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Engine and vehicle tailpipe emissions can be measured in laboratories equipped with engine dynamometers and chassis dynamometers, respectively. In addition to laboratory testing, there is an increase in interest to measure on-road vehicle emissions using portable emissions measurement systems in order to determine real-driving emissions. Current methods to quantify engine, vehicle tailpipe, and real-driving emissions include the raw continuous, dilute continuous, and dilute bag measurement methods. Although the dilute bag measurement method is robust, recent improvements to the raw and dilute continuous measurement methods can account for the time delay between the probe tip and analyzer in addition to gas transport dynamics in order to reliably recover the tailpipe concentration signals. These improvements significantly increase the reliability of results using the raw and dilute continuous measurement methods, making them possible alternatives to the bag method.

Regulations around the globe are driving the adoption of alternative fuels and vehicles through the implementation of stricter standards aimed at reducing carbon footprint and criteria emissions such as nitrogen oxides (NOx), particulate matter (PM), and total hydrocarbon (THC) emissions. Low emission zones have been implemented across Europe which restrict access by some vehicles with the aim of improving the air quality. The Paris Agreement on climate change declared governments’ intentions to reduce greenhouse gas (GHG) emissions as outlined in each country’s nationally determined contribution. Providing affordable energy to support prosperity while reducing environmental impacts, including the risks of climate change, is the dual challenge for the energy and transport industries.

In the last decade, numerous studies have been conducted to investigate the mechanism of Low Speed Pre-Ignition (LSPI) in Turbocharged Gasoline Direct Injection (TGDi) engines. According to technical reports, engine oil formulations can significantly influence the occurrence of LSPI particularly when higher levels of calcium-based additives are used, increasing the tendency for LSPI events to occur. While most of the studies conducted to date utilized engine tests, this paper evaluates the effect of engine oil formulations on LSPI under real-world driving conditions, so that not only the oil is naturally aged within an oil change interval, but also the vehicle is aged through total test distance of 160,000 km. Three engine oil formulations were prepared, and each tested in three vehicles leading to an identical fleet totaling nine vehicles, all of which were equipped with the same TGDi engine.

Historically, greenhouse gas (GHG) emissions standards for vehicles have focused on tailpipe emissions. However, sound environmental policy requires a more holistic well-to-wheels (WTW) assessment that includes both production of the fuel and its use in the vehicle. The present research explores the net change in WTW GHG emissions associated with moving from regular octane (RO) to high octane (HO) gasoline. It considers both potential increases in refinery emissions from producing HO fuel and potential reductions in vehicle emissions through the use of fuel-efficient engines optimized for such fuel. Three refinery configurations of varying complexity and reforming capacity were studied. A set of simulations covering different levels of HO gasoline production were run for each refinery configuration.

Increasingly stringent vehicle emissions legislation is being introduced throughout the world, regulating the allowed levels of particulate matter emitted from vehicle tailpipes. The regulation may prove challenging for gasoline vehicles equipped with modern gasoline direct injection (GDI) technology, owing to their increased levels of particulate matter production. It is expected that gasoline particulate filters (GPFs) will soon be fitted to most vehicles sold in China and Europe, allowing for carbonaceous particulate matter to be effectively captured. However, GPFs will also capture and accumulate non-combustible inorganic ash within them, mainly derived from engine oil. Studies exist to demonstrate the impact of such ash on GPF and vehicle performance, but these commonly make use of accelerated ash loading methods, which themselves introduce significant variation.

Motorcycle OEMs faced with stringent global fuel economy and emission regulations are being forced to develop new hardware and emissions control technologies to remain compliant. Motorcycle oils have become an enabling technology for the development of smaller, more efficient engines operating at higher power density. Many OEMs have therefore become reliant on lubricants to not only provide enhanced durability under more extreme operating conditions, but to also provide fuel economy benefits through reduced energy losses. Unlike passenger car oils that only lubricate the engine, motorcycle oils must lubricate both the engine and the drive train. These additional requirements place different performance demands versus a crankcase lubricant. The drive train includes highly loaded gears that are exposed to high pressures, in turn requiring higher levels of oil film strength and antiwear system durability.

Downsized gasoline engines, coupled with gasoline direct injection (GDI) and turbocharging, have provided an effective means to meet both emissions standards and customers’ drivability expectations. As a result, these engines have become more and more common in the passenger vehicle marketplace over the past 10 years. To maximize fuel economy, these engines are commonly calibrated to operate at low speeds and high engine loads – well into the traditional ‘knock-limited’ region. Advanced engine controls and GDI have effectively suppressed knock and allowed the engines to operate in this high efficiency region more often than was historically possible. Unfortunately, many of these downsized, boosted engines have experienced a different type of uncontrolled combustion. This combustion occurs when the engine is operating under high load and low speed conditions and has been named Low Speed Pre-Ignition (LSPI). LSPI has shown to be very damaging to engine hardware.

Improving vehicle fuel economy is a major consideration for original equipment manufacturers (OEMs) and their technology suppliers worldwide as government legislation increasingly limits carbon dioxide emissions. At the same time that automotive OEMs have been driving toward lower viscosity axle oils to improve fuel economy, OEMs have worked to improved durability over an extended drain interval. These challenges have driven the use of API group III and/or API group IV base oils in most factory fill axle oils. This paper details the development of a novel lower viscosity SAE 75W-85 axle technology based on group II base oil that rivals the performance of a PAO-based axle oil and challenges the conventional wisdom of not using group II base oils in fuel efficient axle oils.

This paper investigates experimental uncertainties associated with gaseous and particulate emissions measurements in a partial flow emissions sampling system developed and built at the Larson Transportation Institute of the Pennsylvania State University. A small fraction of the tail pipe exhaust is diluted with dilution air and passed through a cyclone to eliminate particles bigger than 2.5 microns. The diluted exhaust is then passed through a 47 mm Teflon filter for gravimetric measurement of Particulate Matter (PM). Mass flow controllers operating at 5Hz are used to control the flow rates of dilution air, diluted exhaust, and proportional flow of diluted exhaust into a Tedlar bag. An ultrasonic flow meter is used to measure flow rate of tail pipe exhaust. At the end of a test, the concentration of gaseous emissions in the bag, namely CO2, CO, HC, and NOx are measured using a bag emissions analyzer.

Polymer Electrolyte Membrane Fuel Cell (PEMFC) is regarded as a potential alternative clean energy source for automobile applications. Key challenges to the acceptance of PEMFC for automobiles are the cost reduction, improvement in power density for its compactness, and cold-start capability. High current density operation is a promising solution for them. However, high current density operation under normal and sub-zero temperature requires more oxygen flux for the electrochemical reaction in the catalyst layer, and it causes more heat and water flux, resulting in the significant voltage losses. So, the theoretical investigation is very helpful for the fundamental understanding of complex transport phenomena in high current density operation under normal and sub-zero temperature. In this study, the numerical model was established to elucidate the impacts of mass transport phenomena on the cell performance through the numerical validation with experimental and visualization results.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.

The ASTM D6121 (L-37) is a key hypoid gear lubricant durability test for ASTM D7450-08 (API Category GL-5) and the higher performance level SAE J2360. It is defined as the ‘Standard Test Method for Evaluation of Load-Carrying Capacity of Lubricants Under Conditions of Low Speed and High Torque Used for Final Hypoid Drive Axles’. Pass/fail is determined upon completion of the test by rating the pinion and ring gears for several types of surface distress, including wear, rippling, ridging, pitting, spalling and scoring. Passing the L-37 in addition to the other tests required for API Category GL-5 credentials, as well as the more strenuous SAE J2360 certification, requires in-depth formulating knowledge to appropriately balance the additive chemistry. This paper describes the results of ASTM D6121 experiments run for the purposes of better understanding gear oil durability.

Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).

In a two-stroke engine, carbon is a natural by-product of incomplete combustion. Fuel and oil quality vary leading to various degrees of carbon deposit build up on critical engine parts over time. If the carbon deposits are left on engine components and allowed to accumulate, it can lead to reduced horsepower, reduced fuel economy, increased emissions, and in the worst case the deposits can cause engine damage. A novel two-stroke engine oil was developed specifically to remove these deposits, restore the operating efficiency, and potentially lengthen the useful life of the two-stroke engine. In order to prove the restorative ability of this novel technology, dynamometer tests and field trials were conducted. In the dynamometer portion, the oil was tested in two of the standard TC-W3® certification tests for marine engine oils. The first was the OMC 40HP and the second was the OMC 70HP test.

Limited technical studies to speciate particulate matter (PM) emissions from gasoline fueled vehicles have indicated that the lubricating oil may play an important role. It is unclear, however, how this contribution changes with the condition of the lubricant over time. In this study, we hypothesize that the mileage accumulated on the lubricant will affect PM emissions, with a goal of identifying the point of lubricant mileage at which PM emissions are minimized or at least stabilized relative to fresh lubricant. This program tested two low-mileage Tier 2 gasoline vehicles at multiple lubricant mileage intervals ranging from zero to 5000 miles. The LA92 cycle was used for emissions testing. Non-oxygenated certification fuel and splash blended 10% and 20% ethanol blends were used as test fuels.

The world is firmly focused on reducing energy consumption and on increasingly stringent regulations on CO2 emissions. Examples of regulatory changes include the new United States Environmental Protection Agency's (U.S. EPA) fuel economy test procedures which were required beginning with the 2008 model year for vehicles sold in the US market. These test procedures include testing at higher speeds, more aggressive acceleration and deceleration, and hot-weather and cold-temperature testing. These revised procedures are intended to provide an estimate that more accurately reflects what consumers will experience under real world driving conditions. The U.S.

Life Cycle Assessment (LCA) is a methodology used to determine quantitatively the environmental impacts of a range of options. The environmental community has used LCA to study all of the impacts of a product over its life cycle. This analysis can help to prevent instances where a greater degree of environmental harm results when changes are made to products based on consideration of impacts in only part of the life cycle. This study applies the methodology to engine lubricants, and in particular chlorine limits in engine lubricant specifications. Concern that chlorine in lubricants might contribute to emissions from vehicle exhausts of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF), collectively called PCDD/F, led to the introduction of chlorine limits in lubricant specifications. No direct evidence was available linking chlorine in lubricants to PCDD/F formation, but precautionary principles were used to set lubricant chlorine limits.

Ongoing efforts in applying a “high-end” turbulent combustion model (a transported probability density function - tPDF - method) to direct-injection internal combustion engines are discussed. New numerical algorithm and physical modeling issues arise compared to more conventional modeling approaches. These include coupling between Eulerian finite-volume methods and Lagrangian Monte Carlo particle methods, liquid fuel spray/tPDF coupling, and heat transfer. Sensitivity studies are performed and quantitative comparisons are made between model results and experimental measurements in a diesel/PCCI engine. Marked differences are found between tPDF results that account explicitly for turbulence/chemistry interactions (TCI) and results obtained using models that do not account for TCI. Computed pressure and heat release profiles agree well with experimental measurements and respond correctly to variations in engine operating conditions.

Phosphorus is known to reduce effectiveness of the three-way catalysts (TWC) commonly used by automotive OEMs. This phenomenon is referred to as catalyst deactivation. The process occurs as zinc dialkyldithiophosphate (ZDDP) decomposes in an engine creating many phosphorus species, which eventually interact with the active sites of exhaust catalysts. This phosphorous comes from both oil consumption and volatilization. Novel low-volatility ZDDP is designed in such a way that the amounts of volatile phosphorus species are significantly reduced while their antiwear and antioxidant performances are maintained. A recent field trial conducted in New York City taxi cabs provided two sets of “aged” catalysts that had been exposed to GF-4-type formulations. The trial compared fluids formulated with conventional and low-volatility ZDDPs. Results of field test examination were reported in an earlier paper (1).

With the increasing use of modern, EGR-equipped, heavy-duty diesel engines and the use of lower sulfur and alternate fuels, such as biodiesel, lubricants are being exposed to a range of different compositions of acids. To complement the traditional detergent bases, todays lubricants have evolved to include a higher proportion of basic materials from amine-derived sources to aid in oxidation and soot control. This paper explores the impact of the different sources of acids, some of the issues they create and how they can be addressed, exemplified in a prototype CJ-4 lubricant formulation.