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Technical Paper

Experimental and Modeling Study of NH3-SCR on a Hydrocarbon-Poisoned Cu-CHA Catalyst

2023-10-31
2023-01-1659
A urea-selective catalytic reduction (SCR) system is used for the reduction of NOx emitted from diesel engines. Although this SCR catalyst can reduce NOx over a wide temperature range, improvements in NOx conversion at relatively low temperatures, such as under cold-start or low-load engine conditions, are necessary. A close-coupled SCR (cc-SCR), which was set just after the engine exhaust manifold, was developed to address this issue. The temperature of the SCR catalyst increases rapidly owing to the higher exhaust temperatures, and NOx conversion is then enhanced under cold-start conditions. However, since the diesel oxidation catalyst is not installed before the SCR catalyst, hydrocarbon (HC) emissions pass directly through the SCR catalyst and poison it, leading to lower NOx conversion. Therefore, the mechanism of NOx conversion reduction on HC-poisoned SCR catalysts are required to be studied.
Technical Paper

Effects of Different Driving Behavior during Actual Road Driving on Ammonia Emissions from Gasoline Vehicles

2023-09-29
2023-32-0095
Three-way catalysts are used in gasoline vehicles for simultaneous purifying nitrogen oxide, carbon monoxide, and hydrocarbon in recent years. However, the reduction of ammonia emission generated in the three-way catalyst is pressing issue. In EURO 7, ammonia will also be subject to the Real Driving Emissions regulation, and its emissions must be reduced. Previous studies have shown that ammonia emissions are higher under fuel-rich conditions, suggesting that differences in driving behavior have a significant impact on ammonia emissions in real-world driving, which includes various driving environments. In this study, driving tests were conducted on a direct- injection gasoline vehicle equipped with a three-way catalyst and Portable Emission Measurement System and Sensor-based Emission Measurement System to investigate the actual ammonia emissions on actual roads.
Technical Paper

Effect of Olefin Content in Gasoline on Knock Characteristics and HCHO Emission in Lean Burn Spark Ignition Engine

2023-09-29
2023-32-0083
In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock performance. The experiments were performed using a single-cylinder engine for 6 fuel types including gasoline blends which have difference in RON varying between 90.4 and 100.2. The results showed that adding olefin content to the premium gasoline provided unfavorable effect on auto-ignition as the auto-ignition happened at unburned gas temperature of 808 K which was 52 K lower at excess air of 2.0. Thus, it reduced anti-knock performance.
Technical Paper

Research on Super-Lean Burn Spark Ignition Engine with In-Cylinder Water Injection using Gasoline Surrogate Fuels

2023-09-29
2023-32-0055
The combination of super-lean burn spark ignition engine (excess air ratio λ ≈ 2) and in-cylinder water injection (WI) makes it possible to achieve thermal efficiency higher than 50%. Toward future fuel diversification including carbon-neutral fuels, technologies to improve SI engine thermal efficiency applicable to various fuels are required. In this study, the effect of in-cylinder WI on SI engine performance with a compression ratio of 17 and λ = 1.85 is investigated using premium gasoline, 5 components surrogate fuels for premium gasoline (S5H), and for regular gasoline (S5R). In the case of premium gasoline and S5H, spark timing can be advanced to MBT (minimum advance for best torque) by WI and gross indicated thermal efficiency (gITE) increases to 51.2% (premium gasoline) at water/fuel weight ratio (W/F) = 57.7% and 50.8% (S5H) at W/F = 62.9%. In the case of S5R, on the other hand, a strong knock forces a large spark retard at no-water condition.
Technical Paper

Real World Emissions Analysis Using Sensor-based Emissions Measurement System for Light-duty Direct-Injection Gasoline Vehicle

2022-03-29
2022-01-0572
In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.
Technical Paper

Study on Fuel-Saving Durability of Ultra-Low Viscosity 0W-8 Gasoline Engine Oil

2021-04-06
2021-01-0566
The JASO GLV-1 standard was introduced in Japan for 0W-8 ultra-low viscosity gasoline engine oil to improve fuel economy. Fuel economy targets are specified for new oil but not for aged oil. In contrast, Sequence VI in the ILSAC GF-6 standard requires fuel economy improvement for both new and aged oils. This test simulates fuel economy improvement after 6400 km (FEI 1) and 16000 km (FEI 2) of driving based on US fuel economy certification testing. Currently, 0W-8 is not included in the ILSAC standard and the fuel-saving durability of 0W-8 has not been investigated. To include ultra-low viscosity oil like 0W-8 in future engine oil standards, it is necessary to know its fuel-saving durability and to examine the evaluation test method. This study focused on the fuel-saving durability of 0W-8 with or without the Mo friction modifier and considered the evaluation method.
Technical Paper

Investigation on Effect of Offset Orifice Nozzle on Diesel Combustion Characteristics

2020-09-15
2020-01-2038
Compression ignition engines provide superior thermal efficiency over other internal combustion engines. Unfortunately the combustion process is diffusive combustion, meaning a lot of fuel is impinged the on the piston and cylinder wall. This creates cooling loss coupled with smoke, CO and THC. Minimization of the nozzle orifice diameter is a simple method widely used to shorten spray penetration. However, decreasing the nozzle orifice diameter also decreases fuel flow rate resulting in a prolonged injection and combustion process and reducing thermal efficiency. An offset orifice nozzle causes less fuel impingement by shorter fuel spray penetration without significant reduction of fuel flow rate. The offset orifice nozzle was made by shifting its alignment from the center of the sac to the edge of the sac following the swirl direction. A counterbore design was applied to maintain constant orifice length.
Technical Paper

Stereoscopic Micro-PIV Measurement of Near-Wall Velocity Distribution in Strong Tumble Flow under Motored SI Engine Condition

2020-09-15
2020-01-2019
In a state-of-the-art lean-burn spark ignition engine, a strong in-cylinder flow field with enhanced turbulence intensity is formed, and understanding the wall heat transfer mechanism of such a complex flow is required. The flow velocity and temperature profiles inside the wall boundary layer are strongly related to the heat transfer mechanism. In this study, two-dimensional three-component (2D3C) velocity distribution near the piston top surface was measured during the compression stroke in a strong tumble flow using a rapid compression and expansion machine (RCEM) and a stereoscopic micro-PIV system. The bore, stroke, compression ratio, and compression time were 75 mm, 128 mm, 15, and 30 ms (equivalent to 1000 rpm), respectively.
Journal Article

Evaluation of Mechanism for EGR Deposit Formation Based on Spatially- and Time-Resolved Scanning-Electron-Microscope Observation

2020-09-15
2020-01-2027
Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide emissions. To meet the strict emission regulations, e.g., Real Driving Emissions, the EGR system is required to be used at temperatures lower than the present ones. However, under cool conditions, an adhesive deposit forms on the EGR valve or cooler because of the particulate matter and other components present in the diesel exhaust. This causes sticking of the EGR valve or degradation of the heat-exchange performance, which are serious problems. In this study, the EGR deposit formation mechanism was investigated based on spatially- and time-resolved scanning electron microscopy (SEM) observation. The deposit was formed in a custom-made sample line using real exhaust emitted from a diesel engine. The exhaust including soot was introduced into the sample line for 24 h (maximum duration), and the formed deposit was observed using SEM.
Technical Paper

Real-World Emission Analysis Methods Using Sensor-Based Emission Measurement System

2020-04-14
2020-01-0381
Every year, exhaust gas regulations are getting stricter with the intention to solve the average air pollution problem, however, local roadside pollution is still a pressing issue. In order to solve this local roadside pollution problem, it is necessary to evaluate and/or predict “where” and “how much” pollutants such as NOx are emitted. To predict the local roadside pollution, it is necessary to collect emissions data from various kinds of vehicles driving on real-world and analyze them. In recent years, Real Driving Emission regulations using PEMS (Portable Emission Measurement System) have been introduced mainly in Europe. A typical PEMS configuration can weigh close to 100 kg however, and its weight affects the driving conditions of vehicles running on actual roads. In this study, we focused on the analysis of real-world emissions using SEMS (Sensor-based Emission Measurement System).
Journal Article

Combustion Characteristic of Offset Orifice Nozzle under Multi Pulse Ultrahigh Pressure Injection and PCCI Combustion Conditions

2020-01-24
2019-32-0522
CI engines provide higher thermal efficiency compared to other internal combustion engines. On the other hand large amounts of smoke and NOx are produced during combustion. Smoke and NOx can be reduced by applying Premixed Charge Compression Ignition (PCCI) combustion. Unfortunately, the problems of PCCI combustion include unstable start of combustion and limited operating range. The multi-pulse ultrahigh pressure injection allows fuel to control PCCI combustion. The objective of offset orifice nozzle is to improve mixture formation and shorten spray penetration in order to increase thermal efficiency and control PCCI combustion. The offset orifice nozzle was designed by shift orifice aliment from into the sac center to edge of sac follow swirl direction. Counter bore design was applied to offset orifice nozzle in order to keep the constant orifice length as standard nozzle.
Technical Paper

Investigation on Premixed Charge Compression Ignition Combustion Control Using Multi Pulse Ultrahigh Pressure Injection

2019-04-02
2019-01-1155
Compression ignition (CI) engines provide higher thermal efficiency compared to other internal combustion engines although large amounts of NOx and soot are produced during combustion. NOx and soot emissions can be reduced by using Premixed Charge Compression Ignition (PCCI) combustion. However, the problems of PCCI combustion include limited operating range, unstable start of combustion and an increase in combustion noise. The multi-pulse ultrahigh pressure injection allows fuel to be injected near TDC, improving mixture formation and enhancing the possibility to extend the operating range of PCCI combustion. The objective of this paper is to control and extend the operating range of PCCI combustion using multi-pulse ultrahigh pressure injection. This has not been studied before. Combustion characteristics were investigated using apparent rate of heat release analysis, heat balance analysis, exhaust emission measurement and soot concentration measurement.
Technical Paper

A Cycle-to-Cycle Variation Extraction Method for Flow Field Analysis in SI IC Engines Based on Turbulence Scales

2019-01-15
2019-01-0042
To adhere to stringent environmental regulations, SI (spark ignition) engines are required to achieve higher thermal efficiency. In recent years, EGR (exhaust gas recirculation) systems and lean-burn operation has been recognized as key technologies. Under such operating conditions, reducing CCV (cycle-to-cycle variation) in combustion is critical to the enhancement of overall engine performance. Flow-field CCV is one of the considerable factors affecting combustion in engines. Conventionally, in research on flow fields in SI engines, the ensemble average is used to separate the measured velocity field into a mean component and a fluctuation component, the latter of which contains a CCV component and a turbulent component. To extract the CCV of the flow field, previous studies employed spatial filter, temporal filter, and POD (proper orthogonal decomposition) methods.
Technical Paper

Heat Transfer Analysis in a Diesel Engine Based on a Heat Flux Measurement Using a Rapid Compression and Expansion Machine

2017-11-05
2017-32-0115
To investigate the heat transfer phenomena inside the combustion chamber of a diesel engine, a correlation for the heat transfer coefficient in a combustion chamber of a diesel engine was investigated based on heat flux measured by the authors in the previous study(8) using the rapid compression and expansion machine. In the correlation defined in the present study, thermodynamically estimated two-zone temperatures in the burned zone and the unburned zone are applied. The characteristic velocity given in the correlation is related to the speed of spray flame impinging on the wall during the fuel injection period. After the fuel injection period, the velocity term of the Woschni’s equation is applied. It was shown that the proposed correlation well expresses heat transfer phenomena in diesel engines.
Technical Paper

Effect of Biofuel and Soot on Metal Wear Characteristic Using Electron Microscopy and 3D Image Processing

2017-11-05
2017-32-0095
The soot contamination in used engine oils of diesel engine vehicles was about 1% by weight. The soot and metal wear particle sizes might be in the range of 0-1 µm and 1-25 µm, respectively. The characteristics of soot affecting on metal wear was investigated. Soot particle contamination in diesel engine oil was simulated using carbon black. Micro-nanostructure of soot particles were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and laser diffraction spectroscopy (LDS). The metal wear behavior was studied by means of a Four-Ball tribology test with wear measured. Wear roughness in micro-scale was investigated by high resolution optical microscopy (OM) , 3D rendering optical technique and SEM image processing method. It was found that the ball wear scar diameter increased proportionally to the soot primary particle size. The effect of biodiesel contamination were also increasing in wear scar diameter.
Technical Paper

Impact of Biodiesel on Small CI Engine Combustion Behavior and Particle Emission Characteristic

2017-11-05
2017-32-0094
Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.
Technical Paper

The Effect of Exhaust Gas Recirculation on Performance and Emission of Ethanol Fumigated Diesel Engine

2017-11-05
2017-32-0101
Primary energy source such as fossil fuel keep decreasing due to various kind of usage. According to less amount of the fossil fuel, human seeks for an alternative fuel source such as alcohol. Alcohol like ethanol can be produced easily from strarchy plant. But using alcohol as blended fuel with diesel fuel doesn't work well because alcohol has low cetane number, lack of lubricity and very low miscibility with diesel fuel. To overcome this, fumigation system or port fuel injection of alcohol seems interesting. Although it requires more complicate system but it can compensate the miscibility issue and alcohol can be used in higher dose to give more energy. Diesel engine produces a lot of emission such as NOx and some other carbon content emission like HC, CO and soot due to they run in lean condition as their characteristic. Modern diesel engines are now coupled with exhaust gas recirculation system to help reduce in main emission like NOx.
Journal Article

Kinetic Modeling Study of NOx Conversion Based on Physicochemical Characteristics of Hydrothermally Aged SCR/DPF Catalyst

2017-10-08
2017-01-2386
Diesel engines have better fuel economy over comparable gasoline engines and are useful for the reduction of CO2 emissions. However, to meet stringent emission standards, the technology for reducing NOx and particulate matter (PM) in diesel engine exhaust needs to be improved. A conventional selective catalytic reduction (SCR) system consists of a diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and urea-SCR catalyst. Recently, more stringent regulations have led to the development of SCR systems with a larger volume and increased the cost of such systems. In order to solve these problems, an SCR catalyst-coated DPF (SCR/DPF) is proposed. An SCR/DPF system has lower volume and cost compared to the conventional SCR system. The SCR/DPF catalyst has two functions: combustion of PM and reduction of NOx emissions.
Journal Article

Investigation of Mechanism for Formation of EGR Deposit by in situ ATR-FTIR Spectrometer and SEM

2016-10-17
2016-01-2351
Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide (NOx) emissions. However, a lacquer is formed on the EGR valve or EGR cooler due to particulate matter and other components present in diesel exhaust, causing serious problems. In this study, the mechanism of lacquer deposition is investigated using attenuated total reflection Fourier transform infrared spectrometry (ATR-FTIR) and scanning electron microscopy (SEM). Deposition of temperature-dependent lacquers was evaluated by varying the temperature of a diamond prism between 80 and 120 °C in an ATR-FTIR spectrometer integrated into a custom-built sample line, which branched off from the exhaust pipe of a diesel engine. Lacquers were deposited on the diamond prism at 100 °C or less, while no lacquer was deposited at 120 °C. Time-dependent ATR-FTIR spectra were obtained for approximately 2 h from the beginning of the experiment.
Technical Paper

Measurement of Sound Speed in DME in a Wide Range of Pressure and Temperature Including the Critical Point

2016-10-17
2016-01-2258
Dimethyl ether (DME) is a promising alternative fuel for compression ignition (CI) engines. DME features good auto ignition characteristics and soot-free combustion. In order to develop an injection system suitable for DME, it is necessary to understand its fuel properties. Sound speed is an important fuel property that affects the injection characteristics. However, the measurement data under high-pressures corresponding to those in fuel injection systems are lacking. The critical temperature of DME is lower than that of diesel fuel, and is close to the injection condition. It is important to understand the behavior of the sound speed around the critical point, since the sound speed at critical point is extremely low. In this study, sound speed in DME in a wide pressure and temperature range of 1 MPa to 80 MPa, 298.15 K to 413.15 K, including the vicinity of the critical point, was measured. The sound speed in DME decreases as either the pressure falls or the temperature rises.
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