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Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Technical Paper

Development of In Mold Coating Clear Coat Paint for Carbon Fiber Sheet Molding Compound Roof

2022-03-29
2022-01-0345
Carbon Fiber Reinforced Plastic (CFRP) is used for various products in the aerospace and sports industries due to its superior specific tensile strength and specific rigidity. With increasing attention to Carbon Neutrality (CN) in the world, vehicle electrification and lightweighting are expanding. As a result, the application of CFRP to luxury cars, electric cars, and sports cars, is increasing. For example, CFRP is used on Lexus LC and RC-F, and Toyota 86 GRMN. However, there are two technical concerns. The first is its durability, which caused by CFRP resin characteristic. The second is poor appearance, which is caused by CFRP surface pinholes. In order to secure good durability and surface appearance, CFRP must be pre-treated before painting (putty applied as a filler for plastic surface coverage, followed by surface sanding) and needs multiple painting steps. Current painted CFRP is not suitable for mass production due to this long and complicated process.
Technical Paper

Deployment of OTA-Upgradable Teammate Advanced Drive

2022-03-29
2022-01-0063
Teammate Advanced Drive is a driving support system with state-of-the-art automated driving technology that has been developed for customers’ safe and secure driving on highways based on the Toyota’s Mobility Teammate Concept. This SAE Level 2 (L2) system assists overtaking, lane changes, and branching to the destination, in addition to providing hands-free lane centering and car following. The automated driving technology includes self-localization onto a High Definition Map, multi-modal sensing to cover 360 degrees of the surrounding environment using fusion of LiDARs, cameras, and radars, and a redundant architecture to realize fail-safe operation when a malfunction or system limitation occurs. High-performance computing is provided to implement deep learning for predicting and responding to various situations that may be encountered while driving.
Technical Paper

Computational Design of Cathode Coating Materials for All-Solid-State Lithium-Ion Batteries

2021-04-06
2021-01-0758
All-solid-state lithium (Li)-ion batteries have attracted significant interest for their enhanced energy density compared with conventional batteries employing an organic liquid electrolyte. However, the interfacial impedance and reaction between electrodes and the electrolyte can hinder the transport of Li-ions, thus degrading the battery performance. This paper presents a systematic screening method to identify coatings to reduce impedance and maintain interface stability during battery operation. Promising coating materials are rapidly selected by evaluating properties for ideal coating materials from computational databases containing a vast collection of Li compounds. Finally, a few candidates are discovered and their battery performances are tested. This approach is demonstrated to be an efficient way to predict and evaluate functional coatings for a high performance all-solid -state battery design.
Journal Article

Development of Unidirectional CFRP Reinforced Aluminum Bumper Reinforcement

2021-04-06
2021-01-0362
Since bumper reinforcements are positioned at front/rear ends of vehicles, weight reduction of the bumper reinforcements enhances vehicle dynamic performance by reducing a yaw moment of inertia. CFRP (Carbon Fiber Reinforced Plastic) composites are attractive lightweight materials due to their excellent specific strength and rigidity. However, because of their relatively high cost, applications of CFRP materials to vehicle structural parts are limited. In this study we have developed a lightweight, structural part, which consists of a thin-walled Al (Aluminum) bumper reinforcement with a UD (Unidirectional)-CFRP sheet. The intention is to prevent an increased part cost by reducing the amount of Al and by minimizing the amount of CFRP. Compared to Al, UD-CFRP sheets have even higher tensile strength and modulus. When vehicles crash, bumper reinforcements may be subjected to bending force.
Technical Paper

Development of Ultra Low Viscosity 0W-8 Engine Oil

2020-04-14
2020-01-1425
Further fuel economy improvement of the internal combustion engine is indispensable for CO2 reduction in order to cope with serious global environmental problems. Although lowering the viscosity of engine oil is an effective way to improve fuel economy, it may reduce the wear resistance. Therefore, it is important to achieve both improved fuel economy and reliability. We have developed new 0W- 8 engine oil of ultra-low viscosity and achieved an improvement in fuel economy by 0.8% compared to the commercial 0W-16 engine oil. For this new oil, we reduced the friction coefficient under boundary lubrication regime by applying an oil film former and calcium borate detergent. The film former increased the oil film thickness without increasing the oil viscosity. The calcium borate detergent enhanced the friction reduction effect of molybdenum dithiocarbamate (MoDTC).
Technical Paper

Development of a New High Orientation Paint System to Achieve Outstanding Real Metallic Designs

2020-04-14
2020-01-0899
Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.
Technical Paper

Development of Quantitative Fuel Film Distribution Measurement by LIEF Technique and Application to Gasoline Spray

2020-04-14
2020-01-1159
From the point of global and local environment, internal combustion engine is facing the need for significant improvement of exhaust emission. Especially, important is the reduction of unburned hydrocarbon (HC) from fuel film on liner under cold condition. In this study, at first, quantitative fuel film measurement technique by using Laser Induced Exciplex Fluorescence (LIEF) was developed. For the light source, 4th harmonic pulse yttrium aluminum garnet (YAG) laser (266nm) was used. For the tracer, the combination of N,N-Dimethylaniline (DMA) and naphthalene was used and quantitative concentration was decided by calibration test. With LIEF, the distribution of fuel film can be obtained by measuring the fluorescence only from the liquid phase. In order to evaluate the effect of fuel film on exhaust HC emission from engine, the film distribution was measured using quartz glass liner. For the injector, a prototype 6-hole gasoline injector was used.
Journal Article

Super High Transfer Efficiency Application for Body Coating

2020-04-14
2020-01-0901
In order to achieve the Toyota Environmental Challenge of 2050 (zero CO2 emissions), we have developed an innovative coating system that achieves more than 95% transfer efficiency. In order to reduce paint loss in the painting process, it is necessary to eliminate overdust and bounce dust. The most important point is how to spray (atomization, particle flight, adhesion) without shaping air. We have developed a “super high transfer efficiency system” that eliminates the need for shaping air. We continue to challenge the development of innovative technologies to view the paint shop as clean and eco-friendly environment.
Technical Paper

Development of Three-Way Catalyst with Advanced Coating Layer

2020-04-14
2020-01-0653
Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.
Journal Article

Development of a Highly Anti-Corrosive Organic-Inorganic Hybrid Paint

2016-04-05
2016-01-0540
A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.
Journal Article

Development of Paint Booth: “New Paint Mist Collection Method”

2016-04-05
2016-01-1258
1 Inside a paint booth to spray paint on vehicle bodies, bumpers, and other parts (hereinafter referred to as “works”), air whose temperature and humidity are controlled by air-conditioner is supplied by blower fans through filters. Dust-eliminated and regulated air flow is sent downward from top to bottom (hereinafter referred to as “downflow”) in the painting booth. Conventionally, paint which does not adhere to work in spraying (hereinafter referred to as “paint mist”) is collected while flowing at a high speed through a slit opening called venturi scrubber in a mixture of air and water. However, this mist collecting system using venturi scrubber requires a large space with a large amount of pressure loss while consuming substantial energy. By radically changing the mist collecting principle, we developed a new compact system with less pressure loss aiming to reduce energy consumption by 40% in a half-size booth.
Journal Article

Reduction of Heat Loss and Improvement of Thermal Efficiency by Application of “Temperature Swing” Insulation to Direct-Injection Diesel Engines

2016-04-05
2016-01-0661
The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.
Technical Paper

Factors in Annoyance Due to Windshield Reflection of the Outline of the Head-up Display

2016-04-05
2016-01-1417
The use of a head-up display (HUD) system has become popular recently, as it can provide feedback information at a position easily seen by the driver. However, the outline of the HUD bezel often reflects on the windshield of a HUD equipped vehicle. This phenomenon occurs when the sun is at a high position and reflects off the top of the instrument panel and the front view is dark. For this reason, it can occur when driving on asphalt paved roads, causing annoyance to the driver. Under fixed environmental conditions, the vehicle based factors that influence the annoyance caused by reflected boundary lines are the position of the reflection, line thickness, and the contrast of the reflected boundary line. These can be represented by the conspicuity of a striped pattern (contrast sensitivity function). In previous research in 1991, M. S. Banks et al. studied a contrast sensitivity function that included the factors stated above.
Technical Paper

Development of Instantaneous Temperature Measurement Technique for Combustion Chamber Surface and Verification of Temperature Swing Concept

2016-04-05
2016-01-0675
To improve the thermal efficiency of an internal combustion engine, the application of ceramics to heat loss reduction in the cylinders has been studied [1-2]. The approach taken has focused on the low heat conductivity and high heat resistance of the ceramic. However, since the heat capacity of the ceramic is so large, there is a problem in that the wall temperature increases during the combustion cycle. This leads to a decrease in the charging efficiency, as well as knocking in gasoline engines. To overcome these problems, the application of thermal insulation without raising the gas temperature during the intake stroke has been proposed [3-4]. As a means of achieving this, we developed a "temperature swing heat insulation coating" [5, 6, 7, 8, 9]. This reduces the heat flux from the combustion chamber into the cooling water by making the wall temperature follow the gas temperature as much as possible during the expansion and exhaust strokes.
Technical Paper

Anti- Combustion Deposit Fuel Development for 2009 Toyota Formula One Racing Engine

2011-08-30
2011-01-1983
Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.
Technical Paper

Development of Anti Scratch Clear Coat

2008-04-14
2008-01-1461
“Anti-scratch performance” is the highest in customer's needs of paint. To achieve anti-acid and anti-scratch performance, we selected 2K-urethane because of a high degree of freedom in paint design. In addition, we have done a precise molecular design of the acrylic polyol and the isocyanate. As a result, “a highly durable, soft, fine-crosslinking paint film” was achieved, and “anti-scratch clear coat” that surpassed the current clear coats was developed.
Technical Paper

LED Headlamp Development for Mass Production

2008-04-14
2008-01-0339
To meet the market requirement for headlamps having lower power consumption, high photometric performance and long life whilst providing new styling opportunities, it has been anticipated that LED light sources would provide the necessary technological basis. Against this backdrop, Koito has succeeded in developing the necessary headlamp technologies and commercializing the world's first headlamp utilizing white LED's. The key point is that the various challenges associated with the development of an LED headlamp such as the commercial application of a synthesized light distribution, control of the light axis structure for the multi-lamp system, development of adequate thermal management for the cooling of the LED's and the achievement of volume production of the lamps have been successfully overcome.
Technical Paper

Hexagonal Cell Ceramic Substrates for Lower Emission and Backpressure

2008-04-14
2008-01-0805
Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass
Technical Paper

Variation in Corrosion Resistance of Trivalent Chromate Coating Depending on Type of Zinc Plating Bath

2006-04-03
2006-01-1671
Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.
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