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Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Journal Article

Development of a Ceramic EHC

2022-03-29
2022-01-0536
In recent years, electrically heated catalysts (EHCs) have been developed to achieve lower emissions. In several EHC heating methods, the direct heating method, which an electric current is applied directly to the catalyst substrate, can easily activate the catalyst before engine start-up. The research results reported on the use of the direct heating EHC to achieve significant exhaust gas purification during cold start-up [1]. From the perspective of catalyst loading, ceramics is considered to be a better material for the substrate than metal due to the difference in coefficient of thermal expansion between the catalyst and the substrate, but the EHC made of ceramics has difficulties such as controllability of the current distribution, durability and reliability of the connection between the substrate and the electrodes.
Technical Paper

Development of Ultra Low Viscosity 0W-8 Engine Oil

2020-04-14
2020-01-1425
Further fuel economy improvement of the internal combustion engine is indispensable for CO2 reduction in order to cope with serious global environmental problems. Although lowering the viscosity of engine oil is an effective way to improve fuel economy, it may reduce the wear resistance. Therefore, it is important to achieve both improved fuel economy and reliability. We have developed new 0W- 8 engine oil of ultra-low viscosity and achieved an improvement in fuel economy by 0.8% compared to the commercial 0W-16 engine oil. For this new oil, we reduced the friction coefficient under boundary lubrication regime by applying an oil film former and calcium borate detergent. The film former increased the oil film thickness without increasing the oil viscosity. The calcium borate detergent enhanced the friction reduction effect of molybdenum dithiocarbamate (MoDTC).
Technical Paper

Development of Simplified Finite Element Model for Ultra-High-Strength Steel Resistance Spot Weld Fractures

2020-04-14
2020-01-0220
This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.
Technical Paper

Development of a New High Orientation Paint System to Achieve Outstanding Real Metallic Designs

2020-04-14
2020-01-0899
Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.
Technical Paper

Development of TLP-AI Technology to Realize High Temperature Operation of Power Module

2019-04-02
2019-01-0607
Application of SiC power devices is regarded as a promising means of reducing the power loss of power modules mounted in power control units. Due to those high thermostable characteristics, the power module with SiC power devices are required to have higher operating temperature than the conventional power module with Si power devices. However, the limitations of current packaging technology prevent the utilization of the full potential of SiC power devices. To resolve these issues, the development of device bonding technology is very important. Although transient liquid phase (TLP) bonding is a promising technology for enabling high temperature operation because its bonding layer has a high melting point, the characteristics of the TLP bonding layer tend to damage the power devices. This paper describes the development of a bonding technology to achieve high temperature operation using a stress reduction effect.
Technical Paper

Theory of Collision Avoidance Capability in Automated Driving Technologies

2018-04-03
2018-01-0044
This paper proposes a theory to analyze the collision avoidance capability of automated driving technologies. The theory gives answers to a fundamental question whether automated vehicles fall into extreme conditions at all rather than another question how a vehicle reacts under extreme conditions (is it as safe as driver?). The theory clarifies the following matters: There are two types of hazards to cause collisions, cognitive hazards and behavioral hazards. Cognitive hazards are handled by controlling the upper limit speed of the automated vehicle including when stopped. There are two methods for handling behavioral hazards, preparation and response. The response known well is the coping method activated when the hazard is detected in the dynamic (operational) level. The preparation is the coping method operating at all time in the semantic (tactical) level.
Technical Paper

Development of Three-Way Catalysts Enhanced NOx Purifying Activity

2018-04-03
2018-01-0942
Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).
Technical Paper

Optimizing Transmission Loss for Lightweight Body Structures

2017-06-05
2017-01-1812
In an effort to reduce mass, future automotive bodies will feature lower gage steel or lighter weight materials such as aluminum. An unfortunate side effect of lighter weight bodies is a reduction in sound transmission loss (TL). For barrier based systems, as the total system mass (including the sheet metal, decoupler, and barrier) goes down the transmission loss is reduced. If the reduced surface density from the sheet metal is added to the barrier, however, performance can be restored (though, of course, this eliminates the mass savings). In fact, if all of the saved mass from the sheet metal is added to the barrier, the TL performance may be improved over the original system. This is because the optimum performance for a barrier based system is achieved when the sheet metal and the barrier have equal surface densities. That is not the case for standard steel constructions where the surface density of the sheet metal is higher than the barrier.
Journal Article

An Application of a Model-Prediction-Based Reference Modification Algorithm to Engine Air Path Control

2017-03-28
2017-01-0586
In real-world automotive control, there are many constraints to be considered. In order to explicitly treat the constraints, we introduce a model-prediction-based algorithm called a reference governor (RG). The RG generates modified references so that predicted future variables in a closed-loop system satisfy their constraints. One merit of introducing the RG is that effort required in control development and calibration would be reduced. In the preceding research work by Nakada et al., only a single reference case was considered. However, it is difficult to extend the previous work to more complicated systems with multiple references such as the air path control of a diesel engine due to interference between the boosting and exhaust gas recirculation (EGR) systems. Moreover, in the air path control, multiple constraints need to be considered to ensure hardware limits. Hence, it is quite beneficial to cultivate RG methodologies to deal with multiple references and constraints.
Journal Article

Theoretical Study on Spray Design for Small-Bore Diesel Engine (Second Report)

2017-03-28
2017-01-0704
Generally, soot emissions increase in diesel engines with smaller bore sizes due to larger spray impingement on the cavity wall at a constant specific output power. The objective of this study is to clarify the constraints for engine/nozzle specifications and injection conditions to achieve the same combustion characteristics (such as heat release rate and emissions) in diesel engines with different bore sizes. The first report applied the geometrical similarity concept to two engines with different bore sizes and similar piston cavity shapes. The smaller engine emitted more smoke because air entrainment decreases due to the narrower spray angle. A new spray design method called spray characteristics similarity was proposed to suppress soot emissions. However, a smaller nozzle diameter and a larger number of nozzle holes are required to maintain the same spray characteristics (such as specific air-entrainment and penetration) when the bore size decreases.
Technical Paper

Feasibility Study of Drowsy Driving Prediction based on Eye Opening Time

2017-03-28
2017-01-1398
Since drowsy driving is a major cause of serious traffic accidents, there is a growing requirement for drowsiness prevention technologies. This study proposes a drowsy driving prediction method based on eye opening time. One issue of using eye opening time is predicting strong drowsiness before the driver actually feels sleepy. Because overlooking potential hazards is one of the causes of traffic accidents and is closely related to driver cognition and drowsiness, this study focuses on eye opening movements during driving. First, this report describes hypotheses concerning drowsiness and eye opening time based on the results of previous studies. It is assumed that the standard deviation of eye opening time (SDEOP) indicates driver drowsiness and the following two transitions are considered: increasing and decreasing SDEOP. To confirm the hypotheses, the relationship between drowsiness and SDEOP was investigated.
Journal Article

Development of a New Ceramic Substrate with Gas Flow Control Functionality

2017-03-28
2017-01-0919
Emission regulations in many countries and regions around the world are becoming stricter in reaction to the increasing awareness of environment protections, and it has now become necessary to improve the performance of catalytic converters to achieve these goals. A catalytic converter is composed of a catalytically active material coated onto a ceramic honeycomb-structured substrate. Honeycomb substrates play the role of ensuring intimate contact between the exhaust gas and the catalyst within the substrate’s flow channels. In recent years, high-load test cycles have been introduced which require increased robustness to maintain low emissions during the wide range of load changes. Therefore, it is extremely important to increase the probability of contact between the exhaust gas and catalyst. To achieve this contact, several measures were considered such as increasing active sites or geometrical surface areas by utilizing substrates with higher cell densities or larger volumes.
Technical Paper

Friction Reduction Technology for Low Viscosity Engine Oil Compatible with LSPI Prevention Performance

2016-10-17
2016-01-2276
Increasing numbers of vehicles equipped with downsized, turbocharged engines have been introduced seeking for better fuel economy. LSPI (low speed pre-ignition), which can damage engine hardware, is a potential risk of the engines. We reported that engine oil formulation affects frequency of LSPI events, and formulating magnesium detergents into oil is a promising option to prevent LSPI events. From the viewpoint of achieving better fuel economy by engine oil, lowering viscosity is being required. However, it causes reduced oil film thickness and will expand boundary lubrication condition regions in some engine parts. Hence, a technology to reduce friction under boundary lubrication becomes important.
Journal Article

Development of a Highly Anti-Corrosive Organic-Inorganic Hybrid Paint

2016-04-05
2016-01-0540
A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.
Journal Article

Reduction of Heat Loss and Improvement of Thermal Efficiency by Application of “Temperature Swing” Insulation to Direct-Injection Diesel Engines

2016-04-05
2016-01-0661
The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.
Journal Article

Analysis of Influence of Snow Melting Agents and Soil Components on Corrosion of Decorative Chrome Plating

2016-04-05
2016-01-0539
The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.
Technical Paper

High Efficiency Diesel Engine with Low Heat Loss Combustion Concept - Toyota’s Inline 4-Cylinder 2.8-Liter ESTEC 1GD-FTV Engine -

2016-04-05
2016-01-0658
A highly efficient new 2.8-liter inline 4-cylinder diesel engine has been developed in response to growing demand for diesel engines and to help save energy while providing high-torque performance. Engine efficiency was improved by reducing cooling loss based on an innovative combustion concept applied across the whole engine. Cooling loss was reduced by restricting in-cylinder gas flows and improving combustion chamber insulation. To prevent the restricted gas flows from affecting emissions, a new combustion chamber shape was developed that increased air utilization in the cylinder through optimizing the in-cylinder fuel distribution. Combustion chamber insulation was improved by a new insulation coat that changes the wall surface temperature in accordance with the gas temperature. This reduces cooling loss and avoids the trade-off effect of intake air heating.
Technical Paper

Theoretical Study on Spray Design for Small-Bore Diesel Engine

2016-04-05
2016-01-0740
1 Recently, demand for small-bore compact vehicle engines has been increasing from the standpoint of further reducing CO2 emissions. The generalization and formulation of combustion processes, including those related to emissions formation, based on a certain similarity of physical phenomena regardless of engine size, would be extremely beneficial for the unification of development processes for various sizes of engines. The objective of this study is to clarify what constraints are necessary for engine/nozzle specifications and injection conditions to achieve the same combustion characteristics (such as heat release rate and emissions) in diesel engines with different bore sizes.
Technical Paper

Solar Module Laminated Constitution for Automobiles

2016-04-05
2016-01-0351
Replacing the metal car roof with conventional solar modules results in the increase of total car weight and change of center of mass, which is not preferable for car designing. Therefore, weight reduction is required for solar modules to be equipped on vehicles. Exchanging glass to plastic for the cover plate of solar module is one of the major approaches to reduce weight; however, load bearing property, impact resistance, thermal deformation, and weatherability become new challenges. In this paper a new solar module structure that weighs as light as conventional steel car roofs, resolving these challenges is proposed.
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