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Technical Paper

PN-Emissions of Gasoline Cars MPI and Potentials of GPF

2018-04-03
2018-01-0363
Further efforts to reduce the air pollution from traffic are undertaken worldwide and the filtration of exhaust gas will also be increasingly applied on gasoline cars (GPF1 … gasoline particle filter). In the present paper, some results of investigations of nanoparticles from four MPI gasoline cars are represented. The measurements were performed at vehicle tailpipe and in CVS-tunnel. Moreover, two variants of GPF were investigated on a high-emitting modern vehicle, including analytics of PAH and attempts of soot loading in road application. The modern MPI vehicles can emit a considerable amount of PN, which in some cases attains the level of Diesel exhaust gas without DPF and can pass over the actual European limit value for GDI (6.0 x 1011 #/km). The GPF-technology offers in this respect further poten-tials to reduce the PN-emissions of traffic.
Technical Paper

Nanoparticle Emissions of DI Gasoline Cars with/without GPF

2017-03-28
2017-01-1004
In the present paper some results of investigations of nanoparticles from five DI gasoline cars are represented. The measurements were performed at vehicle tailpipe and in CVS-tunnel. Moreover, five variants of “vehicle - GPF” were investigated. These results originate from the project GasOMeP (Gasoline Organic & Metal Particulates), which focused on metal-nanoparticles (including sub 20nm) from gasoline cars with different engine technologies. The PN-emission level of the investigated GDI cars in WLTC without GPF is in the same range of magnitude very near to the actual limit value of 6.0 × 1012 #/km. With the GPF’s with better filtration quality, it is possible to lower the emissions below the future limit value of 6.0 × 1011 #/km. There is no visible nuclei mode and the ultrafine particle concentrations below 10mm are insignificant. Some of the vehicles show at constant speed operation a periodical fluctuation of the NP-emissions, as an effect of the electronic control.
Technical Paper

Semi-Empirical 0D Modeling for Engine-Out Soot Emission Prediction in D.I. Diesel Engines

2016-04-05
2016-01-0562
Due to its harmful effect on both human health and environment, soot emission is considered as one of the most important diesel engine pollutants. In the last decades, the industrial engine manufacturers have been able to strongly reduce its engine-out value by many different techniques, in order to respect the stricter emission norms. Simulation modeling has played and continues to play a key role for this purpose in the engine control system development. In this context, this paper proposes a new soot emission model for a direct injection diesel engine. This soot model is based on a zero-dimensional semi-physical approach coupled with a crank-angle resolved combustion model and a thermodynamic calculation of the burned gas products temperature. Furthermore, a multi linear regression model has been used to estimate the soot emissions as function of significant physical combustion parameters.
Technical Paper

Compressor Efficiency Extrapolation for 0D-1D Engine Simulations

2016-04-05
2016-01-0554
0D-1D codes allow researchers to obtain a prediction of the behavior of internal combustion engines with little computational effort. One of the submodels of such codes is devoted to the centrifugal compressor. This model is often based on the compressor performance maps, therefore requiring the extrapolation of the maps so that all possible operating conditions are covered. Particularly, a suitable extrapolation of isentropic efficiency map is sought. This work first examines different available methods for compressor efficiency extrapolation into off-design conditions. No method is found to provide satisfactory results at all extrapolated regions: low and high compressor speeds and low compression ratio at measured speeds. Hence, a new method is proposed and its accuracy is assessed with the aid of compressor off-design measurements.
Journal Article

Investigation on Multiple Injection Strategies for Gasoline PPC Operation in a Newly Designed 2-Stroke HSDI Compression Ignition Engine

2015-04-14
2015-01-0830
Partially Premixed Combustion (PPC) of fuels in the gasoline octane range has proven its potential to achieve simultaneous reduction in soot and NOX emissions, combined with high indicated efficiencies; while still retaining proper control over combustion phasing with the injection event, contrary to fully premixed strategies. However, gasoline fuels with high octane number as the commonly available for the public provide a challenge to ensure reliable ignition especially in the low load range, while fuel blends with lower octane numbers present problems for extending the ignition delay in the high load range and avoid the onset of knocking-like combustion. Thus, choosing an appropriate fuel and injection strategy is critical to solve these issues, assuring successful PPC operation in the full engine map.
Journal Article

Development and Validation of a New Zero-Dimensional Semi-Physical NOx Emission Model for a D.I. Diesel Engine Using Simulated Combustion Process

2015-04-14
2015-01-1746
Reducing NOx tailpipe emissions is one of the major challenges when developing automotive Diesel engines which must simultaneously face stricter emission norms and reduce their fuel consumption/CO2 emission. In fact, the engine control system has to manage at the same time the multiple advanced combustion technologies such as high EGR rates, new injection strategies, complex after-treatment devices and sophisticated turbocharging systems implemented in recent diesel engines. In order to limit both the cost and duration of engine control system development, a virtual engine simulator has been developed in the last few years. The platform of this simulator is based on a 0D/1D approach, chosen for its low computational time. The existing simulation tools lead to satisfactory results concerning the combustion phase as well as the air supply system. In this context, the current paper describes the development of a new NOx emission model which is coupled with the combustion model.
Technical Paper

Investigations of SDPF -Diesel Particle Filter with SCR Coating for HD-Applications

2015-04-14
2015-01-1023
Diesel exhaust gas aftertreatment systems, which include the selective catalytic reduction (SCR)*) for reduction of NOx are necessary to fulfil the latest legal requirements and are extensively used in the heavy duty (HD) sector. The present paper informs about some results obtained with SCR and with SDPF (a DPF with SCR-coating) on a medium duty research engine Iveco F1C. Beside the limited gaseous emission components NH3, NO2 and N2O were measured. The analysis of nanoparticle emissions was performed with SMPS and CPC. The integration of functions of filtration and NOx-reduction in one element of exhaust aftertreatment system offers several advantages and is widely investigated and considered as a market solution.
Technical Paper

Experiences from Nanoparticle Research on Four Gasoline Cars

2015-04-14
2015-01-1079
The invisible nanoparticles (NP)*) from combustion processes penetrate easily into the human body through the respiratory and olfactory pathways and carry numerous harmful health effects potentials. NP count concentrations are limited in EU for Diesel passenger cars since 2013 and for gasoline cars with direct injection (GDI) since 2014. The limit for GDI was temporary extended to 6 × 1012 #/km, (regulation No. 459/2012/EU). Nuclei of metals as well as organics are suspected to significantly contribute especially to the ultrafine particle size fractions, and thus to the particle number concentration. In the project GasOMeP (Gasoline Organic & Metal Particulates) metal-nanoparticles (including sub 20nm) from gasoline cars are investigated for different engine technologies. In the present paper some results of investigations of nanoparticles from four gasoline cars - an older one with MPI and three newer with DI - are represented.
Technical Paper

VERTdePN Quality Test Procedures of DPF+SCR Systems

2014-04-01
2014-01-1579
The combined exhaust gas aftertreatment systems (DPF+SCR) are the most efficient way and the best available technology (BAT) to radically reduce the critical Diesel emission components particles (PM&NP) and nitric oxides (NOx). SCR (selective catalytic reduction) is regarded as the most efficient deNOx-system, diesel particle filters are most efficient for soot abatement. Today, several suppliers offer combined systems for retrofitting of HD vehicles. Quality standards for those quite complex systems and especially for retrofit systems are needed to enable decisions of several authorities and to estimate the potentials of improvements of the air quality in highly populated agglomerations. The present paper informs about the VERTdePN *) quality test procedures, which were developed in an international network project with the same name 2007-2011 (VERT … Verification of Emission Reduction Technologies; dePN … decontamination, disposal of PM / NP and of NOx).
Technical Paper

Testing of SCR-Systems on HD-Vehicles-TeVeNOx

2014-04-01
2014-01-1569
The selective catalytic reduction SCR is extensively used for NOx reduction of recent HD-vehicles. There are some manufacturers and some applications of SCR as retrofit systems (mostly for the low emission zones LEZ and in combination with a DPF). In charge of Swiss authorities AFHB investigated several SCR-systems, or (DPF+SCR)-systems on HD-vehicles and proposed a simplified quality test procedure of those systems. This procedure can especially be useful for the admission of retrofit systems but it can also be helpful for the quality check of OEM-systems. The project name was TeVeNOx - Testing of Vehicles with NOx reduction systems. In the present paper the test procedures will be described and some specific results will be discussed.
Technical Paper

NO2-Formation in Diesel Particle Filter Systems

2013-04-08
2013-01-0526
NO₂ is much more toxic than NO. The average proportion of NO₂ in exhaust gases of vehicles increases significantly due to the use of oxidation catalysts and catalytic coatings in the exhaust gas systems during the last decades combined with generalization of using low sulfur fuels. Diesel oxidation catalysts (DOC) and Pt-containing DPF coatings are widely used to support the regeneration of particle filters, being a source of strongly increased production of NO₂. The present work shows some examples and summarizes the experiences in this matter performed at the Laboratories for IC-Engines & Exhaust Emissions Control (AFHB) of the University of Applied Sciences Biel-Bienne, Switzerland, during some research activities on engine dynamometers in the years 2010-2012.
Technical Paper

Diesel Emissions with DPF & SCR and Toxic Potentials with BioDiesel (RME) Blend Fuels

2013-04-08
2013-01-0523
The use of alternative fuels and among them the biofuels of 1st generation - fatty acid methyl esters FAME's and pure plants oils - for propulsion of IC engines is an important objective in several countries in order to save the fossil fuels and to limit the CO₂ production. The properties of bio-fuels and bio-blend-fuels can vary and this has an impact on the operation and emissions of diesel engines and on the modern exhaust aftertreatment systems. The present paper represents the most important results obtained with RME at AFHB, EMPA and EC-JRC. Most of the activities were performed in the network project BioExDi (Biofuels, Exhaust Systems Diesel) in collaboration between industry and research institutes.
Technical Paper

The Potential of Highly Premixed Combustion for Pollutant Control in an Automotive Two-Stroke HSDI Diesel Engine

2012-04-16
2012-01-1104
An innovative alternative to overcome the load limits of the early injection highly premixed combustion concept consists of taking advantage of the intrinsic characteristics of two-stroke engines, since they can attain the full load torque of a four-stroke engine as the addition of two medium load cycles, where the implementation of this combustion concept could be promising. In this frame, the main objective of this investigation focuses on evaluating the potential of the early injection HPC concept using a conventional diesel fuel combined with a two-stroke poppet valves engine architecture for pollutant control, while keeping a competitive engine efficiency. On a first stage, the HPC concept was implemented at low engine load, where the concept is expected to provide the best results, by advancing the start of injection towards the compression stroke and it was confirmed how it is possible to reduce NOX and soot emissions, but increasing HC and CO emissions.
Technical Paper

Metal Oxide Particle Emissions from Diesel and Petrol Engines

2012-04-16
2012-01-0841
All internal combustion piston engines emit solid nanoparticles. Some are soot particles resulting from incomplete combustion of fuels, or lube oil. Some particles are metal compounds, most probably metal oxides. A major source of metal compound particles is engine abrasion. The lube oil transports these abraded particles into the combustion zone. There they are partially vaporized and ultrafine oxide particles formed through nucleation [1]. Other sources are the metallic additives to the lube oil, metallic additives in the fuel, and debris from the catalytic coatings in the exhaust-gas emission control devices. The formation process results in extremely fine particles, typically smaller than 50 nm. Thus they intrude through the alveolar membranes directly into the human organism. The consequent health risk necessitates a careful investigation of these emissions and effective curtailment.
Technical Paper

DPF's Regeneration Procedures and Emissions with RME Blend Fuels

2012-04-16
2012-01-0844
The fatty acid methyl esters (FAME's) - in Europe mostly RME (Rapeseed methyl ester) - are used in several countries as alternative biogene diesel fuels in various blending ratios with fossil fuels (Bxx). Questions often arise about the influences of these biocomponents on the modern exhaust aftertreatment systems and especially on the regeneration of diesel particle filters (DPF). In the present work different regeneration procedures of DPF systems were investigated with biofuels B0, B20 & B100. The tested regeneration procedures were: - passive regenerations: DOC + CSF; CSF alone, and - active regenerations: standstill burner; fuel injections & DOC. During each regeneration on-line measurements of regulated and unregulated emission components (nanoparticles & FTIR) were conducted. It can be stated that the increased portion of RME in fuel provokes longer time periods to charge the filter with soot.
Journal Article

Control-Oriented Modeling of a LNT-SCR Diesel After-Treatment Architecture

2011-04-12
2011-01-1307
Lean NOx trap (LNT) and Selective Catalytic Reduction catalysts (SCR) are two leading candidates for diesel NOx after-treatment. Each technology exhibits good properties to reduce efficiently diesel NOx emissions in order to match the forthcoming EURO 6 standards. NOx reduction in LNT is made through a two-step process. In normal (lean) mode, diesel engine exhausts NOx is stored into the NOx trap; then when necessary the engine runs rich during limited time to treat the stored NOx. This operating mode has the benefit of using onboard fuel as NOx reducer. But NOx trap solution is restrained by limited active temperature windows. On the other hand, NH₃-SCR catalysts operate in a wider range of temperature and do not contain precious metals. However, NH₃-SCR systems traditionally use urea-water solution as reducing agent, requiring thus additional infrastructure to supply the vehicles with enough reducer. These pros and cons are quite restrictive in classical LNT or NH₃-SCR architecture.
Technical Paper

DPF Systems for High Sulfur Fuels

2011-04-12
2011-01-0605
During the first decade of diesel particle filter development and deployment in cars, trucks, buses and underground sites, DPF regeneration methods were engineered that were compatible with the then prevalent high sulfur content in the fuel ≻ 2000 ppm. The mainly used methods were burners, electrical heaters, replaceable filters and non-precious metal fuel additives. Low sulfur diesel fuel became only available from 1996 in Sweden, 1998 in Switzerland, and after 2000 everywhere in Europe. Thus, the deployment of precious metal catalytic converters was feasible both as original equipment and retrofitting of in-use engines. The so-called CRT particle filters using PGM-catalysis for providing NO₂ for low temperature regeneration became very successful wherever ULSD was available.
Technical Paper

Diesel Emission with DPF+SCR in VERTdePN - Testing & Potentials

2011-04-12
2011-01-1139
The most efficient way and the best available technology (BAT) to radically reduce the critical diesel emission components particles (PM&NP) and nitric oxides (NOx) are combined exhaust gas aftertreatment systems (DPF+SCR). SCR (selective catalytic reduction) is regarded as the most efficient deNOx-system, diesel particle filters are most efficient for soot abatement. Today, several suppliers offer combined systems for retrofitting of HD vehicles. The presented results are part of the work in the international network project VERT *) dePN (de-activation, de-contamination, disposal of particles and NOx), which has the objectives to establish test procedures and quality standards and to introduce the SCR-, or combined DPF+SCR-systems in the VERT verification procedure.
Technical Paper

System Approach for NOx Reduction: Double LNT Diesel After-Treatment Architecture

2011-04-12
2011-01-1300
This paper presents an after-treatment architecture combining a close coupled NOx trap and an under floor NOx trap. Instead of simply increasing the volume of the catalyst, we propose to broaden the active temperature window by splitting the LNT along the exhaust line. In order to design this architecture, a complete 1D model of NOx trap has been developed. Validated with respect to experimental data, this model has been useful to define the two volumes of LNT, making significant savings on the test bench exploitation. However, one of the main difficulties to operate the proposed architecture is the NOx purge and sulfur poisoning management. In order to optimize the NOx and sulfur purge launches, we have developed a control strategy based on an embedded reduced LNT model. These strategies have been validated on different driving cycles, by the means of simulation and of vehicle tests using rapid prototyping tools.
Journal Article

Effects of Methane/Hydrogen Blends On Engine Operation: Experimental And Numerical Investigation of Different Combustion Modes

2010-10-25
2010-01-2165
The introduction of alternative fuels is crucial to limit greenhouse gases. CNG is regarded as one of the most promising clean fuels given its worldwide availability, its low price and its intrinsic properties (high knocking resistance, low carbon content...). One way to optimize dedicated natural gas engines is to improve the CNG slow burning velocity compared to gasoline fuel and allow lean burn combustion mode. Besides optimization of the combustion chamber design, hydrogen addition to CNG is a promising solution to boost the combustion thanks to its fast burning rate, its wide flammability limits and its low quenching gap. This paper presents an investigation of different methane/hydrogen blends between 0% and 40 vol. % hydrogen ratio for three different combustion modes: stoichiometric, lean-burn and stoichiometric with EGR.
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