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In order to adapt to energy security and the changes of global-scale environment, further improvement of fuel economy and adaptation to each country’s severer exhaust gas emission regulation are required in an automotive engine. To achieve higher power performance with lower fuel consumption, the engine’s basic internal design such as an engine block and cylinder head were changed and the combustion speed was dramatically increased. Consequently, stroke-bore ratio and valve layout were optimized. Also, both flow coefficient and intake tumble ratio port were improved by adopting a laser cladded valve seat. In addition, several new technologies were adopted. The Atkinson cycle using a new Electrical VVT (Variable Valve Timing) and new combustion technology adopting new multi-hole type Direct fuel Injector (DI) improved engine power and fuel economy and reduced exhaust emissions.

This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.

As the demand for improved fuel economy increases and new CO2 regulations have been issued, aerodynamic drag reduction has become more critical. One of the important factors to consider is cooling drag. One way to reduce cooling drag is to decrease the air flow volume through the front grille, but this has an undesirable impact on cooling performance as well as component heat load in the under-hood area. For this reason, cooling drag reduction methods while keeping reliability, cooling performance and component heat management were investigated in this study. At first, air flow volume reduction at high speed was studied, where aerodynamic drag has the greatest influence. For vehicles sold in the USA, cooling specification tends to be determined based on low speed, while towing or driving up mountain roads, and therefore, there may be extra cooling capacity under high speed conditions.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

It may be possible to simplify the structure and control systems of a lithium-ion battery by replacing the conventional liquid electrolyte with a solid electrolyte, resulting in higher energy density. However, power performance is a development issue of batteries using a solid electrolyte. To increase battery power performance, in addition to lithium ionic conductivity within the bulk of the electrolyte, it is also necessary to boost the lithium ionic conductivity at the interface between the electrode active material and the electrolyte, and to boost electron and lithium ionic conductivity within the cathode and anode active material. This research studied the mechanism of resistance reduction by electrode surface modification. Subsequently, this research attempted to improve electron conductivity by simultaneously introducing oxygen vacancies and carrying out nitrogen substitution in the crystalline structure of the Li4Ti5O12 anode active material.

Vehicles have been more required to save energy against the background of the tendency of ecology. As the result of improving efficiency of internal combustion engines and adoption of electric power train, heat loss from engine coolant, which is used to heat the cabin, decreases and consequently additional energy may be consumed to maintain thermal comfort in the passenger compartment in winter. This paper is concerned with the humidity control system that realizes reduction of ventilation heat loss by controlling recirculation rate of the HVAC system by using highly accurate humidity sensor to evaluate risk of fogging on the windshield. As the results of the control, fuel consumption of hybrid vehicles decreases and maximum range of electric vehicles increases.

A full vehicle multi-body dynamic (MBD) model with suspension control system is developed for fatigue life prediction under rough road condition. The model consists of tires, a trimmed body, heavy attached parts, powertrain, suspension, joints, and a driver model, and includes a suspension control system that varies characteristics of the suspension according to the rough road inputs. For tires, a commercial MBD tire model is employed with identifiable parameters. The models are simulated to run on the optically measured road surface of the proving ground. Apart from the trimmed body, several important heavy attached parts are modeled separately, that represent dynamic behavior that induces complex body input load. These parts, along with suspension and powertrain systems are connected to the body using nonlinear elements such as joints, springs, and dampers. Contact conditions are used to represent mount bushing, hood lock, stopper rubber, etc.

Multi-cylinder hydrogen-absorbing alloy tanks for fuel cell vehicles have 10 to 40 metallic cylinders that are bundled and filled with hydrogen-absorbing alloy. In this system, the cylinders themselves act as a heat exchanger and the working pressure is lowered to 10 to 20 MPa compared with high-pressure MH tanks. Moreover, both heat conduction and mass reduction can be achieved by reducing the wall thickness of the cylinders. A model verification experiment was conducted using a one-quarter-scale prototype of a full size tank, and a conduction simulation model verified in the experiment was used to predict the performance of the full size tank. Results showed that it is possible to fill the tank with hydrogen to 80% of its capacity in a five-minute filling time, although issues related to heat conductivity performance require improvement. Accordingly, it may be possible to adopt this tank as part of a system if the storage amount of the hydrogen-absorbing alloy can be increased.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Diamond-like carbon (DLC) coating has excellent properties like high hardness and low friction. So it has attracted considerable attention in recent years as a low-friction coating material. However, some DLC coatings display increased wear in oil containing Mo-DTC (Molybdenum-dithiocarbamates). Wear analyses of sliding surface after block-on-ring tests were conducted suggest that the decomposition product from Mo-DTC, MoO3, reacts with active sites in the DLC to promote the wear of DLC.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

In this paper, the authors have developed a new measuring method of the liquid fuel film thickness on walls, such as intake ports, the combustion chamber and cylinder liner of a Port Fuel Injection (PFI) engine, and clarified the fuel film behavior under various running conditions when Fiber-based Laser-Induced Fluorescence (Fiber-based LIF) was applied to the newly developed method. The thickness of the fuel film is measured by detecting the intensity of fluorescence from the film that is irradiated by a He-Cd laser. A single optical fiber is used to simultaneously transmit the laser beam and the fluorescence from the film. In addition, the S/N ratio of the fluorescence is improved by using a He-Cd laser of which the wavelength (λ=442nm) is able to efficiently irradiate test fuel doped 2-3-butandione. Using this method, the fuel film thickness on the wall of the PFI engine was analyzed in two case studies.

We developed a new Manual Transmission Gear Oil (MTF) named LV for improved fuel economy and CO2 reduction. MTF LV is a low viscosity fluid to reduce stir losses at lower temperatures. In general, low viscosity fluids can cause metal fatigue, wear and seizure. The MTF LV was designed to overcome these problems by maintaining the oil film thickness after it is deteriorated and improving the wear characteristics with additives. As a result, the MTF LV provides equal or better durability than the current MTF. In addition, it also has good performance at low temperatures, better shift feeling characteristics, and improved oxidation stability.

It is important to reduce the viscosity of automatic transmission fluid (ATF) in order to improve fuel economy. However, in general, low viscosity fluid can cause metal fatigue, wear, and seizure. It is necessary to increase the viscosity of the fluid at higher temperatures to maintain the durability of the automatic transmission (AT). The key point is the selection of the base oil and the viscosity index improver (VII) with both a high viscosity index (VI) and excellent shear stability. On the basis of this concept, a new generation high performance ATF named WS was developed. WS can achieve the highest level of fuel economy, while maintaining the durability of the AT.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

The tendency of spark ignition direct injection (SIDI) engines to form injector deposits was investigated using engine dynamometer tests on a SIDI engine equipped with fan spray type injectors. Fifteen test fuels with varying 90% distillation temperature (T90), aromatics, olefins, oxygenates and sulfur levels were prepared to identify the effects of fuel properties on injector deposits. The results suggested that not only the T90 but also the number of alkyl substituent of aromatics had effects on injector deposit formation. Effects of detergents on the injector deposit cleanliness were also evaluated in this study.

The transfer efficiency for painting processes utilizing water-borne materials is low, and the residual paint is disposed of as waste. In this study, we focused on a recycling system to collect and dissolve the paint over-spray in the booth water, and to concentrate and regenerate it by means of an ultra filter (UF). Paint adaptable to the recycling system has been developed by providing compatibility between the high hydrophilicity of liquid paint and the high hydrophobicity of the paint film, in order to ensure the recyclability and the high anti-corrosion performance required of paint on automobile underbody parts. This recycling technology is used in an actual propeller shaft painting process and provides large waste reduction and a decrease in painting cost.

Numerical 3-D simulations are performed for the improvement of the new direct injection gasoline engine. A solution based local grid refinement method has been developed in order to reduce the CPU time. This method has been incorporated into the CFD program (STAR-CD) with in-house spray and combustion models. Calculation results were compared with the experimental data taken by the LIF technique, and good agreement was obtained for the mixture formation and combustion processes. Some calculations were carried out for the fuel-air mixture formation process during late injection stratified combustion and the following results were obtained. The unburnt fuel has a tendency to remain in the side of the piston cavity at the latter part of the combustion period. To reduce the amount of unburnt fuel, it was shown that the combination of a thin thickness fan spray and compact cavity forms a spherical mixture, suitable for combustion.