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Automotive exhaust emission regulations are becoming progressively stricter due to increasing awareness of the hazardous effects of exhaust emissions. The main challenge to meet the regulations is to reduce the emissions during cold starts, because catalytic converters are ineffective until they reach a light-off temperature. It has been found that 50% to 80% of the regulated hydrocarbon and carbon monoxide emissions are emitted from the automotive tailpipe during the cold starts. Therefore, understanding the catalytic converter characteristics during the cold starts is important for the improvement of the cold start performances This paper describes a mathematical model that simulates transient performances of catalytic converters. The model considers the effect of heat transfer and catalyst chemical reactions as exhaust gases flow through the catalyst. The heat transfer model includes the heat loss by conduction and convection.

Five small two-stroke engine designs were tested at different air/fuel ratios, under steady state and transient cycles. The effects of combustion chamber design, carburetor design, lean burning, and fuel composition on performance, hydrocarbon and carbon monoxide emissions were studied. All tested engines had been designed to run richer than stoichiometric in order to obtain satisfactory cooling and higher power. While hydrocarbon and carbon monoxide emissions could be greatly reduced with lean burning, engine durability would be worsened. However, it was shown that the use of a catalytic converter with acceptably lean combustion was an effective method of reducing emissions. Replacing carburetion with in-cylinder fuel injection in one of the engines resulted in a significant reduction of hydrocarbon and carbon monoxide emissions.

The distribution of fuel-air mixtures in many L-head engines is not homogeneous. If local mixture is too rich or lean, incomplete combustion occurs. This can play a major role in unburned hydrocarbon and carbon monoxide emissions. Fuel-air mixture distribution depends on in-cylinder swirl and turbulence and is directly related to intake manifold configuration, fuel delivery system design and combustion chamber shape. Understanding the spatial mixture distribution may help improve the design of these aforementioned components. Consequently, a more complete combustion process may result, and emissions reduced. A method that measures the emission of CH and C2 radicals via the use of an optical fiber bundle was used in this research to map the mixture uniformity in the combustion chamber. The intensity ratio (IC2/ICH) was correlated to the fuel-air equivalence ratio. The mixture distribution measured was then correlated with the hydrocarbon emission sequence.

A laboratory test reactor has been used to determine the rates of oxidation of carbon monoxide (CO), hydrocarbons (HCs) as a class, and hydrogen (H2). The feed was supplied from the exhaust of a single-cylinder engine, with additions of H2 and CO in some runs. The test reactor was designed to be well mixed, and this was verified experimentally for mixing on macroscopic and microscopic scales. Wall effects were found to be unimportant. Kinetic data from 157 runs were correlated with global reaction rate expressions containing Arrhenius temperature dependence and power law concentration dependence. CO oxidation was found to be approximately 1/4 order in CO with an activation energy of 28,200 cal/g-mole. HC oxidation was found to be approximately 1/4 order in HC and 1/2 order in each of O2, CO, and NO with an activation energy of 29,800 cal/g-mole. H2 oxidation rates were not well correlated, but a zero-order rate with an activation energy of 52,000 cal/g-mole is reasonable.

The physiology of carbon monoxide is discussed in the human respiratory system. The details of the relationship of carbon monoxide and hemoglobin are outlined, and the effects of specific concentrations of CO are shown. Acute and chronic exposures to CO create certain effects on the various bodily systems, and these are described in detail.