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Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Journal Article

Experimental and Numerical Study on the Effect of Nitric Oxide on Autoignition and Knock in a Direct-Injection Spark-Ignition Engine

2022-08-30
2022-01-1005
Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.
Journal Article

Development of Strength Distributed Hot Stamp Parts

2019-04-02
2019-01-0522
1 Structural parts, such as the center pillar, are a multi-layer structure. They are a combination of high-strength panels and high-toughness panels, to control the deformation mode during a crash. If we can make this multi-layered structure as one panel, consisting of different hardness within it, we will be able to make a lightweight part. In this study, we have developed a method to fabricate a ‘lightweight center pillar’ with the following processes. First, the whole panel is hardened by quenching within the hot stamp process. Next, certain areas of the panel are softened by partial tempering. We have found that the temperature zone for softening is between A1 and A3, and it is easy to perform a rapid and accurate tempering by utilizing induction heating around the Curie temperature between A1 and A3 transformation temperature.
Journal Article

Development of Engine Lubrication System with New Internal Gear Fully Variable Discharge Oil Pump

2017-10-08
2017-01-2431
Over the past decades, the automotive industry has made significant efforts to improve engine fuel economy by reducing mechanical friction. Reducing friction under cold conditions is becoming more important in hybrid vehicle (HV) and plug-in hybrid vehicle (PHV) systems due to the lower oil temperatures of these systems, which results in higher friction loss. To help resolve this issue, a new internal gear fully variable discharge oil pump (F-VDOP) was developed. This new oil pump can control the oil pressure freely over a temperature range from -10°C to hot conditions. At 20°C, this pump lowers the minimum main gallery pressure to 100 kPa, thereby achieving a friction reduction effect of 1.4 Nm. The developed oil pump achieves a pressure response time constant of 0.17 seconds when changing the oil pressure from 120 kPa to 200 kPa at a temperature of 20°C and an engine speed of 1,600 rpm.
Technical Paper

Optimizing Transmission Loss for Lightweight Body Structures

2017-06-05
2017-01-1812
In an effort to reduce mass, future automotive bodies will feature lower gage steel or lighter weight materials such as aluminum. An unfortunate side effect of lighter weight bodies is a reduction in sound transmission loss (TL). For barrier based systems, as the total system mass (including the sheet metal, decoupler, and barrier) goes down the transmission loss is reduced. If the reduced surface density from the sheet metal is added to the barrier, however, performance can be restored (though, of course, this eliminates the mass savings). In fact, if all of the saved mass from the sheet metal is added to the barrier, the TL performance may be improved over the original system. This is because the optimum performance for a barrier based system is achieved when the sheet metal and the barrier have equal surface densities. That is not the case for standard steel constructions where the surface density of the sheet metal is higher than the barrier.
Journal Article

Analysis of Influence of Snow Melting Agents and Soil Components on Corrosion of Decorative Chrome Plating

2016-04-05
2016-01-0539
The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.
Technical Paper

Improvement of Adhesion Properties between Epoxy Resin and Primer and between Primer and Ni Plating in Hybrid Vehicle Power Semiconductor Module under High Temperature Conditions

2016-04-05
2016-01-0500
In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.
Journal Article

Multiplex Communication Protocol for Switch/Sensor/Actuator Network: “CXPI”

2016-04-05
2016-01-0057
The growing functionality and complexity of recent vehicle electronic systems have made inter-device communication (on-board LAN) technology vital to vehicle design. By field of application, the LAN (Local Area Network) systems currently in use are LIN (Local Interconnect Network) used for body systems, CAN (Controller Area Network) used for control systems, and MOST (Media Oriented Systems Transport ) used for multimedia and camera systems, and work to standardize the next-generation communication technology for each of those fields is underway. This paper provides a technical overview of the CXPI (Clock Extension Peripheral Interface) communication protocol, which satisfies the body system requirements (rapid response, system extensibility, high reliability, and low cost). It also presents the progress made on standardization at SAE and other organizations.
Technical Paper

Development of Side Impact Dummy FE Models using Reverse Engineering

2012-04-16
2012-01-0091
This paper describes the development of dummy FE models to be used for side impact simulations. The precise geometries of the ES-2re dummy and the SID-IIs dummy were measured at a pitch of 1.0 mm using X-ray CT scan. The material properties and the mechanical responses of the components were measured in static and dynamic tests and were used for the model validation. The models were further validated to US-NCAP side impact requirements. Good correlation was seen for both response time history, and to peak deformation values. It is shown that modeling the precise dummy internal structure in addition to the external geometry and applying accurate material properties enabled simulation of deformation kinematics and load transfer inside the dummies. As a result, it was possible to accurately simulate the injury value time histories in an actual test, and understand the mechanisms causing changes to the loading.
Technical Paper

A Study of Mixed-FAME and Trace Component Effects on the Filter Blocking Propensity of FAME and FAME Blends

2010-10-25
2010-01-2116
Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.
Technical Paper

Development of High-Strength Aluminum Piston Material

2010-04-12
2010-01-0220
Mass reduction of parts is growing in importance as a means for reducing CO2 emissions from vehicles.The aim of the present research was to contribute to further mass reduction of pistons by developing a new aluminum casting material with highest level of fatigue strength. This goal was achieved using a development concept of creating a homogeneous structure in which Ti was added to create a fine structure and appropriate quantities of Fe and Mn were added to form a compound that is stable at high temperatures. Stand-alone tests of prototype pistons fabricated using the developed material show that the material is 14% stronger than the conventional material, thereby enabling increases in power and mass reduction.
Technical Paper

Analysis of Degradation Mechanism of Lead-Free Materials

2009-04-20
2009-01-0260
The use of lead-free (Pb-free) solder and plating in onboard electronic components has accelerated rapidly in recent years, but solutions have yet to be found for the issues of whisker generation in tin (Sn) plating and crack initiation in Pb-free solder, despite widespread research efforts. Analysis of the whisker generation mechanism has focused on internal energy levels and crystal orientation, and analysis of the crack initiation mechanism in Pb-free solder has examined changes in the grain boundaries of Sn crystals.
Journal Article

Development of Hardening Depth Evaluation Technique using Eddy Current – Establishment and Introduction of In-line Hardening Depth Inspection System –

2009-04-20
2009-01-0867
A hardening depth evaluation technique using eddy current has been developed, which can be applied to a mass production line for destructive (cutting) inspections. Using this technique, changes in the hardness of the induction-hardened structure can be detected based on the changes in magnetic permeability. This technique reduces the thermal effect and improves measurement accuracy through a multi-frequency exciting method and a difference method algorithm.
Technical Paper

JCAPII Cross Check Tests of Fast Electrical Mobility Spectrometers for Evaluation of Accuracy

2007-10-29
2007-01-4081
Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.
Technical Paper

Improvement of NOx Storage-Reduction Catalyst

2007-04-16
2007-01-1056
In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.
Technical Paper

Hybrid Vehicles Lessons Learned and Future Prospects

2006-10-16
2006-21-0027
There exist many environmental and earth resource problems to be solved for the 21st century. Hybridization of both internal combustion powertrains and fuel cell powertrains holds great promise for next generation vehicles. This paper describes the lessons learned during design, development, production and marketing of nearly 700,000 hybrid vehicles to date. We review the evolution of major components with a focus on reducing cost, mass and volume while increasing power and efficiency. We also describe the future prospects for hybrid vehicles.
Technical Paper

Achievements and Exploitation of the AUTOSAR Development Partnership

2006-10-16
2006-21-0019
Reductions of hardware costs as well as implementations of new innovative functions are the main drivers of today's automotive electronics. Indeed more and more resources are spent on adapting existing solutions to different environments. At the same time, due to the increasing number of networked components, a level of complexity has been reached which is difficult to handle using traditional development processes. The automotive industry addresses this problem through a paradigm shift from a hardware-, component-driven to a requirement- and function-driven development process, and a stringent standardization of infrastructure elements. One central standardization initiative is the AUTomotive Open System ARchitecture (AUTOSAR). AUTOSAR was founded in 2003 by major OEMs and Tier1 suppliers and now includes a large number of automotive, electronics, semiconductor, hard- and software companies.
Technical Paper

Significance of Electronics Platforms and the Motivation for JasPar

2006-10-16
2006-21-0020
In recent vehicles, E/E architecture is defined and used as a platform to accommodate various electronics features for better development efficiency, lower cost and higher quality. As electronics features increase and integrated control systems make vehicle electronics more complex, good electronics platforms are vital for today's and future vehicle development. This paper first describes the evolution of vehicle electronics and its recent trend and then addresses the challenges facing vehicle electronics: ✓ More integrated control systems ✓ More software ✓ More networks ✓ Shorter time to market Finally, why JasPar1), Japan Automotive Software Platform and Architecture, was founded and how it is organized will be described including the working group activities on FlexRay implementation.
Technical Paper

Variation in Corrosion Resistance of Trivalent Chromate Coating Depending on Type of Zinc Plating Bath

2006-04-03
2006-01-1671
Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.
Technical Paper

Study of Plastic Plating Using Highly Concentrated Ozonized Water Pretreatment

2005-04-11
2005-01-0618
In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).
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