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The growth of hydraulic fracking has resulted in a dramatic cost reduction of Compressed Natural Gas (CNG), a low carbon fuel. CNG cannot be used as singular fuel in conventional Compression Ignition (CI) engines because of its high auto-ignition characteristics. However, CNG-assisted diesel combustion represents a means to shift the energy consumption of CI engines away from liquid fossil fuels. Calculation of the rate of heat release is vital for understanding and optimizing this mode of engine operation. A previously constructed three-zone equilibrium heat release model that is calibrated to engine exhaust emission measurements was augmented in order to allow for the addition of CNG in the engine intake. The model was also adapted to permit reuse of unburned CNG gas with other exhaust species via exhaust gas recirculation. This is because experiments demonstrated a potentially significant increase in methane emissions under high CNG flowrates.

Software packages including Argonne National Lab's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model and the EPA's Motor Vehicle Emissions Simulation (MOVES) model are useful in analyzing the emission profiles of light-duty vehicles. In particular, GREET performs a detailed life cycle fuel energy and emissions analysis, while MOVES focuses on energy and emissions during vehicle operation. This study uses MOVES2010b in the creation of emission trends in order to predict future emissions regulations and the subsequent aftertreatment device areas of improvement required to meet these standards. A second objective was to create four time sheet tables in order to update the base vehicle operation emission profiles used in GREET. The simulation results depict the balance between nitrous oxide and hydrocarbon emissions, the dependency upon climate effects, and areas for potential improvement given recent engine design trends.