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Technical Paper

Three-Way Catalytic Reaction in an Electric Field for Exhaust Emission Control Application

2021-04-06
2021-01-0573
To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.
Technical Paper

Study of Simple Detection of Gasoline Fuel Contaminants Contributing to Increase Particulate Matter Emissions

2020-04-14
2020-01-0384
The reduction of particulate emissions is one of the most important challenges facing the development of future gasoline engines. Several studies have demonstrated the impact of fuel chemical composition on the emissions of particulate matter, more particularly, the detrimental effect of high boiling point components such as heavy aromatics. Fuel contamination is likely to become a critical issue as new regulations such as Real Driving Emissions RDE involves the use of market fuel. The objective of this study is to investigate several experimental approaches to detect the presence of Diesel contamination in Gasoline which is likely to alter pollutant emissions. To achieve this, a fuel matrix composed of 12 fuels was built presenting diesel fuel in varying concentrations from 0.1 to 2% v/v. The fuel matrix was characterized using several original techniques developed in this study.
Technical Paper

Development of High Accuracy NOx Sensor

2019-04-02
2019-01-0749
This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.
Technical Paper

Application of Models of Short Circuits and Blow-Outs of Spark Channels under High-Velocity Flow Conditions to Spark Ignition Simulation

2018-09-10
2018-01-1727
This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.
Technical Paper

Critical Analysis of PM Index and Other Fuel Indices: Impact of Gasoline Fuel Volatility and Chemical Composition

2018-09-10
2018-01-1741
Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.
Technical Paper

The New Toyota Inline 4-Cylinder 2.5L Gasoline Engine

2017-03-28
2017-01-1021
In order to adapt to energy security and the changes of global-scale environment, further improvement of fuel economy and adaptation to each country’s severer exhaust gas emission regulation are required in an automotive engine. To achieve higher power performance with lower fuel consumption, the engine’s basic internal design such as an engine block and cylinder head were changed and the combustion speed was dramatically increased. Consequently, stroke-bore ratio and valve layout were optimized. Also, both flow coefficient and intake tumble ratio port were improved by adopting a laser cladded valve seat. In addition, several new technologies were adopted. The Atkinson cycle using a new Electrical VVT (Variable Valve Timing) and new combustion technology adopting new multi-hole type Direct fuel Injector (DI) improved engine power and fuel economy and reduced exhaust emissions.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
Journal Article

An Application of Shape Optimization to Brake Squeal Phenomena

2015-09-27
2015-01-2658
The present paper describes an application of non-parametric shape optimization to disc brake squeal phenomena. A main problem is defined as complex eigenvalue problem in which the real part of the complex eigenvalue causing the brake squeal is chosen as an objective cost function. The Fre´chet derivative of the objective cost function with respect to the domain variation, named as the shape derivative of the objective cost function, is evaluated using the solution of the main problem and the adjoint problem. A selection criterion of the adoptive mode number in component mode synthesis (CMS), which is used in the main problem, is presented in order to reduce the computational error in complex eigenvalue pairs. A scheme to solve the shape optimization problem is presented using an iterative algorithm based on the H1 gradient method for reshaping. For an application of the optimization method, a numerical example of a practical disc brake model is presented.
Technical Paper

Development of Advanced Three-Way Catalyst with Improved NOx Conversion

2015-04-14
2015-01-1005
Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.
Technical Paper

Development of NSR and DiAir System to Achieve Clean Emissions under Transient Cycle

2014-10-13
2014-01-2809
In this paper, a control strategy to switch NSR (NOx storage and reduction) function from standard DeNOx by rich combustion to DiAir (Diesel NOx After-treatment by Adsorbed Intermediate Reductants) and additional advantages to use HCI (Hydrocarbon Injector) during desulfation were introduced. Investigations under a transient cycle suggest that NOx conversion with DiAir is strongly affected by preliminary NOx storage condition in the NSR catalyst. To avoid NOx breakthrough just after starting HC dosing for DiAir, a rich operation to reduce stored NOx was shown to be important and high NOx conversion could be maintained using this control strategy under a transient cycle. Furthermore, by combining HCI and in-cylinder post injection, usage of rich condition for NSR DeSOx can be expand to wider engine speed and load area.
Technical Paper

A Solid Particle Number Measurement System Including Nanoparticles Smaller than 23 Nanometers

2014-04-01
2014-01-1604
The particle number (PN) emission regulation has been implemented since 2011 in Europe. PN measurement procedure defined in ECE regulation No. 83 requires detecting only solid particles by eliminating volatile particles, the concentrations of which are highly influenced by dilution conditions, using a volatile particle remover (VPR). To measure PN concentration after the VPR, a particle number counter (PNC) which has detection threshold at a particle size of 23 nm is used, because most solid particles generated by automotive engines are considered to be larger than 23 nm. On the other hand, several studies have reported the existence of solid and volatile particles smaller than 23 nm in engine exhaust. This paper describes investigation into a measurement method for ultrafine PNCs with thresholds of below 23 nm and evaluation of the VPR performance for the particles in this size range. The detection efficiency of an ultrafine PNC was verified by following the ECE regulation procedure.
Technical Paper

Economy with Superior Thermal Efficient Combustion (ESTEC)

2014-04-01
2014-01-1192
From the time the first Hybrid Vehicle (HV) was launched, 17 years have past, and HV vehicles have boosted the global CO2 reduction trend. In order to maximize their merit, many HV engines focused on the best fuel consumption value namely thermal efficiency. This was because HV systems can control the operating area of engine and get merit. However, considering climate change and energy issues, it is important to focus conventional vehicle as well as HV vehicle progress. The Atkinson cycle with a high compression ratio is the typical approach that HV engines use to enhance thermal efficiency. However, the drawback of the high compression ratio is a reduction of engine torque. Thermal efficiency at low load areas is relatively more important with conventional engines than with HV engines and how to overcome these issues is significantly important with conventional engines.
Technical Paper

Influence of Engine Oil Properties on Soot Containing Deposit Formation in Turbocharger Compressor

2013-10-14
2013-01-2500
Due to increasing demands for further CO2 reduction and tighter exhaust emissions regulations, automakers are increasingly downsizing turbo-charged diesel engines by raising specific power, or adopting low-pressure loop exhaust gas recirculation (LPL-EGR) systems to improve the EGR rate. However, adopting a higher boost pressure to increase the specific power, or introducing hot exhaust gas before the turbocharger compressor with the LPL-EGR system creates higher gas temperatures in the compressor, which results in soot-containing deposits derived from the engine oil in the compressor. This phenomenon causes significant deterioration of turbocharger efficiency. Therefore, countermeasures such as restricting boost pressure or limiting EGR usage in the operational map are necessary to prevent engine performance deterioration. Increasing the gas temperature in the compressor while preventing deposit formation should enable further improvements in fuel consumption and engine power.
Technical Paper

Validation Test Result Analysis of Plug-in Hybrid Vehicle

2013-04-08
2013-01-1464
In recent years, many various energy sources have been investigated as replacements for traditional automotive fossil fuels to help reduce CO2 emissions, respond to instabilities in the supply of fossil fuels, and reduce emissions of air pollutants in urban areas. Toyota Motor Corporation considers the plug-in hybrid vehicle (PHV), which can efficiently use electricity supplied from infrastructure, to be the most practical current solution to these issues. For this reason, Toyota began sales of the Prius Plug-in Hybrid in 2012 in the U.S., Europe and Japan. This is the first PHV to be mass-produced by Toyota Motor Corporation. Prior to this, in December 2009, Toyota sold 650 PHVs through lease programs for validation testing in the U.S., Europe and Japan. Additional 30 PHVs were introduced in China in March 2011 for the same objective.
Technical Paper

Development of DISI Engine Utilizing a Fan-Shaped Spray Jet

2013-04-08
2013-01-0260
A new combustion concept for DISI gasoline engine was developed to achieve superior performances of high power and low environmental load. It realizes a high specific power and a good lean combustion performance simultaneously by utilizing a DI spray jet effectively to accelerate the in-cylinder tumble flow. Injection direction and configuration of the DI spray was optimized for intensification of the in-cylinder flow and high mixture homogeneity, a thin fan-shaped spray generated by a slit nozzle was adopted. As a result, combustion was accelerated by increase of in-cylinder turbulence intensity, and homogeneity of air-fuel mixture was improved. In addition, in-cylinder fuel wall wetting, which causes emission of particulate matter (PM) and oil dilution, was drastically reduced by improvement of the fan-shaped spray.
Journal Article

Study of Diesel Engine System for Hybrid Vehicles

2011-08-30
2011-01-2021
In this study, we combined a diesel engine with the Toyota Hybrid System (THS). Utilizing the functions of the THS, reducing engine friction, lowering the compression ratio, and adopting a low pressure loop exhaust gas recirculation system (LPL-EGR) were examined to achieve both low fuel consumption and low nitrogen oxides (NOx) emissions over a wide operating range. After applying this system to a test vehicle it was verified that the fuel economy greatly surpassed that of a conventional diesel engine vehicle and that NOx emissions could be reduced below the value specified in the Euro 6 regulations without DeNOx catalysts.
Journal Article

Measurement of Oil Film Thickness in the Main Bearings of an Operating Engine using Thin-Film Electrode

2011-08-30
2011-01-2117
Oil film thickness is one of the most important issues for optimization of bearing design. A technique has been developed to measure oil film thickness by noting the change in capacitance between the shaft and a thin-film electrode of several micrometers thickness formed on the surface of a bearing. The authors applied this technique to the main journals of an automobile engine and measured the oil film thickness up to maximum speed and full load. The oil film thickness became thinner with increased engine load, and then turned thicker with increased engine speed.
Journal Article

Development of Di-Air - A New Diesel deNOx System by Adsorbed Intermediate Reductants

2011-08-30
2011-01-2089
An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.
Journal Article

Development of an On-Board PM Sensor for the OBD System Based on an Electrochemical Polarization

2011-08-30
2011-01-2059
An on-board particulate matter (PM) sensor, consisting of a gas-permeable electrochemical cell with a porous yttria-stabilized zirconia solid oxide electrolyte, was developed to assist the on-board diagnostics (OBD) system of a vehicle. Exhaust is pumped from the anode side to the cathode side and PM deposited on the anode is instantly oxidized by the catalytic effects of the metal component of the electrode at temperatures higher than 350°C. The PM oxidation reaction occurs at the three-phase boundary between the anode, electrolyte and gas phase, and causes a slight change in the bulk average oxygen concentration, which produces electrochemical polarization by the difference in oxygen partial pressures between the anode and cathode. The developed PM sensor has a detection limit of 2 mg/m₃, at which level will enable PM detection in the OBD system according to the EURO VI regulation.
Technical Paper

Combustion Improvement of CNG Engines by Hydrogen Addition

2011-08-30
2011-01-1996
This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.
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