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Engine knock is one of the limiting factors in determining the compression ratio and engine efficiency for spark ignited engines. Using the Southwest Research Institute Knock-CoV test method, it was previously shown that the knock limited load versus combustion phasing (CA50) has a constant slope. All of the knock mitigation strategies tested provided a shift to these knock limited loads but also increased the slope. That is, for the same CA50 retard the knock limited load could be increased more. Our hypothesis was that due to fuel sensitivity, or the difference between the RON and MON, the reactions that lead to knock will behave differently as the pressure-temperature history changes with engine speeds and loads. The fuel affects on the knock and CoV limits were studied by testing fuels with various sensitivities including methanol, E85 (85% ethanol) and Iso-octane.

The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.

Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.

1Increasing adoption of downsized, boosted, spark-ignition engines has improved vehicle fuel economy, and continued improvement is desirable to reduce carbon emissions in the near-term. However, this strategy is limited by damaging preignition events which can cause hardware failure. Research to date has shed light on various contributing factors related to fuel and lubricant properties as well as calibration strategies, but the causal factors behind an individual preignition cycle remain elusive. If actionable precursors could be identified, mitigation through active control strategies would be possible. This paper uses artificial neural networks to search for identifiable precursors in the cylinder pressure data from a large real-world data set containing many preignition cycles. It is found that while follow-up preignition cycles in clusters can be readily predicted, the initial preignition cycle is not predictable based on features of the cylinder pressure.

Dedicated-EGR™ (D-EGR™) is a concept where the exhaust of one dedicated cylinder (D-Cyl) is routed into the intake thus producing EGR to be used by the whole engine. The D-Cyl operates rich of stochiometric which produces syngas that enhances the EGR stream permitting faster combustion and greater knock mitigation. Operating an engine using D-EGR improves the knock resistance which can permit a higher compression ratio (CR) thereby increasing efficiency. One challenge of traditional D-EGR is that the D-Cyl combustion becomes unstable operating with both rich and EGR dilute conditions. Therefore, the ‘Split Intake D-EGR’ concept seeks to resolve this problem by feeding fresh air to the D-Cyl, thus allowing even richer operation in the D-Cyl which further increases the H2 and CO yield thereby enhancing the efficiency benefits.

The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.

The automotive sector is rapidly transitioning to decarbonized, electric vehicles solutions. However, due to challenges with such rapid adoption, Internal combustion engines (ICE) are expected to be used for decades to come. In this transition period it is important to continue to improve ICE efficiency. A key design parameter to increase ICE efficiency is the compression ratio. For gasoline engines, the compression ratio is limited so as to avoid knock. Engine designers can employ several strategies to mitigate knock and enable higher compression ratios. In this study, a new methodology has been developed to compare various knock mitigation strategies. By comparing the knock limited load at a given combustion phasing the expected compression ratio increase can be inferred.

This project’s objective was to generate experimental data to evaluate the impact of metals doped B20 on diesel particle filter (DPF) ash loading and performance compared to that of conventional petrodiesel. The effect of metals doped B20 vs. conventional diesel on a DPF was quantified in a laboratory controlled accelerated ash loading study. The ash loading was conducted on two DPFs – one using ULSD fuel and the other on B20 containing metals dopants equivalent to 4 ppm B100 total metals. Engine oil consumption and B20 metals levels were accelerated by a factor of 5, with DPFs loaded to 30 g/L of ash. Details of the ash loading experiment and on-engine DPF performance evaluations are presented in the companion paper (Part I). The DPFs were cleaned, and ash samples were taken from the cleaned material. X-ray Fluorescence (XRF), X-Ray Photoelectron Spectroscopy (XPS) and X-Ray Diffraction (XRD) were conducted on the ash samples.

The project objective was to generate experimental data to evaluate the impact of metals doped B20 on DPF ash loading and performance compared to that of conventional petrodiesel. Accelerated ash loading was conducted on two DPFs – one exposed to regular diesel fuel and the other to B20 containing metal dopants equivalent to 4 ppm B100 total metals (currently total metals are limited to 10 ppm in ASTM D6751, the standard for B100). Periodic performance evaluations were conducted on the DPFs at 10 g/L ash loading intervals. After the evaluations at 30 g/L, the DPF was cleaned with a commercial DPF cleaning machine and another round of DPF evaluations were conducted. A comparison of the effect of ash loading with the two fuels and DPF cleaning is presented. The metals doped B20 fuel resulted in ash that was similar to that deposited when exposed to ULSD (lube oil ash) and exhibited similar ash cleaning removal efficiency.

Stoichiometric natural gas engines with three-way catalysts emit less NOx and CH4 due to their higher efficiency compared to lean-burn natural gas engines. Although hydrothermal aging of three-way catalysts has been extensively studied, a deeper understanding beyond hydrothermal aging is needed to explain real-world performance, especially for natural gas engines with near-zero NOx emissions. In this investigation, field-aged three-way catalysts were characterized to identify the contribution of chemical aging to their overall performance. It was found that the sulfur species on the field-aged TWCs were entirely distributed along the catalyst length, showing a decreasing trend, whereas phosphorous contamination was mainly observed at the inlet section of the three-way catalysts, and the phosphorous concentration declined sharply along the axial length.

As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.

Internal combustion engines (ICE) will be a part of personal transportation for the foreseeable future. One recent trend for engines has been downsizing which enables the engine to be run more efficiently over regulatory drive cycles. Due to downsizing, engine power density has increased which leads to problems with engine knock. Therefore, there is an increasing need to find a means to reduce the knock propensity of downsized engines. One of the ways of reducing knock propensity is by introducing Exhaust Gas Recirculation (EGR) into the combustion chamber, however, volumetric efficiency also reduces with EGR which places challenges on the boosting system. The individual benefits of high-pressure (HP-EGR) and low-pressure (LP-EGR) loop EGR system to assist the boosting system of a 2.0 L Gasoline Direct Injection (GDI) production engine are explored in this paper.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.

Particulate matter (PM) and NOX are two major pollutants generated by diesel engines. Modern diesel aftertreatment systems include selective catalytic reduction (SCR) technology that helps reduce tailpipe NOX emissions when coupled with diesel exhaust fluid (DEF/urea) injection. However, this process also results in the formation of urea derived byproducts that can influence non-volatile particle number (PN) measurement conducted in accordance with the European Union (EU) Particle Measurement Program (PMP) protocol. In this program, an experimental investigation of the impact of DEF injection on tailpipe PN and its implications for PMP compliant measurements was conducted using a 2015 model year 6.7 L diesel engine equipped with a diesel oxidation catalyst, diesel particulate filter and SCR system. Open access to the engine controller was available to manually override select parameters.

Euro VI regulations in Europe and its adaptors recently extended the regulation to include Particle Number (PN) for in-use conformity testing. However, the in-use PN Portable Emissions Measurement System (PEMS) is still evolving and has higher measurement uncertainty when compared against laboratory-grade PN systems. The PN systems for laboratory require a condensation particle counter (CPC). Thus, in this study, a CPC-based Horiba PN-PEMS was selected for performance evaluation against the laboratory-grade PN systems. This study was divided into four phases. The first two phases’ measurements were conducted from the Constant Volume Sampler (CVS) tunnel where the brake-specific particle number (BSPN) levels of 1010-12 and 1013 (#/bhp-h) were measured from the engines equipped with diesel particulate filter (DPF) and without DPF, respectively. In comparison against PN systems, PN-PEMS, on average, reported 14% lower BSPN from 82 various tests for the BSPN levels of 1010-11.

The confluence of increasing fuel economy requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits of higher octane numbers and high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were prepared with varying composition, octane numbers and ethanol blend levels. The paper reports on the third part of this study where cylinder pressures were recorded for fuels under knocking conditions in both a single-cylinder research engine (SCE), utilizing a GM LHU head and piston, as well as the CFR engines used for octane ratings.

It is widely acknowledged that the CFR octane rating engines are not representative of modern engines and that there is a gap in the quantification of knock severity between the two engine types. As part of a comprehensive study of the autoignition of different fuels in both the CFR octane rating engines and a modern, direct injection, turbocharged spark-ignited engine, a series of fuel blends were tested with varying composition, octane numbers and ethanol blend levels. The paper reports on the fourth part of this study where cylinder pressures were recorded under standard knock conditions in CFR engines under RON and MON conditions using the ASTM prescribed instrumentation. By the appropriate signal conditioning of the D1 detonation pickups on the CFR engines, a quantification of the knock severity was possible that had the same frequency response as a cylinder pressure transducer.

As agencies and governing bodies evaluate the feasibility of reduced emission standards, additional focus has been placed on technology durability. This is seen in proposed updates, which would require Original Equipment Manufacturers (OEMs) to certify engine families utilizing a full useful life (FUL) aftertreatment system. These kinds of proposed rulings would place a heavy burden on the manufacturer to generate FUL components utilizing traditional engine aging methods. Complications in this process will also increase the product development effort and will likely limit the amount of aftertreatment durability testing. There is also uncertainty regarding the aging approach and the representative impact compared to field aged units. Existing methodologies have evolved to account for several deterioration mechanisms that, when controlled, can be utilized to create a flexible aging protocol. As a result, these methodologies provide the necessary foundation for continued development.

California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.