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Technical Paper

Correlating Laboratory Oil Aerosol Coking Rig Tests to Diesel Engine Tests to Understand the Mechanisms Responsible for Turbocharger Compressor Coking

2017-03-28
2017-01-0887
Deposit formation within turbocharger compressor housings can lead to compressor efficiency degradation. This loss of turbo efficiency may degrade fuel economy and increase CO2 and NOx emissions. To understand the role that engine oil composition and formulation play in deposit formation, five different lubricants were run in a fired engine test while monitoring turbocharger compressor efficiency over time. Base stock group, additive package, and viscosity modifier treat rate were varied in the lubricants tested. After each test was completed the turbocharger compressor cover and back plate deposits were characterized. A laboratory oil mist coking rig has also been constructed, which generated deposits having the same characteristics as those from the engine tests. By analyzing results from both lab and engine tests, correlations between deposit characteristics and their effect on compressor efficiency were observed.
Technical Paper

Low Volatility ZDDP Technology: Part 2 - Exhaust Catalysts Performance in Field Applications

2007-10-29
2007-01-4107
Phosphorus is known to reduce effectiveness of the three-way catalysts (TWC) commonly used by automotive OEMs. This phenomenon is referred to as catalyst deactivation. The process occurs as zinc dialkyldithiophosphate (ZDDP) decomposes in an engine creating many phosphorus species, which eventually interact with the active sites of exhaust catalysts. This phosphorous comes from both oil consumption and volatilization. Novel low-volatility ZDDP is designed in such a way that the amounts of volatile phosphorus species are significantly reduced while their antiwear and antioxidant performances are maintained. A recent field trial conducted in New York City taxi cabs provided two sets of “aged” catalysts that had been exposed to GF-4-type formulations. The trial compared fluids formulated with conventional and low-volatility ZDDPs. Results of field test examination were reported in an earlier paper (1).
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