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Connected vehicles (CVs) have situational awareness that can be exploited for control and optimization of the powertrain system. While extensive studies have been carried out for energy efficiency improvement of CVs via eco-driving and planning, the implication of such technologies on the thermal responses of CVs (including those of the engine and aftertreatment systems) has not been fully investigated. One of the key challenges in leveraging connectivity for optimization-based thermal management of CVs is the relatively slow thermal dynamics, which necessitate the use of a long prediction horizon to achieve the best performance. Long-term prediction of the CV speed, unlike the short-range prediction based on vehicle-to-infrastructure (V2I) and vehicle-to-vehicle (V2V) communications-based information, is difficult and error-prone.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

Misfire is generally defined as be no or partial combustion during the power stroke of internal combustion engine. Because a misfired engine will dramatically increase the exhaust emission and potentially cause permanent damage to the catalytic converters, California Air Resources Board (CARB), as well as most of other countries’ on-board diagnostic regulations mandates the detection of misfire. Currently almost all the OEMs utilize crankshaft position sensors as the main input to their misfire detection algorithm. The detailed detection approaches vary among different manufacturers. For example, some chooses the crankshaft angular velocity calculated from the raw output of the crankshaft positon sensor as the measurement to distinguish misfires from normal firing events, while others use crankshaft angular acceleration or the associated torque index derived from the crankshaft position sensor readings as the measurement of misfire detection.

A three-way catalytic converter (TWC) is an emissions control device, used to treat the exhaust gases in a gasoline engine. The conversion efficiency of the catalyst, however, drops with age or customer usage and needs to be monitored on-line to meet the on board diagnostics (OBD II) regulations. In this work, a non-intrusive catalyst monitor is developed to diagnose the track the remaining useful life of the catalyst based on measured in-vehicle signals. Using air mass and the air-fuel ratio (A/F) at the front (upstream) and rear (downstream) of the catalyst, the catalyst oxygen storage capacity is estimated. The catalyst capacity and operating exhaust temperature are used as an input features for developing a Support Vector Machine (SVM) algorithm based classifier to identify a threshold catalyst. In addition, the distance of the data points in hyperspace from the calibrated threshold plane is used to compute the remaining useful life left.

Traditionally, a three-way catalyst (TWC) is controlled to a set heated exhaust gas oxygen (HEGO) sensor voltage (typically placed after the monitored catalyst) that corresponds to optimal catalyst efficiency. This limits the control action, as we rely on emissions breakthrough at the HEGO sensor to infer the state of catalyst. In order to robustly meet the super ultra-low emission regulations, a more precise TWC control around the oxidation level of catalyst is desirable. In this work, we developed a comprehensive set of models to predict the oxygen storage capacity using measured in-vehicle signals only. This is accomplished by developing three models; the first model is a linear in parameter regression model to predict the feed gas emissions from measured signals like engine speed and air-to-fuel ratio (A/F). The second model is a low-dimensional physics based model of the three-way catalyst to predict the exhaust emissions and oxidation state of the catalyst.

In the current paper, three dimensional fluid flow and pressure loss characteristics are investigated numerically for the geometry of a catalytic converter with two substrates inside. Various relative positions of two substrates are considered: air gap widths in the axial direction and different alignments of substrate's channels in the lateral direction. Studies are focused on the effects of those relative positions on flow uniformity inside both substrates and additional pressure loss through converter system. Under the same flow conditions and a constant air gap width, the stagger alignment in the lateral direction, shown in Fig. 1 (a), gives the highest additional pressure loss (pressure drop through air gap). Additional pressure loss drops with the increase of air gap width and reaches the lowest value at certain air gap width, then increases with the increases of gap width.

With concerns over increasing worldwide demand for gasoline and greenhouse gases, many automotive companies are increasing their product lineup of vehicles to include flex-fuel vehicles that are capable of operating on fuel blends ranging from 100% gasoline up to a blend of 15% gasoline/85% ethanol (E85). For the purpose of this paper, data was obtained that will enable an evaluation relating to the effect the use of E85 fuel has on exhaust system surface temperatures compared to that of regular unleaded gasoline while the vehicle undergoes a typical drive cycle. Three vehicles from three different automotive manufacturers were tested. The surface of the exhaust systems was instrumented with thermocouples at specific locations to monitor temperatures from the manifold to the catalytic converter outlet. The exhaust system surface temperatures were recorded during an operation cycle that included steady vehicle speed operation; cold start and idle and wide open throttle conditions.

The goal of the project was to reduce tailpipe-out hydrocarbon (HC) plus oxides of nitrogen (NOx) emissions to 50 percent or less of the current California Air Resources Board (CARB) useful life standard of 12 g/hp-hr for Class I engines, or 9 g/hp-hr for Class II engines. Low-emission engines were developed using three-way catalytic converters, passive secondary-air induction (SAI) systems, and in two cases, enleanment. Catalysts were integrated into the engine's mufflers, where feasible, to maintain a compact package. Due to the thermal sensitivity of these engines, carburetor calibrations were left unchanged in four of the six engines, at the stock rich settings. To enable HC oxidation under such rich conditions, a simple passive supplemental air injection system was developed. This system was then tuned to achieve the desired HC+NOx reduction.

The Environmental Protection Agency (EPA) and California Air Resources Board (CARB) requirements for high mileage durability of emission components make it necessary to ensure the mechanical robustness of metallic catalytic converters. In addition, the robustness of design features must be assessed in the early design development phase without resorting to vehicle fleet testing. By following established reliability methods, a new approach for time and cost efficient accelerated durability testing was developed, which can account for the combined effects of critical stressors of a metallic catalytic converter. This paper describes the methodology used to determine the critical stressors and their levels in actual operating conditions which were determined by analyzing a broad range of vehicle test information. This information was used to develop a temperature profile and a high vibration load profile for the new life test method.

An experimental study of the acoustic characteristics of automotive catalytic converters is presented. The investigation addresses the effects and relative importance of the elements comprising a production catalytic converter assembly including the housing, substrate, mat and seals. Attenuation characteristics are measured for one circular and one oval catalytic converter geometry, each having 400 cell per square inch substrates. For each geometry, experimental results are presented to address the effect of individual components in isolation, and in combination with other assembly components. Additional experiments investigate the significance of acoustic paths around the substrate and through the peripheral wall of the substrate. The experimental results are compared to address the significance of each component on the overall attenuation.

Automotive catalytic converters must provide a very high level of mechanical and thermal durability to maintain performance during their 100,000 to 150,000 mile life expectancy. The work reported herein characterizes the converter as a base (can) excited spring (mat material) supported mass (substrate). A mat material coupon test apparatus was developed for the purpose of providing parameter data for the converter model in the form of stiffness and material loss factor data as a function of shear deflection across the mat. An intumescent mat material was chosen and its dynamic properties evaluated for a range of converter operating parameters. The mat material response properties were placed into a mat material database as a function of gap bulk density, substrate temperature, and temperature gradient across the mat.

Recent internal research performed at SwRI examined an emissions control mechanism that we have labeled, ‘phased A/F perturbation.’ The suggested mechanism of phased perturbation involves independently controlling the fuel delivered to each bank of a dual bank engine, which allows the two banks to have an adjustable, relative A/F perturbation phase-shift from one another. Exhaust from the two banks can be combined to achieve a near-stoichiometric mixture prior to entering a single underbody catalyst. Since both rich and lean exhaust species would be present simultaneously, a highly reactive mixture would continuously enter the catalyst. In that work, it was found that A/F phasing produced as significant an effect on conversion efficiency as perturbation amplitude and frequency, i.e. A/F phasing was identified as a third dimension for optimization of exhaust gas composition as it enters the catalyst.

This paper describes an on-vehicle demonstration of a hydrogen-heated catalyst (HHC) system for reducing the level of cold-start hydrocarbon emissions from a gasoline-fueled light-duty vehicle. The HHC system incorporated an onboard electrolyzer that generates and stores hydrogen (H2) during routine vehicle operation. Stored hydrogen and supplemental air are injected upstream of a platinum-containing automotive catalyst when the engine is started. Rapid heating of the catalytic converter occurs immediately as a result of catalytic oxidation of hydrogen (H2) with oxygen (O2) on the catalyst surface. Federal Test Procedure (FTP) emission results of the hydrogen-heated catalyst-equipped vehicle demonstrated reductions of hydrocarbons (HC) and carbon monoxide (CO) up to 68 and 62 percent, respectively. This study includes a brief analysis of the emissions and fuel economy effects of a 10-minute period of hydrogen generation during the FTP.

A typical automotive catalytic converter is constructed with a ceramic substrate and a steel shell. Due to a mismatch in coefficients of thermal expansion, the steel shell will expand away from the ceramic substrate at high temperatures. The gap between the substrate and shell is usually filled with a fiber composite material referred to as “mat.” Mat materials are compressed during assembly and must maintain an adequate pressure around the substrate under extreme temperature conditions. The container deformation measurement procedure is used to determine catalytic converter shell expansion during and after a period of hot catalytic converter operation. This procedure is useful in determining the potential physical durability of a catalytic converter system, and involves measuring converter shell expansion as a function of inlet temperature. A post-test dimensional measurement is used to determine permanent container deformation.

An increasing number of passenger vehicle exhaust systems incorporate catalytic converters that are “close-coupled” to the exhaust manifold to further reduce the quantity of cold-start emissions and increase overall catalyst conversion efficiencies. In general, close-coupled catalytic converters are not necessarily subjected to higher inlet exhaust temperatures than conventional underbody catalytic converters. To establish a foundation of on-vehicle temperature data, several passenger vehicles with close-coupled catalytic converters were studied while operating on a chassis dynamometer. Converter temperatures were measured over a variety of vehicle test conditions, including accelerations and extended steady-state speeds for several throttle positions, at both zero- and four-percent simulated road grades.

To aid in the catalytic converter design and development process, a test apparatus was designed and built which will allow comparative evaluation of the durability of candidate mat materials under highly controlled thermal and vibration environments. The apparatus directly controls relative shear deflection between the substrate and can to impose known levels of mat material strain while recording the transmitted shear force across the mat material. Substrate and can temperatures are controlled at constant levels using a resistive thermal exposure (RTE) technique. Mat material fatigue after several million cycles is evident by a substantial decrease in the transmitted force. A fragility test was found to be an excellent method to quickly compare candidate materials to be used for a specific application. Examples of test results from several materials are given to show the utility of the mat material evaluation technique.

In order to further reduce vehicle cold-start emissions, the use of catalytic converters that are “close-coupled” to the exhaust manifold is increasing. To understand the vibrational environment of close-coupled and underbody converters, a laboratory study was conducted on several passenger vehicles. Catalytic converter vibration spectra were measured on a chassis dynamometer with the vehicle operating over a variety of test conditions. Vehicle operating conditions included hard accelerations and extended steady-state speeds at distinct throttle positions over zero-percent and four-percent simulated road grades.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

Proposed emissions standards will require that emissions control systems function at extremely high efficiency. Recently, studies have shown that elevated gasoline fuel sulfur levels (GFSL) can impair catalytic converter efficiency. In this study, a variety of tri-metal catalysts were evaluated to determine if formulation changes could reduce emissions sensitivity to GFSL. Catalysts with elemental composition similar to an OEM, but with double the precious metal (PM) loading, were evaluated using 38 and 620 ppm GFSL. Doubling the PM loading significantly reduced catalyst sensitivity to sulfur. Doubling the rhodium loading, at the expense of the platinum loading, significantly improved NOx emission sulfur sensitivity.

The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.