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Adding oxygenates to diesel fuel has shown the potential for reducing particulate (PM) emissions in the exhaust. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for advanced engine testing. A fuel matrix was designed to consider the effect of molecular structure and boiling point on the ability of oxygenates to reduce engine-out exhaust emissions from a modern diesel engine. Nine test fuels including a low-sulfur (∼1 ppm), low-aromatic hydrocracked base fuel and 8 oxygenate-base fuel blends were utilized. All oxygenated fuels were formulated to contain 7% wt. of oxygen. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. The base fuel was evaluated in four speed-load modes and oxygenated blends only in one mode. Each operating mode and fuel combination was run in triplicate.

Heating neat (100 percent) methanol fuel (M100) is shown to improve dramatically the atomization of the fuel from a production, automotive, port fuel injector of pintle design. This improvement is particularly noticeable and important when compared with atomization at low fuel temperatures, corresponding to those conditions where cold-start is a significant problem with neat methanol-fueled (M100) vehicles. The improved atomization is demonstrated with photographs and laser-diffraction measurements of the drop-size distributions. Fuel temperatures were varied from -34°C (-29°F to 117°C (243°F), while the boiling point of methanol is 64.7°C (148.5°F). Air temperatures were ambient at about 24°C (75°F). For temperatures above the boiling point, some flash boiling and vaporization were presumably occurring, and these may have contributed to the atomization, but the trends for drop size did not shown any discontinuity near the boiling point.