinder Experiment

2023-10-31
2023-01-1641
Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.
Technical Paper

Comparison on Combustion and Emissions Performance of Biodiesel and Diesel in a Heavy-duty Diesel Engine: NOX, Particulate Matter, and Particle Size Distribution

2023-09-29
2023-32-0100
Low carbon emissions policies for the transportation sector have recently driven more interest in using low net-carbon fuels, including biodiesel. An internal combustion engine (ICE) can operate effectively using biodiesel while achieving lower engine-out emissions, such as soot, mostly thanks to oxygenate content in biodiesel. This study selected a heavy-duty (HD) single-cylinder engine (SCE) platform to test biodiesel fuel blends with 20% and 100% biodiesel content by volume, referred to as B20, and B100. Test conditions include a parametric study of exhaust gas recirculating (EGR), and the start of injection (SOI) performed at low and high engine load operating points. In-cylinder pressure and engine-out emissions (NOX and soot) measurements were collected to compare diesel and biodiesel fuels.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part I: Accelerated Ash Loading and DPF Performance Evaluation

2023-04-11
2023-01-0297
The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.
Technical Paper

Diesel Particulate Filter Durability Performance Comparison Using Metals Doped B20 vs. Conventional Diesel Part II: Chemical and Microscopic Characterization of Aged DPFs

2023-04-11
2023-01-0296
This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.
Technical Paper

Engine and Emissions Performance of Renewable Diesel in a Heavy-Duty Diesel Engine: A Single-cylinder Engine Experiment

2023-04-11
2023-01-0273
As an alternative fuel, renewable diesel (RD) could improve the performance of conventional internal combustion engines (ICE) because of its difference in fuel properties. With almost no aromatic content in the fuel, RD produces less soot emissions than diesel. The higher cetane number (CN) of RD also promotes ignition of the fuel, which is critical, especially under low load, and low reactivity conditions. This study tested RD fuel in a heavy-duty single-cylinder engine (SCE) under compression-ignition (CI) operation. Test condition includes low and high load points with change in exhaust gas recirculation (EGR) and start of injection (SOI). Measurements and analysis are provided to study combustion and emissions, including particulate matters (PM) mass and particle number (PN). It was found that while the combustion of RD and diesel are very similar, PM and PN emissions of RD were reduced substantially compared to diesel.
Technical Paper

Evaluation of Indrio’s Ammonia Sensor using a Diesel Fuel Based Burner Platform

2023-04-11
2023-01-0383
This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement.
Technical Paper

Reduced Power Cylinder Friction with Advanced Coatings and Optimized Lubricants

2022-03-29
2022-01-0523
The engine power cylinder is comprised of the piston, piston rings, and cylinder. It accounts for a significant amount of total engine friction within reciprocating, internal combustion engines. Reducing power cylinder friction is key to the development of efficient internal combustion engines. However, isolating individual power cylinder tribocouples for detailed analysis can be challenging. In this work, a new reciprocating liner test rig is developed and introduced. The rig design is novel, using a stationary piston and a reciprocating cylinder liner. Friction is calculated from the force measured in the connecting rod which supports the piston. The rig allows for independent control of peak cylinder pressure, speed, and lubricant temperature. Using the newly developed test rig, several technologies for friction reduction are evaluated and compared.
Technical Paper

Continuous Oil Consumption Measurement Using Laser Induced Breakdown Spectroscopy

2022-03-29
2022-01-0581
This paper describes a new method for measuring oil consumption using laser induced breakdown spectroscopy (LIBS). LIBS focuses a high energy laser pulse on a sample to form a transient plasma. As the plasma cools, each element produces atomic emission lines which can be used to identify and quantify the elements present in the original sample. In this work, a LIBS system was used on simulated engine exhaust with a focus on quantifying the inorganic components (termed ash) of the particulate emissions. Because some of the metallic elements in the ash almost exclusively result from lube oil consumption, their concentrations can also be correlated to an oil consumption rate. Initial testing was performed using SwRI’s Exhaust Composition Transient Operation Laboratory®(ECTO-Lab®) burner system so that oil consumption and ash mass could be precisely controlled.
Journal Article

Fuel Additive Transport into Engine Oil Determination using Laser Induced Fluorescence (LIF) and Liquid Chromatography (LC)

2021-09-21
2021-01-1149
The transport of fuel-borne additives into the engine oil is a critical factor for the efficacy with which the additive functionality can be imparted on the engine. This paper describes the combination of Laser Induced Fluorescence (LIF) and Liquid Chromatography (LC) to determine the real-time additive concentrations and transfer ratios in a spark-ignition, 2-liter GM LHU engine. The current research used a continuous sample circuit from the engine sump which passed through an integrating cavity flow cell to enhance the LIF signal. In the absence of a fluorescence signature of any of the native additive species, a suitable fluorescing dye was selected to simulate the additive. After establishing rigorous calibration curves, LC was employed as a referee method to do a direct comparison with the LIF determined dye concentrations.
Technical Paper

Reduced Piston Oil Cooling for Improved Heavy-Duty Vehicle Fuel Economy

2021-04-06
2021-01-0387
Increased electrification of future heavy-duty engines and vehicles can enable many new technologies to improve efficiency. Electrified oil pumps are one such technology that provides the ability to reduce or turn off the piston oil cooling jets and simultaneously reduce the oil pump flow to account for the reduced flow rate required. This can reduce parasitic losses and improve overall engine efficiency. In order to study the potential impact of reduced oil cooling, a GT-Power engine model prediction of piston temperature was calibrated based on measured piston temperatures from a wireless telemetry system. A simulation was run in which the piston oil cooling was controlled to target a safe piston surface temperature and the resulting reduction in oil cooling was determined. With reduced oil cooling, engine BSFC improved by 0.2-0.8% compared to the baseline with full oil cooling, due to reduced heat transfer from the elevated piston temperatures.
Technical Paper

Solid Particle Emissions from a Diesel Fuel Based Burner Platform

2021-04-06
2021-01-0627
Diesel engines are the primary power source for the medium and heavy-duty truck applications in the US. There is a wide range of regulatory developments being considered in the US that would impact the field of diesel engines and aftertreatment systems, such as the California Air Resources Board’s (CARB) low NOX standards and the extended durability requirement for aftertreatment systems. The proposed durability standards would require manufacturers to develop aftertreatment systems targeting up to 800,000 miles of full useful life (FUL) for Heavy heavy-duty (HHD) Application. Robust design and validation of aftertreatment systems is critical to ensure compliance with such stringent regulations. Several methodologies are being considered by the regulatory agencies for the compliance validation process, including the option of accelerated aging of the aftertreatment systems for a portion of the FUL.
Journal Article

Market Fuel Effects on Low Speed Pre-Ignition

2021-04-06
2021-01-0487
Low-Speed Pre-ignition (LSPI) is an undesirable abnormal combustion phenomenon observed in turbocharged, direct-injection spark-ignition engines and is characterized by early heat release, high cylinder pressures and severe, potentially damaging knock. LSPI has been studied for more than a decade and engine design, operating conditions and fuel and engine oil formulations have all been identified as contributing factors. A significant focus on engine oil has led to the establishment of the Sequence IX engine test and the second-generation of GM dexos® oil requirements, as well as a convergence of engine oil detergent causality. Conclusions about the effects of fuel on LSPI have been more varied, but as part of a recently completed research consortium, the LSPI tendency of market fuels with a range of properties, including composition, boiling point distribution, ethanol content and particulate matter index (PMI) were evaluated.
Journal Article

Detailed Analyses and Correlation of Fuel Effects on Stochastic Preignition

2020-04-14
2020-01-0612
Stochastic or Low-Speed Preignition (SPI or LSPI) is an undesirable abnormal combustion phenomenon encountered in spark-ignition engines. It is characterized by very early heat release and high cylinder pressure and can cause knock, noise and ultimately engine damage. Much of the focus on mitigating SPI has been directed towards the engine oil formulation, leading to the emergence of the Sequence IX test and second-generation GM dexos® oil requirements. Engine design, calibration and fuels also contribute to the prevalence of SPI. As part of a recently completed research consortium, a series of engine tests were completed to determine the impact of fuel composition on SPI frequency. The fuel blends had varying levels of paraffins, olefins, aromatics and ethanol.
Technical Paper

Combined Fuel and Lubricant Effects on Low Speed Pre-Ignition

2018-09-10
2018-01-1669
Many studies on low speed pre-ignition have been published to investigate the impact of fuel properties and of lubricant properties. Fuels with high aromatic content or higher distillation temperatures have been shown to increase LSPI activity. The results have also shown that oil additives such as calcium sulfonate tend to increase the occurrence of LSPI while others such as magnesium sulfonate tend to decrease the occurrence. Very few studies have varied the fuel and oil properties at the same time. This approach is useful in isolating only the impact of the oil or the fuel, but both fluids impact the LSPI behavior of the engine simultaneously. To understand how the lubricant and fuel impacts on LSPI interact, a series of LSPI tests were performed with a matrix which combined fuels and lubricants with a range of LSPI activity. This study was intended to determine if a low activity lubricant could suppress the increased LSPI from a high activity fuel, and vice versa.
Technical Paper

Effect of Lubricant Oil on Particle Emissions from a Gasoline Direct Injection Light-Duty Vehicle

2018-09-10
2018-01-1708
Gasoline direction injection (GDI) engines have been widely used by light-duty vehicle manufacturers in recent years to meet stringent fuel economy and emissions standards. Particulate Matter (PM) mass emissions from current GDI engines are primarily composed of soot particles or black carbon with a small fraction (15% to 20%) of semi-volatile hydrocarbons generated from unburned/partially burned fuel and lubricating oil. Between 2017 and 2025, PM mass emissions regulations in the USA are expected to become progressively more stringent going down from current level of 6 mg/mile to 1 mg/mile in 2025. As PM emissions are reduced through soot reduction, lubricating oil derived semi-volatile PM is expected to become a bigger fraction of total PM mass emissions.
Technical Paper

Development of a Standardized Test to Evaluate the Effect of Gasoline Engine Oil on the Occurrence of Low Speed Pre-Ignition - The Sequence IX Test

2018-09-10
2018-01-1808
The study described in this paper covers the development of the Sequence IX Low Speed Pre-Ignition (LSPI) test for the new engine oil category, ILSAC GF-6. The purpose of the Sequence IX test is to evaluate a lubricant’s ability to protect against LSPI events which are prevalent when operating a highly boosted/downsized gasoline direct-injected engine. LSPI is characterized as a combustion event that starts before ignition spark, typically followed by excessive in-cylinder pressures and heavy knock, which can cause severe engine damage and failure. Industry research has shown that oil formulation can contribute to the frequency of LSPI activity. The Sequence IX test was developed using a turbocharged gasoline direct-injected 2.0 liter Ford Ecoboost engine with dual independent variable cam timing. The engine was modified with in-cylinder pressure sensors and a high-resolution crank angle encoder to characterize individual engine combustion cycles and identify potential LSPI events.
Technical Paper

Effect of Micro-Hole Nozzle on Diesel Spray and Combustion

2018-04-03
2018-01-0301
The influence of nozzle geometry on spray and combustion of diesel continues to be a topic of great research interest. One area of promise, injector nozzles with micro-holes (i.e. down to 30 μm), still need further investigation. Reduction of nozzle orifice diameter and increased fuel injection pressure typically promotes air entrainment near-nozzle during start of injection. This leads to better premixing and consequently leaner combustion, hence lowering the formation of soot. Advances in numerical simulation have made it possible to study the effect of different nozzle diameters on the spray and combustion in great detail. In this study, a baseline model was developed for investigating the spray and combustion of diesel fuel at the Spray A condition (nozzle diameter of 90 μm) from the Engine Combustion Network (ECN) community.
Technical Paper

Optimization of Heavy Duty Diesel Engine Lubricant and Coolant Pumps for Parasitic Loss Reduction

2018-04-03
2018-01-0980
As fuel economy becomes increasingly important in all markets, complete engine system optimization is required to meet future standards. In many applications, it is difficult to realize the optimum coolant or lubricant pump without first evaluating different sets of engine hardware and iterating on the flow and pressure requirements. For this study, a Heavy Duty Diesel (HDD) engine was run in a dynamometer test cell with full variability of the production coolant and lubricant pumps. Two test stands were developed to allow the engine coolant and lubricant pumps to be fully mapped during engine operation. The pumps were removed from the engine and powered by electric motors with inline torque meters. Each fluid circuit was instrumented with volume flow meters and pressure measurements at multiple locations. After development of the pump stands, research efforts were focused on hardware changes to reduce coolant and lubricant flow requirements of the HDD engine.
Technical Paper

Dilute Measurement of Semi-Volatile Organic Compounds (SVOC) from a Heavy-Duty Diesel Engine

2017-10-08
2017-01-2393
Semi-volatile organic compounds (SVOC) are a group of compounds in engine exhaust that either form during combustion or are part of the fuel and lubricating oil. Since these compounds occur at very low concentrations in diesel engine exhaust, the methods for sampling, handling, and analyzing these compounds are critical to obtaining good results. An improved dilute exhaust sampling method was used for sampling and analyzing SVOC in engine exhaust, and this method was performed during transient engine operation. A total of 22 different SVOC were measured using a 2012 medium-duty diesel engine. This engine was equipped with a stock diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst in series. Exhaust concentrations for SVOC were compared both with and without exhaust aftertreatment. Concentrations for the engine-out SVOC were significantly higher than with the aftertreatment present.
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