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Nowadays, proton exchange membrane (PEM) fuel cell is widely seen as a promising energy conversion device especially for transportation application scenario because of its high efficiency, low operation temperature and nearly-zero road emission. Extensive modeling work have been done based on different dimensions during the past decades, including one-dimensional (1D), two-dimensional (2D), three-dimensional (3D) and intermediate combinations in between (e.g. “1+1D”). 1D model benefits from a rationally-chosen set of assumptions to obtain excellent calculation efficiency, yet at the cost of accuracy to some extent. In contrast, 3D model has great advantage over 1D model on acquiring more comprehensive information inside the fuel cell. For macro-scale modeling work, one compromise aiming to realize both acceptable computation speed and reasonable reflection of cell operation state is to simplify the membrane electrode assembly (MEA).

Lean NOx trap (LNT) is a great potential NOx abatement method for lean-burn gasoline engines in consideration of exhaust aftertreatment cost and installation space. NOx firstly is adsorbed on storage sites during the lean-burn period, then reduced to N2 under catalysis of the catalyst sites in the rich-burn phase. There must be a spillover of NOx species between both types of sites. For a better understanding of this spillover process of NOx species between Pt (as the catalytic center) and BaO sites (as storage components in commercial catalyst), this work focused on the vital first step of spillover, the adsorption of NOx on clean substrate surface (γ-Al2O3 (110) surface) and Ba\Pt cluster supported by the surface. Based on first principles software VASP (Vienna Ab-initio Simulation Package), the most stable adsorption structures of NO with Pt3 clusters and (BaO)3 clusters on carrier γ- Al2O3 (110) surface were confirmed and the adsorption energy of these structures were compared.

Proton exchange membrane fuel cell (PEMFC) provides a promising future low carbon automotive powertrain solution. The catalyst layer (CL) is its core component which directly influences the output performance. PEMFC performance can be greatly improved by the effective optimization of CL composition. This work demonstrates a deep optimization of CL composition for improving the PEMFC performance, including the platinum (Pt) loading, Pt percentage of carbon-supported Pt and ionomer to carbon ratio of the anode and the cathode,. The simulation results by a PEMFC three-dimensional (3D) computation fluid dynamics (CFD) model coupled with the CL agglomerate model is used to train the artificial neural network (ANN) which can efficiently predict the current density under different CL composition. Squared correlation coefficient (R-square) and mean percentage error in the training set and validation set are 0.9867, 0.2635% and 0.9543, 1.1275%, respectively.

Although turbulence plays a critical role in engines operated within low temperature combustion (LTC) regime, its interaction with chemistry on auto-ignition at low-ambient-temperature and lean-oxygen conditions remains inadequately understood. Therefore, it is worthwhile taking turbulence-chemistry interaction (TCI) into consideration in LTC engine simulation by employing advanced combustion models. In the present study, large eddy simulation (LES) coupled with linear eddy model (LEM) is performed to simulate the ignition process in n-heptane spray under engine-relevant conditions, known as Spray H. With LES, more details about unsteady spray flame could be captured compared to Reynolds-averaged Navier-Stokes equations (RANS). With LEM approach, both scalar fluctuation and turbulent mixing on sub-grid level are captured, accounting for the TCI. A skeletal mechanism is adopted in this numerical simulation, including 41 species and 124 reactions.

Electrically assisted turbochargers are a promising technology for improving boost response of turbocharged engines. These systems include a turbocharger shaft mounted electric motor/generator. In the assist mode, electrical energy is applied to the turbocharger shaft via the motor function, while in the regenerative mode energy can be extracted from the shaft via the generator function, hence these systems are also referred to as regenerative electrically assisted turbochargers (REAT). REAT allows simultaneous improvement of boost response and fuel economy of boosted engines. This is achieved by optimally scheduling the electrical assist and regeneration actions. REAT also allows the exhaust turbine to operate within a narrow range of optimal vane positions relative to the unassisted variable geometry turbocharger (VGT). The ability to operate within a narrow range of VGT vane positions allows an opportunity for a more optimal turbine design for a REAT system.

The previous study indicates that the detonation waves generated by acetylene/oxygen mixture can converge in the combustion chamber. In order to verify the destructive effect of detonation wave convergence on piston materials, the detonation bomb device was modified to fundamentally investigate the material failures of aluminum alloy for pistons. The results show that the specimens are destroyed in the middle and edge region after dozens of detonations, which is consistent with the typical characteristics of the piston failures in engines. Therefore, the hypothesis that failures of piston material is caused by the detonation wave convergence is verified.

Liquefied natural gas (LNG) engine could provide both reduced operating cost and reduction of greenhouse gas (GHG) emissions. Stoichiometric operation with EGR and the three-way catalyst has become a potential approach for commercial LNG engines to meet the Euro VI emissions legislation. In the current study, numerical investigations on the knocking tendency of several combustion chambers with different geometries and corresponding performances were conducted using CONVERGE CFD code with G-equation flame propagation model coupled with a reduced natural gas chemical kinetic mechanism. The results showed that the CFD modeling approach could predict the knock phenomenon in LNG engines reasonably well under different thermodynamic and flow field conditions.

The potential of diesel/gasoline RCCI combustion coupled with late intake valve closing (LIVC) and double direct injection of diesel for meeting high fuel efficiency with ultra-low emissions was investigated in this study. The study was aiming at high load operation in a heavy-duty diesel engine. Based on the reactivity stratification of RCCI combustion, the employment of double injection of diesel fuel provided concentration stratification of the high-reactivity fuel, which is to further realize effective control of the combustion process. Meanwhile, late intake valve closing (LIVC) strategy is introduced to control the maximum in-cylinder pressure and nitrogen oxides (NOx) emissions.

Compared with conventional flow field, metal foam has been increasingly used for gas distributor in the PEM (proton exchange membrane) fuel cell due to its high porosity and conductivity, which significantly enhances the species transport under high current density condition. In this study, the cell performances with metal foam and graphite parallel flow field are compared under normal and subzero temperature conditions. Besides, electrochemical impedance spectroscopy (EIS) is recorded to characterize the Ohmic, polarization and polarization resistance. Under normal condition, the cell with metal foam exhibits three times better performance than the one with parallel flow field. Meanwhile, the effects of inlet gas humidity and flow rates on cell performance are also studied, indicating that the cathode flooding easily occurs due to its difficult water removal. However, the high flow rate can greatly ease the cathode water flooding.

Proton exchange membrane (PEM) fuel cell is widely recognized as an outstanding portable power plant and expected to be possibly commercialization in the near future. As is well known, mechanical stresses implemented on the bipolar plates during the assembly procedure should have prominent influences on mass and heat transfer behavior inside the cell, as well as the resultant performance. In this study, an analytical model is proposed to comprehensively investigate the influence of clamping force on the mass transport, electrochemical properties and overall cell output capability of a PEM fuel cell. The results indicate that proper clamping force not only benefits the gas leakage prevention but also increases the contact area between the neighboring components to decrease the contact ohmic resistance.

In order to improve the combustion and emissions for high-speed marine diesel engines, numerical investigations on effects of different combustion chamber structures combined with oxygen enriched air have to be conducted. The study uses AVL Fire code to establish three-dimensional combustion model and simulate the in-cylinder flow, air-fuel mixing and combustion process with the flow dynamics metrics such as swirl number and uniformity index, analyze the interactional effects of combustion chamber structures and oxygen enriched air against the experimental data for a part load operation at 1350 r/min, find the optimized way to improve engine performance as well as decrease the NOx and soot emissions. The novelty is that this study is to combine different oxygen concentration with different combustion chamber structures including the re-entrant chamber, the straight chamber and the open chamber.

In order to achieve high-efficiency and clean combustion in HCCI engines, combustion must be controlled reasonably. A great variety of species with various reactivities can be produced through low temperature oxidation of fuels, which offers possible solutions to the problem of controlling in-cylinder mixture reactivity to accommodate changes in the operating conditions. In this work, in-cylinder combustion characteristics with low temperature reforming (LTR) were investigated in an optical engine fueled with low octane number fuel. LTR was achieved through low temperature oxidation of fuels in a reformer (flow reactor), and then LTR products (oxidation products) were fed into the engine to alter the charge reactivity. Primary Reference Fuels (blended fuel of n-heptane and iso-octane, PRFs) are often used to investigate the effects of octane number on combustion characteristics in engines.

As the prime after-treatment device for diesel particulate matter (PM) emission control, Diesel Particulate Filter (DPF) has been widely used for its high particle capture efficiency. In order to study the particle motion and deposition distributions in the DPF inlet channel, a 2-D wall flow DPF microcosmic channel model is built in this paper. The motion trajectories of particles with different sizes are investigated considering the drag force, Brownian motion, gravity and Saffman lift. The effects of the space velocity on particle motion trajectories and deposition distributions inside the inlet channel are evaluated. These results demonstrate that the particle motion trajectories are highly dependent on particle sizes and influenced by the space velocity. The effect of the Brownian motion is obvious for fine particles and suppressed when the space velocity is raised.

Engine downsizing is one of the most effective means to improve the fuel economy of spark ignition (SI) gasoline engines because of lower pumping and friction losses. However, the occurrence of knocking combustion or even low-speed pre-ignition at high loads is a severe problem. One solution to significantly increase the upper load range of a 4-stroke gasoline engine is to use 2-stroke cycle due to the double firing frequency at the same engine speed. It was found that a 0.7 L two-cylinder 2-stroke poppet valve gasoline engine equipped with a two-stage serial boosting system, comprising a supercharger and a downstream turbocharger, could replace a 1.6 L naturally aspirated 4-stroke gasoline engine in our previous research, but its fuel economy was close to that of the 4-stroke engine at upper loads due to knocking combustion.

During the aero-engine operation, the compressor blades are subjected to periodic inertial force and aerodynamic excitation caused by blade rotation and airflow disturbance, respectively. Under the coupling alternating loads, the blade is prone to high cycle fatigue failure. In this paper, a time domain calculation model of fluid-structure interaction (FSI) is established to study the vibration characteristics of the blade and its failure modes are analyzed. Then, the fatigue damage of the blade under multi-level loading is evaluated by the nonlinear damage accumulation model. Considering the coupling effect of the airflow and the blade, computational fluid dynamics (CFD) is applied to calculate the aerodynamic parameters on the blade surface under different working conditions, which is imported to the finite element (FE) model to analyze the dynamic characteristics.

Clean combustion is critical for marine engines to meet the Tier III emission regulation. In this paper, the effects of EGR and injection strategies (including injection pressure, injection timing as well as multiple injection technology) on the performance and emissions of a 2-stroke, low speed marine diesel engine were investigated by using computational fluid dynamics (CFD) simulations to reach the IMO Tier III NOx emissions target and reduce the fuel consumption rate. Due to the large length scale of the marine engine, RANS simulation was performed in combination with the CTC-SHELL combustion model. Based on the simulation model, the variation of the cylinder pressure curve, the average temperature in the cylinder, the combustion heat release rate and the emission characteristics were studied.

Recent toxicological and epidemiologic studies have shown that diesel emissions have been a significant toxic air contaminant. Catalyzed DPF (CDPF) not only significantly reduces the PM mass emissions (>90%), but also further promotes carrier self-regeneration and oxidize more harmful gaseous pollutants by the catalyst coated on the carrier. However, some ultrafine particles and potentially harmful gaseous pollutants, such as VOCs species, originally emitted in the vapor-phase at high plume temperature, may penetrate through the CDPF filter. Furthermore, the components and content of catalyst coated on the CDPF could influence the physicochemical properties and toxicity intensity of those escaping ultrafine particles and gaseous pollutants. In this work, (1) we investigated the influence of precious metal content as a variable parameter on the physicochemical properties and catalytic activities of the small CDPF samples.

Particulate matter emissions have become a concern for the development of DISI engines. EGR has been extensively demonstrated as a beneficial technology to migrate knock performance, improve fuel economy and reduce NOX emissions. Recently, the effect of EGR on particulate matter emissions is attracting increased attention. This work investigates the effects of EGR on PN emissions with the variations of engine operating parameters and aims to understand the role of EGR in PN emissions for DISI engines. A 1.8liter turbocharged engine with cooled EGR is used for this study. The engine is operated at steady-state conditions with EGR under various operating parameters including injection timing, excess air ratio, and spark timing to characterize the particle number emissions. The results indicates that there is a high sensitivity of PN emissions to EGR with the variations of those parameters.

The dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion could achieve high efficiency and low emissions over a wide range of operating conditions. However, further high load extension is limited by the excessive pressure rise rate and soot emission. Polyoxymethylene dimethyl ethers (PODE), a novel diesel alternative fuel, has the capability to achieve stoichiometric smoke-free RCCI combustion due to its high oxygen content and unique molecule structure. In this study, experimental investigations on high load extension of gasoline/PODE RCCI operation were conducted using late intake valve closing (LIVC) strategy and intake boosting in a single-cylinder, heavy-duty diesel engine. The experimental results show that the upper load can be effectively extended through boosting and LIVC with gasoline/PODE stoichiometric operation.

In this work the gasoline compression ignition (GCI) combustion characterized by both premixed gasoline port injection and gasoline direct injection in a single-cylinder diesel engine was investigated experimentally and computationally. In the experiment, the premixed ratio (PR), injection timing and exhaust gas recirculation (EGR) rate were varied with the pressure rise rate below 10 bar/crank angle. The experimental results showed that higher PR and earlier injection timing resulted in advanced combustion phasing and improved thermal efficiency, while the pressure rise rates and NOx emissions increased. Besides, a lowest ISFC of 176 g/kWh (corresponding to IMEP =7.24 bar) was obtained, and the soot emissions could be controlled below 0.6 FSN. Despite that NOx emission was effectively reduced with the increase of EGR, HC and CO emissions were high. However, it showed that GCI combustion of this work was sensitive to EGR, which may restrict its future practical application.