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Awareness of environmental protection with respect to the particulate number (PN) in the exhaust emissions of gasoline direct injection (GDI) engine vehicles has increased. In order to decrease the emission of particulate matter (PM), suppressing emissions by improving engine combustion, and/or filtering PM with a gasoline particulate filter (GPF) is effective. This paper describes the improvement of the coated GPF to reduce pressure drop while securing three-way performance and PN filtration efficiency. It was necessary to load a certain amount of washcoat on the GPF to add the three-way function, but this led to an increase in pressure drop that affected engine power. The pressure drop was influenced by the gas permeation properties of the filter wall.

When vehicles run on the flooded road, water enters to the engine compartment and sometimes reaches the position of the air intake duct and electrical parts and causes the reliability problems. Numerical simulation is an effective tool for this phenomenon because it can not only evaluate the water level before experiment but also identify the intrusion route. Recently, the gap around the engine cooling modules tends to become smaller and the undercover tends to become bigger than before in order to enhance the vehicle performance (e.g., aerodynamics, exterior noise). Leakage tightness around the engine compartment becomes higher and causes an increase of the buoyancy force from the water. Therefore the vehicle attitude change is causing a greater impact on the water level. This paper describes the development of a water level prediction method in engine compartment while running on the flooded road by using the coupled multibody and fluid dynamics.

Computational fluid dynamic (CFD) is widely used to develop engine combustion. Especially the in-cylinder spray calculation is important in order to resolve the issues of direct injection gasoline engines (e.g., particulate matter (PM) and oil dilution caused by fuel wetting on the cylinder walls). Conventional spray calculation methods require fitting based on measurements of spray characteristics such as penetration and droplet diameter (i.e., the Sauter mean diameter (SMD)). Particularly in the case of slit nozzle shapes that widen from the inlet to the outlet to form a fan-shaped spray, fitting the shape of spray is a complex procedure because the flow inside the nozzle is not uniform. In response, a new calculation method has been developed that eliminates the need for spray shape fitting by combining calculations of the Eulerian multiphase and the Lagrangian multiphase.

This paper presents typical flow structures around a 60%-scale wind-tunnel model of a Formula One (F1) car, using planar particle image velocimetry (PIV). The customized PIV system is permanently installed in a wind tunnel to help aerodynamicists in the development loop. The PIV results enhance the understanding of the mean velocity field in the two-dimensional plane in some important areas of the car, such as the front-wheel wake and the underfloor flow. These real phenomena obtained in the wind tunnel also help maintain the accuracy of simulations using computational fluid dynamics (CFD) by allowing regular checking of the correlation with the real-world counterpart. This paper first surveys recent literature on unique flow structures around the rotating exposed wheel, mostly that on the isolated wheel, and then gives the background to F1 aerodynamics in the late 2000s.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

Alcohol fuels that can be produced from cellulose continue to become more widely used in gasoline engines. This research investigated the application of alcohol to diesel engines with the aims of improving the combustion of diesel engines and of utilizing alternative fuels. Two methods were compared, a method in which alcohol is injected into the air intake system and a method in which alcohol is blended in advance into the diesel fuel. Alcohol is an oxygenated fuel and so the amount of soot that is emitted is small. Furthermore, blended fuels have characteristics that help promote mixture formation, which can be expected to reduce the amount of soot even more, such as a low cetane number, low viscosity, low surface tension, and a low boiling point. Ethanol has a strong moisture-absorption attribute and separates easily when mixed with diesel fuel. Therefore, 1-butanol was used since it possesses a strong hydrophobic attribute and does not separate easily.

Exhaust emissions are well known to have adverse impacts on human health. Studies have demonstrated that there is an association between ambient particulate matter (PM) levels and various harmful cardiopulmonary conditions. Soot exhaust from diesel engines can be a significant contributor to airborne pollutants. A key component in PM level control for a diesel engine is a diesel particulate filter (DPF). This device traps soot while allowing other exhaust gases to pass unhindered. However, the performance of diesel particulate filters can change with increasing soot loadings and thus may require regeneration or replacement. Improved understanding of diesel particulate filters is dependent upon the knowledge of the actual soot loading and the soot distribution within the DPF. Neutron radiography (NR) has been identified as an effective means of non-destructively identifying hydrogen or carbon adsorbed in PM.

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.

Gas To Liquid (GTL) fuels synthesized from natural gas are known as clean fuels. Therefore, GTL fuels have been expected to be a promising option that can reduce the NOx and PM emissions from diesel engines and contribute to the energy security. In this study, in order to clarify the emission reduction potentials, the improvement of DI diesel engine and aftertreatment systems were investigated by utilizing GTL fuels characteristics. To achieve a further reduction of both NOx and PM emissions, the combustion chamber, injection pattern and EGR calibration were modified. From the results of tests, the engine out NOx emissions were reduced to the Euro 6 regulation level and in parallel the expected deteriorations of HC emission and fuel consumption were suppressed because of the characteristics of high cetane number and zero poly-aromatics hydrocarbons. Additionally, an aftertreatment system was optimized to GTL fuel in order to improve NOx conversion efficiency.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.

Both carbon blacks and carbon nano-onions nanoparticles have a spheroidal shape and a nested structure. They can be used to simulate the presence of soots in used engine oils. When added to fully formulated fresh engines oils, these two kinds of particles behave very differently. Carbon black particles are highly abrasive causing a lot of wear of steel surfaces and friction increases. At the opposite, the addition of carbon onions in lubricant leads to a reduction of both friction and wear compared to pure base oil. This shows that there is an opportunity to control wear in engines by changing the structure of soots during the combustion process.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. The DPNR has been developed under the Toyota D-CAT (Diesel Clean Advanced Technology) concept. Further improvement of the DPNR is hoped for cleaner air in the future. This paper reviews the results of our study to improve the NOx purification performance on the DPNR. The NOx reduction performance of the catalysts deteriorates due to thermal deterioration and sulfur poisoning. In order to improve the thermal resistance of the catalysts, the suppression of precious metal sintering in the catalyst has been studied. As a result, higher catalytic activity after aging especially under lower temperature conditions was obtained. On the other hands, improvement of desulfurization performance is one of the key technologies in order to keep the high NOx reduction capability of the catalyst.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

The Diesel Particulate and NOx Reduction System (DPNR) is an effective technology as a diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. However, it requires desulfurization control since the DPNR catalyst is poisoned by sulfur components in the exhaust gas from the fuel and lubricant. Desulfurization control causes some degree of fuel penalty and thermal deterioration of the DPNR catalyst because it requires control of rich air fuel ratio and high temperature simultaneously. In this paper, we investigated a new system with a sulfur trap catalyst which can trap sulfur components included in the exhaust gas as sulfates (Sulfur trap DPNR). In this system, desulfurization control is not performed because the sulfur poisoning of the DPNR catalyst is drastically suppressed by the sulfur trap catalyst. In the present DPNR, periodic desulfurization control is required.

Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the “dual DPNR”) consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).