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In this study, engine-out gaseous emissions are reviewed using the Fourier Transform Infrared (FTIR) spectroscopy measurement of methanol diesel dual fuel combustion experiments performed in a heavy-duty diesel engine. Comparison to the baseline diesel-only condition shows that methanol-diesel dual fuel combustion leads to higher regulated carbon monoxide (CO) emissions and unburned hydrocarbons (UHC). However, NOX emissions were reduced effectively with increasing methanol substitution rate (MSR). Under dual-fuel operation with methanol, emissions of nitrogen oxides (NOX), including nitric oxide (NO), nitrogen dioxide (NO2), and nitrous oxide (N2O), indicate the potential to reduce the burden of NOX on diesel after-treatment devices such as selective catalytic reduction (SCR).

Southwest Research Institute has developed a passive, flow-through, membrane which separates carbon dioxide (CO2) from other exhaust gas species. Stoichiometric exhaust gas for 0% ethanol fuels contain approximately 14% CO2 by concentration. The membrane consists of a ceramic substrate impregnated with lithium zirconate (Li2ZrO3). In the presence of temperatures of 400-600 °C the CO2 reacts with lithium zirconate to form lithium carbonate (Li2CO3). The new compound moves from the inner surface of the membrane via partial pressure gradient to the outer wall of the membrane and desorbs into a low concentration CO2 environment, e.g. atmospheric air with 400 ppm CO2. SwRI has tested the membrane under engine-like conditions, comparable to 2000 rpm 10 bar BMEP operation, on a standalone burner rig (ECTO-lab burner). On the SwRI ECTO-lab burner rig temperature, flow-rate and exhaust gas products can be independently varied.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

A recent collaborative research project between Southwest Research Institute® (SwRI®) and the University of Texas at San Antonio (UTSA) has demonstrated that a ruthenium (Ru) catalyst is capable of converting oxides of nitrogen (NOX) emissions to nitrogen (N2) with high activity and selectivity. Testing was performed on coated cordierite ceramic cores using SwRI’s Universal Synthetic Gas Reactor® (USGR®). Various gas mixtures were employed, from model gas mixes to full exhaust simulant gas mixes. Activity was measured as a function of temperature, and gaseous inhibitors and promoters were identified. Different Ru supports were tested to identify ones with lowest temperature activity. A Ru catalyst can be used in the exhaust gas recirculation (EGR) leg of a Dedicated-EGR (D-EGR) engine [1,2], where it uses carbon monoxide (CO) and hydrogen (H2) present in the rich gas environment to reduce NOX to N2 with 100% efficiency and close to 100% selectivity to N2.

Southwest Research Institute (SwRI) has successfully demonstrated the cooled EGR concept via the High Efficiency Dilute Gasoline Engine (HEDGE) consortium. Dilution of intake charge provides three significant benefits - (1) Better Cycle Efficiency (2) Knock Resistance and (3) Lower NOx/PM Emissions. But EGR dilution also poses challenges in terms of combustion stability, condensation and power density. The Dedicated EGR (D-EGR) concept brings back some of the stability lost due to EGR dilution by introducing reformates such as CO and H2 into the intake charge. Control of air, EGR, fuel, and ignition remains a challenge to realizing the aforementioned benefits without sacrificing performance and drivability. This paper addresses the DEGR solution from a controls standpoint. SwRI has been developing a unified framework for controlling a generic combustion engine (gasoline, diesel, dual-fuel natural gas etc.).

There are numerous off-road diesel engine applications. In some applications there is more focus on metrics such as initial cost, packaging and transient response and less emphasis on fuel economy. In this paper a combustion concept is presented that may be well suited to these applications. The novel combustion concept operates in two distinct operation modes: lean operation at light engine loads and stoichiometric operation at intermediate and high engine loads. One advantage to the two mode approach is the ability to simplify the aftertreatment and reduce cost. The simplified aftertreatment system utilizes a non-catalyzed diesel particulate filter (DPF) and a relatively small lean NOx trap (LNT). Under stoichiometric operation the LNT has the ability to act as a three way catalyst (TWC) for excellent control of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx).

In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.

The presented work describes how spark calorimeter testing was used for parametric study and secondary circuit model calibration. Tests were conducted at different pressures, sparkplug gaps and supplied primary energies. The conversion efficiency increases and the spark duration decreases when the gas pressure or the sparkplug gap size is increased. Both gas pressure and sparkplug gas size increase the positive column voltage which represents part of the electrical energy delivered to the gas. The opposite direction occurs when the supplied primary energy is increased. The testing results were then used to calibrate the secondary circuit model which consisted of the sparkplug, the sparkplug gap and the secondary wiring. A step-by-step method was used to calibrate the three constants of the model to match the calculated delivered energy with test data during arc / glow phase.

A novel oxygenate, 5-methyl furoate ethyl ester (EF), was made by a chemical process from biomass and ethanol. This compound was then used as a renewable diesel additive at concentrations up to 10 percent by volume. This unique ester, which is similar in composition to a know food additive, was studied for engine performance in comparison with two other oxygenated alternatives (i.e. ethanol - EtOH and ethyl levulinate - EL) and with B20 (20 percent biodiesel). Tests were performed with a 2012 6.7 L Ford diesel engine using the heavy-duty Federal Test Procedure. The emission results indicated that a blend of the ester with diesel was comparable to the base fuel. In addition, the results also indicated that EF reduces the formation of particulate matter (PM) and carbon monoxide. Other properties of EF seem to improve the physical properties of the blended fuel such as lubricity and viscosity when compared to the base fuel.

This paper covers work performed for the California Air Resources Board and US Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on four in-use off-road two-stroke motorcycles and all-terrain vehicles utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.

The objective of this project was to assess the effects of various blends of biodiesel on locomotive engine exhaust emissions. Systematic, credible, and carefully designed and executed locomotive fuel effect studies produce statistically significant conclusions are very scarce, and only cover a very limited number of locomotive models. Most locomotive biodiesel work has been limited to cursory demonstration programs. Of primary concern to railroads and regulators is understanding any exhaust emission associated with biodiesel use, especially NOX emissions. In this study, emissions tests were conducted on two locomotive models, a Tier 2 EMD SD70ACe and a Tier 1+ GE Dash9-44CW with two baseline fuels, conventional EPA ASTM No. 2-D S15 (commonly referred to as ultra-low sulfur diesel - ULSD) certification diesel fuel, and commercially available California Air Resource Board (CARB) ULSD fuel.

The addition of exhaust gas recirculation (EGR) has demonstrated the potential to significantly improve engine efficiency by allowing high CR operation due to a reduction in knock tendency, heat transfer, and pumping losses. In addition, EGR also reduces the engine-out emission of nitrogen oxides, particulates, and carbon monoxide while further improving efficiency at stoichiometric air/fuel ratios. However, improvements in efficiency through enhanced combustion phasing at high compression ratios can result in a significant increase in cylinder pressure. As cylinder pressure and temperature are both important parameters for estimating the durability requirements of the engine - in effect specifying the material and engineering required for the head and block - the impact of EGR on surface temperatures, when combined with the cylinder pressure data, will provide an important understanding of the design requirements for future cylinder heads.

Enhancement of fuel/air mixing is one path towards enabling future diesel engines to increase efficiency and control emissions. Air-assist fuel injections have shown potential for low pressure applications and the current work aims to extend air-assist feasibility understanding to high pressure environments. Analyses were completed and carried out for traditional high pressure fuel-only, internal air-assist, and external air-assist fuel/air mixing processes. A combination of analytical 0-D theory and 3D CFD were used to help understand the processes and guide the design of the air-assisted setup. The internal air-assisted setup was determined to have excellent liquid fuel vaporization, but poorer fuel dispersion than the traditional high-pressure fuel injections.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.

Total and solid particle mass, size, and number were measured in the dilute exhaust of a 2009 vehicle equipped with a gasoline direct injection engine along with an exhaust three-way-catalyst. The measurements were performed over the FTP-75 and the US06 drive cycles using three different U.S. commercially available fuels, Fuels A, B, and C, where Fuel B was the most volatile and Fuel C was the least volatile with higher fractions of low vapor pressure hydrocarbons (C10 to C12), compared to the other two fuels. Substantial differences in particle mass and number emission levels were observed among the different fuels tested. The more volatile gasoline fuel, Fuel B, resulted in the lowest total (solid plus volatile) and solid particle mass and number emissions. This fuel resulted in a 62 percent reduction in solid particle number and an 88 percent reduction in soot mass during the highest emitting cold-start phase, Phasel, of the FTP-75, compared to Fuel C.

Work was performed to determine the feasibility of operating heavy-duty natural gas engines over a wide range of fuel compositions by evaluating engine performance and emission levels. Heavy-duty compressed natural gas engines from various engine manufacturers, spanning a range of model years and technologies, were evaluated using a diversity of fuel blends. Performance and regulated emission levels from these engines were evaluated using natural gas fuel blends with varying methane number (MN) and Wobbe Index in a dynamometer test cell. Eight natural gas blends were tested with each engine, and ranged from MN 75 to MN 100. Test engines included a 2007 model year Cummins ISL G, a 2006 model year Cummins C Gas Plus, a 2005 model year John Deere 6081H, a 1998 model year Cummins C Gas, and a 1999 model year Detroit Diesel Series 50G TK. All engines used lean-burn technology, except for the ISL G, which was a stoichiometric engine.

An investigation was performed to identify the benefits of cooled exhaust gas recirculation (EGR) when applied to a potential ethanol flexible fuelled vehicle (eFFV) engine. The fuels investigated in this study represented the range a flex-fuel engine may be exposed to in the United States; from 85% ethanol/gasoline blend (E85) to regular gasoline. The test engine was a 2.0-L in-line 4 cylinder that was turbocharged and port fuel injected (PFI). Ethanol blended fuels, including E85, have a higher octane rating and produce lower exhaust temperatures compared to gasoline. EGR has also been shown to decrease engine knock tendency and decrease exhaust temperatures. A natural progression was to take advantage of the superior combustion characteristics of E85 (i.e. increase compression ratio), and then employ EGR to maintain performance with gasoline. When EGR alone could not provide the necessary knock margin, hydrogen (H2) was added to simulate an onboard fuel reformer.

In-cylinder emission controls were the focus for diesel engines for many decades before the emergence of diesel aftertreatment. Even with modern aftertreatment, control of in-cylinder processes remains a key issue for developing diesel vehicles with low tailpipe emissions. A reduction in in-cylinder emissions makes aftertreatment more effective at lower cost with superior fuel economy. This paper describes a study focused on an in-cylinder combustion control approach using a Delphi E3 flexible fuel system to achieve low engine-out NOx and PM emissions. A 2003 model year Detroit Diesel Corporation Series 60 14L heady-duty diesel engine, modified to accept the Delphi E3 unit injectors, and ultra low sulfur fuel were used throughout this study. The process of achieving premixed low temperature combustion within the limited range of parameters of the stock ECU was investigated.

A gasoline direct injection engine was operated at elevated EGR levels over a significant portion of the performance map. The engine was modified to use both cooled and un-cooled EGR in high pressure loop and low pressure loop configurations. The addition of EGR at low and part load was shown to decrease NO and CO emissions and to reduce fuel consumption by up to 4%, primarily through the reduction in pumping losses. At high loads, the addition of EGR resulted in higher fuel consumption benefits of 10-20% as well as the expected NO and CO reductions. The fuel economy benefit at high loads resulted from a decrease in knock tendency and a subsequent improvement in combustion phasing as well as reductions in exhaust temperatures that eliminated the requirement for over-fuelling.