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The ASTM D6121 (L-37) is a key hypoid gear lubricant durability test for ASTM D7450-08 (API Category GL-5) and the higher performance level SAE J2360. It is defined as the ‘Standard Test Method for Evaluation of Load-Carrying Capacity of Lubricants Under Conditions of Low Speed and High Torque Used for Final Hypoid Drive Axles’. Pass/fail is determined upon completion of the test by rating the pinion and ring gears for several types of surface distress, including wear, rippling, ridging, pitting, spalling and scoring. Passing the L-37 in addition to the other tests required for API Category GL-5 credentials, as well as the more strenuous SAE J2360 certification, requires in-depth formulating knowledge to appropriately balance the additive chemistry. This paper describes the results of ASTM D6121 experiments run for the purposes of better understanding gear oil durability.

Thermodynamics is the key component of materials science and engineering. The manifestation of thermodynamics is typically represented by phase diagrams, traditionally for binary and occasionally ternary systems. Consequently, the applications of thermodynamics have been rather limited in multi-component engineering materials. Computational thermodynamics, developed in the last few decades, has released the power of thermodynamics. In this presentation, fundamental thermodynamics is reviewed, followed by an introduction of computational thermodynamics in terms of first-principles calculations and thermodynamic modeling, and its application to Mg alloys.

City transit buses are a severe environment for an automatic transmission fluid. The fluid must endure very high operating temperatures because of the use of brake retarders, frequent stop-and-go driving, and numerous shifts. There is an increasing trend toward the use of extended-drain, synthetic-based ATFs for such severe service applications. This paper documents a field trial with both synthetic and petroleum-based ATFs at a large municipal bus fleet in Southern California. Three different commercial ATFs, made with either API Group 2, 3, or 4 base oils, respectively, were compared after roughly 80,000 km. and one year of operation. Because of different additive packages in each fluid, not all of the results can be explained by base oil effects alone. However, the base oil is certainly a dominant contributor to the finished fluid performance. The following four variables were monitored by used oil analysis: iron wear, copper wear, viscosity change, and acid number change.

Throughout the evolution of the automobile, passenger car motor oils have been developed to address issues of wear, corrosion, deposit formation, friction, and viscosity stability. As a result, the internal combustion engines are now developed with the expectation that the lubricants to be used in them will deliver certain performance attributes. Metallurgies, clearances, and built-in stresses are all chosen with certain expectations from the lubricant. A family of chemicals that has been universally used in formulating passenger car motor oils is zinc dithiophosphates (ZDPs). ZDPs are extremely effective at protecting highly stressed valve train components against wear failure, especially in engine designs with a sliding contact between cams and followers. While ZDPs' benefits on wear control are universally accepted, ZDPs have been identified as the source of phosphorus, which deactivates noble metal aftertreatment systems.

The next generation of engine oil under development has been formulated to maintain beneficial oil lubrication properties at increased engine operating temperatures, increased drain-oil intervals, and with the recirculation of exhaust gas back through the engine (EGR). These conditions result in the formation of degradation products from decomposed fuel, additives, and base oil. Decomposition products containing reactive sulfur can result in the corrosion of copper alloys. Sulfur-containing compounds currently used in these formulations can include zinc dithiophosphates (ZDP), molydithiophosphates, molydithiocarbamates, and molybdic acid/amine complexes, along with sulfur containing detergents and antioxidants. Interactions among these components and others in the formulation often determine the propensity of these formulations for corrosion. This paper will discuss the results of corrosion bench tests used to screen oil formulations for copper corrosion.

The specific goal of this project was to determine if there is a difference in the lube oil degradation rates in a heavy-duty diesel engine equipped with an EGR system, as compared to the same configuration of the engine, but minus the EGR system. A secondary goal was to develop FTIR analysis of used lube oil as a sensitive technique for rapid evaluation of the degradation properties of lubricants. The test engine selected for this work was a Caterpillar 3176 engine. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to meet the 2004 emissions standards. The most significant changes in the lubricant occurred during the first 50-100 hours of operation. The results clearly demonstrated that the use of EGR has a significant impact on the degradation of the engine lubricant.

Powder injection molding (PIM) combines the processability of plastics and the superior material properties of metals and ceramics to form high performance components. The process comprises of several stages. Metal or ceramic powder and organic materials are combined into a homogeneous feedstock which is then injection molded into a desired shape. The organic constituent is then removed from the object and sintering is done to form a rigid structure of controllable density. The important benefits afforded by PIM include near net-shape production of complex geometries in the context of low cost and rapid fabrication at high production volumes.

Automatic transmission clutches are complex tribological systems. Frictional performance is controlled by the interaction of base fluids, additive components, composition clutches, and steel reaction plates with varying energy inputs and thermal stresses in an oxidizing environment. This paper, rather than addressing fully formulated fluid performance in such a system, takes a more fundamental approach where the number of system variables is reduced and the relative effects of formulation variables on system performance can be better examined. Relationships among observed friction performance, system oxidation, friction member condition, and representative performance additives are explored using a synthetic base fluid and a conventionally refined mineral base fluid.

Nylon is used as a material in the design of various components of automatic transmissions. Pump rotor guides and thrust washers are among components designed from nylon. Nylon must be compatible with automatic transmission fluid (ATF). An immersion test using nylon strips in various test fluids was developed. The nylon color change was independent of the physical properties (as measured by change of tensile force) of the material. Testing indicated that nylon color change is catalyzed by oxidation effects, and the change in tensile strength is related to thermal degradation. An automatic transmission fluid (ATF) containing calcium sulfonate detergent showed better oxidation resistance and caused less loss of tensile strength in nylon 6 (PA6).