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Compression ignition engines provide superior thermal efficiency over other internal combustion engines. Unfortunately the combustion process is diffusive combustion, meaning a lot of fuel is impinged the on the piston and cylinder wall. This creates cooling loss coupled with smoke, CO and THC. Minimization of the nozzle orifice diameter is a simple method widely used to shorten spray penetration. However, decreasing the nozzle orifice diameter also decreases fuel flow rate resulting in a prolonged injection and combustion process and reducing thermal efficiency. An offset orifice nozzle causes less fuel impingement by shorter fuel spray penetration without significant reduction of fuel flow rate. The offset orifice nozzle was made by shifting its alignment from the center of the sac to the edge of the sac following the swirl direction. A counterbore design was applied to maintain constant orifice length.

To investigate the heat transfer phenomena inside the combustion chamber of a diesel engine, a correlation for the heat transfer coefficient in a combustion chamber of a diesel engine was investigated based on heat flux measured by the authors in the previous study(8) using the rapid compression and expansion machine. In the correlation defined in the present study, thermodynamically estimated two-zone temperatures in the burned zone and the unburned zone are applied. The characteristic velocity given in the correlation is related to the speed of spray flame impinging on the wall during the fuel injection period. After the fuel injection period, the velocity term of the Woschni’s equation is applied. It was shown that the proposed correlation well expresses heat transfer phenomena in diesel engines.

The soot contamination in used engine oils of diesel engine vehicles was about 1% by weight. The soot and metal wear particle sizes might be in the range of 0-1 µm and 1-25 µm, respectively. The characteristics of soot affecting on metal wear was investigated. Soot particle contamination in diesel engine oil was simulated using carbon black. Micro-nanostructure of soot particles were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and laser diffraction spectroscopy (LDS). The metal wear behavior was studied by means of a Four-Ball tribology test with wear measured. Wear roughness in micro-scale was investigated by high resolution optical microscopy (OM) , 3D rendering optical technique and SEM image processing method. It was found that the ball wear scar diameter increased proportionally to the soot primary particle size. The effect of biodiesel contamination were also increasing in wear scar diameter.

Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.

Primary energy source such as fossil fuel keep decreasing due to various kind of usage. According to less amount of the fossil fuel, human seeks for an alternative fuel source such as alcohol. Alcohol like ethanol can be produced easily from strarchy plant. But using alcohol as blended fuel with diesel fuel doesn't work well because alcohol has low cetane number, lack of lubricity and very low miscibility with diesel fuel. To overcome this, fumigation system or port fuel injection of alcohol seems interesting. Although it requires more complicate system but it can compensate the miscibility issue and alcohol can be used in higher dose to give more energy. Diesel engine produces a lot of emission such as NOx and some other carbon content emission like HC, CO and soot due to they run in lean condition as their characteristic. Modern diesel engines are now coupled with exhaust gas recirculation system to help reduce in main emission like NOx.

As well-known, the diesel engine has the highest thermal efficiency at the same load as compared with internal combustion engine but its disadvantage is particulate matter (PM) emitted to the atmosphere. The studies of this paper were divided into two parts. The first part studied the quantity of PM from the both diesel and biodiesel fuels at 80% load (2400 rpm) by the trapping process on diesel particulate filter (DPF) used in a partial flow dilution tunnel. The second part studied the regeneration process of PM under the flow rate of oxygen and nitrogen gas of 13.5 L/min with 10%, 15%, and 21% of oxygen gas. The result showed that amount of PM from biodiesel fuel was lower around two times than PM from diesel fuel. The duration in regeneration process of biodiesel's PM was shorter than diesel while increasing of oxygen percentage can reduce regeneration time.

The diesel particulate membrane filter (DPMF) is a good solution to the problem of high pressure drop that exists across diesel particulate filters (DPFs) as a result of the soot trapping process. Moreover, DPMFs that have a membrane layer composed of SiC nanoparticles can reduce the oxidation temperature of soot and the apparent activation energy. The SiC nanoparticles have an oxide layer on their surface, with a thickness less than 10 nm. From the visualization of soot oxidation on the surface of SiC nanoparticles by an environmental transmission electron microscope (ETEM), soot oxidation is seen to occur at the interface between the soot and oxide layers. The soot oxidation temperature dependency of the contact area between soot and SiC nanoparticles was evaluated using a temperature programmed reactor (TPR). The contact area between soot and SiC nanoparticles was varied by changing the ratio of SiC nanoparticles and carbon black (CB), which was used as an alternative to soot.

Diesel engine is one the effective solutions for reducing CO2 and recognized as a leading candidate for mitigating global warming. To comply with increasingly stringent emission standards, all diesel engines require some sort of NOx control systems such as selective catalytic reduction (SCR) systems. The SCR catalyst for reducing NOx from diesel engines is classified into two groups, urea-SCR and HC-SCR catalyst, respectively. Although the urea-SCR catalyst is widely recognized as promising de-NOx technology in respect to the NOx conversion efficiency, it have some outstanding issues such as ammonia slip, urea injection, storage space, freezing and some infrastructures for supplying urea water solutions. In an attempt to overcome the inherent shortcoming of existing urea-SCR catalyst, hydrocarbons have been considered as alternative reducing agents for SCR process, instead of NH3.

The increase of air pollution and global warming is a threat for human life. Besides, the price of petroleum is increasing rapidly and the resources are diminishing. This obliged scientists and engineers to look for alternative sources of energy, which are cleaner and more sustainable. Biodiesel, defined as mono-alkyls of esters from vegetable oils and animals fat, is a cleaner renewable fuel and has been considered as the best alternative for petroleum based diesel fuel hence it can be used in any compression ignition engines without any significant modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions due to their higher content of oxygen. The produce less soot and hence the feed stuck is plant it will regenerate the CO2 by the photosynthesis which ensures the renewability and reduces global warming.

This work investigates the effects of ignition improvers on the ignition and combustion characteristics of hydrous ethanol with 5% by weight water and 1% by weight Lauric acid (Eh95) under simulated diesel engine conditions using the rapid compression and expansion machine (RCEM). Results indicate that hydrous ethanol with commercial additive (ED95) and hydrous ethanol with 5% by weight glycerol ethoxylate in hydrous ethanol exhibit a near identical rate-of-pressure-rise and heat release rate. Ignition delay of hydrous ethanol with 5% by weight glycerol ethoxylate is shorter, but hydrous ethanol with 1% by weight glycerol ethoxylate has longer ignition delay time and different combustion characteristics compared with hydrous ethanol with commercial additive (ED95). Hydrous ethanol with 1% by weight glycerol ethoxylate and hydrous ethanol with 5% by weight glycerol ethoxylate are considered suitable fuels for high compression-ratio diesel engines.

In order to investigate the combustion phenomena in a combustion chamber of the diesel engine at transient operations, the simultaneous measurements of temperatures of flame and wall surface in a combustion chamber were conducted. The new technique for simultaneous measurements of flame temperature and wall surface was developed. Laser-Induced phosphorescence was used for the measurement of wall surface temperature which was coupled with the flame temperature measurement by a two-color pyrometry. The NOx and soot emissions were also measured simultaneously in transient operations. The relation between the temporal changes of emissions and temperatures of flame and surface wall are discussed. The results show that the temporal change of NOx emission during transient operation is similar to that of the average gas temperature in a chamber. On the other hand, the temporal change of soot emission is similar to neither that of flame temperature nor that of average gas temperature.

Real-time analysis of benzene in automobile exhaust gas was performed using the Jet-REMPI (supersonic jet / resonance enhanced multi-photon ionization) method. Real-time benzene concentration of two diesel trucks and one gasoline vehicle driving in Japanese driving modes were observed under ppm level at 1 s intervals. As a result, it became obvious that there were many differences in their emission tendencies, because of their car types, driving conditions, and catalyst conditions. In two diesel vehicle, benzene emission tendencies were opposite. And, in a gasoline vehicle, emission pattern were different between hot and cold conditions due to the catalyst conditions.

In order to investigate the mechanism of heat transfer on the chamber wall of direct-injection diesel engines, 2-D temperature imaging and heat flux measurement in the flame impinging region on the chamber wall were conducted using laser-induced phosphorescence technique. The temperature of the chamber wall surface was measured by the calibrated intensity variation of the 355nm-excited laser-induced phosphorescence from an electrophoretically deposited thin layer of La2O2S:Eu phosphor on a quartz glass plate placed in a rapid compression and expansion machine (RCEM). Instantaneous 2-D images of wall temperature at different timings after start of injection and time-resolved (10kHz) heat flux near the flame impinging region were obtained for combusting and non-combusting diesel sprays with impinging distance of 23.4mm at different injection pressures (80 and 120MPa).

In this study, the combustion characteristics of diesel flame achieved in a rapid compression and expansion machine (RCEM) at various patterns of oxygen distribution in the chamber are investigated in order to clarify the effect of heterogeneity of oxygen distribution in diesel engines induced by EGR on the soot and NOx emissions. To make the heterogeneous distribution of oxygen in a combustion chamber, the mixtures with different oxygen concentrations are injected through the each different port located on the cylinder wall. Results indicate that the amount of oxygen entrained into the spray upstream the luminous flame region affects the NO emission from diesel flame strongly.

The major aim of this study is to investigate the tribofilm formation and friction-speed characteristics of ZnDTP in the presence of other lubricant additives. Simultaneous measurement of friction and electrical conductivity were employed using ZnDTP and several kinds of functionally different additives. Several analyses of friction surfaces were also carried out in order to measure the reaction film thickness and investigate the chemical composition of this film. It was demonstrated that the presence of each additive with ZnDTP prevented the formation of a ZnDTP tribofilm and thereby could provide lower friction than ZnDTP alone.

Trapping of diesel particulates and phenomena of chemical reaction in regeneration were investigated by visualization through the cross-sectional area of a diesel-particulate-filter wall, using a digital-microscope with a high focusing depth. Herein, SiC-DPF walls were polished up to make a uniform height and to create a mirror-like surface on each SiC-particle-grain. At the beginning of the trapping process, it was observed that large particulates were trapped once in the small pores inside the wall, and then, since the flow-pattern was changed drastically, the trapped particulates were pushed out and blown off again, and finally, trapped in a region further downstream. As time passed, image analysis disclosed that since fine particulates were deposited around the SiC-particle-grain surface, the flow-channels became increasingly narrow.

In order to investigate early soot formation process in diesel combustion, spectral analysis and optical thermometry of early soot formation region in a transient spray flame under diesel-like conditions (Pg2.8 MPa, Tg620-820K) was attempted via laser-induced fluorescence (LIF) from pyrene (C16H10) doped in the fuel. Pyrene is known to exhibit a temperature\-dependent variation of LIF spectrum; the ratio of S2/S1 fluorescence yields, from the lowest excited singlet state S1 and the second excited singlet state S2, depends on temperature. In the present study, pyrene was doped (1%wt) in a model diesel fuel (0-solvent) and the variation of LIF spectra from the pyrene in the spray flame in a rapid compression machine were examined at different ambient temperatures, ambient oxygen concentrations, measurement positions and timings after start of fuel injection.

The purpose of this study is to investigate the turbulent mixing in a diesel spray by large eddy simulation (LES). As the first step for the numerical simulation of diesel spray by LES, the LES of transient circular gas jets and particle laden jets were conducted. The simulation of transient circular jets in cylindrical coordinates has numerical instability near the central axis. To reduce the instability of calculation, azimuthal velocity around the central axis is calculated by the linear interpolation and filter width around the axis is modified to the radial or axial grid scale level. A transient circular gas jet was calculated by the modified code and the computational results were compared with experimental results with a Reynolds number of about 13000. The computational results of mean velocity and turbulent intensity agreed with experimental results for z/D>10. Predicted tip penetration of the jet also agreed to experimental data.

To investigate the ignition process in a diesel spray, the ignition in a transient fuel spray is analyzed numerically by a discrete droplet spray model (DDM) coupled with the Shell kinetics model at various operating conditions. Predicted results show that the fuel mixture injected at the start of injection, which travels along midway between the spray axis and the spray periphery, contributes heavily to the first ignition in a spray. The equivalence ratio and temperature of the first ignited mixture are kept nearly constant until the start of hot ignition. The temperature of the first ignited mixture is kept at a constant value of higher temperature than the thermodynamic equilibrium temperature of the mixture before the hot ignition starts. The equivalence ratio of the first ignited mixture is around 1.6 at initial gas temperatures between 750 K and 850 K.

Multi-step water splitting with Mn-ferrite(MnFe2O4)/sodium carbonate(Na2CO3) system accompanying endothermic reaction was investigated for converting solar energy into chemical energy. This water splitting is caused by the oxidation-reduction of manganese ion in the Mn-ferrite. Multi-water splitting with MnFe2O4/Na2CO3 system was consisted of three steps. The first step was hydrogen generation at 1073K. The second step was oxygen release at 1273K. The third step was Na2CO3 reproduction at 873K. The mechanism of multi-water splitting has been considered by XRD, chemical analysis of colorimetry and back titration. The temperature range 873 to 1273K is quite lower than those studied on the solar furnace reaction (O2 releasing step) in two-step water splitting (1500-2300K). This lower temperature range would permit further progress in converting the direct solar energy into chemical energy.