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In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

In several regions, such as Europe, California, among others, the switch to Electric Vehicles (EVs) has been heavily pushed by policymakers for their high powertrain efficiency and zero tailpipe emissions compared to conventional Internal Combustion Engine Vehicles (ICEVs). Consequently, only zero tailpipe emission vehicles will be sold in Europe from 2035 for the passenger cars and vans segment. But an EV does emit CO2 emissions across its life cycle, mainly during production, and the Well-to-Tank (WTT) phase, i.e., from the electricity generation used to charge the batteries. Nonetheless, due to the high efficiency of the electric powertrain, the energy consumption is significantly less, making the cost of operation significantly low for EVs. Thus, clean electricity grid and cheap energy costs can make EVs one of the best options for decarbonizing transportation systems.

In recent decades, the importance of emerging alternative fuels has increased significantly as a solution to the problems of global warming and air pollution from energy production. In this context, ammonia (NH3) is seen as a potential option and energy vector that may be able to overcome the technical challenges associated with the use of other carbon-free fuels such as hydrogen (H2) in internal combustion engines (ICE). In this research, a numerical methodology for evaluating the impact of using ammonia as a fuel for spark-ignition ICEs has been developed. A combination of a single-cylinder and multi-cylinder numerical experiments has been performed to identify the main challenges and determine correct engine configuration. In addition, the performance of the engine has been evaluated through standard homologation driving cycles, contrasting it with other alternative propulsion configurations.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.

Economy decarbonization will be one of the main goals for the following years. Research efforts are being focused on reducing carbon-based emissions, by increasing the efficiency of the transport power plants while developing new fuel production methods that reduce the environmental footprint of the refinement process. Consequently, the depletion of conventional fuels derived from petroleum with high carbon content, such as gasoline and diesel, motivated the development of propulsive alternatives for the transportation sector. In this paradigm, methane (CH4) fuel appears as a mid-term solution due to its low carbon content, if compared with traditional fuels, and the low CO2 emissions during its production from renewable sources. However, the intrinsic properties of methane compromise the combustion process, subsequently increasing the emission of CO2.

The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.

Emissions regulations for engine and vehicle manufacturers are bound to become more limiting to prevent greenhouse gas emissions and mitigate the negative effects that potentiate global warming. To fulfill the energy demand necessary in the transportation sector for the short-to-medium term, a parallel optimization of the internal combustion engine, powertrain and fuels is necessary. The combination of novel combustion modes like the reactivity-controlled compression ignition (RCCI), that seeks the benefits of both compression ignition and spark ignition engines, with the so-called e-fuels, that reduce the carbon footprint from well-to-wheel, is worth exploring. This work investigates the potential of the RCCI concept using OMEx-gasoline to reduce the engine-out emissions beyond the current EURO VI legislation. To do so, eight representative operating conditions from several driving cycles for heavy-duty vehicles will be explored experimentally.

The reduction of carbon footprint of compression ignition engines for road transport makes it necessary to search for clean fuels alternative to diesel and to evaluate them under engine conditions. For this reason, in this paper, the combustion behaviour of different blends of synthetic fuels has been analyzed in an optical single cylinder engine of Medium Duty size (0,8 liters per cylinder) by means of optical techniques. The aim is to evaluate the effect of synthetic fuels, both partly or completely fossil diesel, in terms of combustion behaviours and soot formation. Therefore, different blends of oxymethylene dimethyl ether (OMEX) with diesel and neat hydrotreated vegetable oil (HVO) were studied. A conventional common rail injection system and a single injection strategy was used. In addition, special care was taken to ensure that conditions inside the engine cylinder at the injection start were as close as possible to the conditions used in previous studies.

Low pressure exhaust gases recirculation (LP-EGR) is becoming a state-of-the-art technique for Nitrogen oxides (NOx) reduction in compression ignited (CI) engines. However, despite the pollutant reduction benefits, LP-EGR suffers from strong non-linearities and delays which are difficult to handle, resulting in reduced engine performance under certain conditions. Measurement and observation of oxygen concentration at the intake have been a research topic over the past few years, and it may be critical for transition phases (from low pressure to high pressure EGR). Here, an adequate selection of models and sensors is essential to obtain a precise and fast measurement for control purposes. The present paper analyses different sensor configurations, with oxygen concentration measurements at the intake and exhaust manifold and combines observation techniques with sensor models to determine the potential of each configuration.

The spatial and temporal locations of autoignition depend on fuel chemistry and the temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into fuel-chemistry aspects through variation of the proportions of fuels with different reactivities, and engine operating condition variations can provide information on physical effects. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

A comparison of the flame structure for two different fuels, dodecane and oxymethylene dimethyl ether (OMEX), has been performed under condition of Spray A of the Engine Combustion Network (ECN). The experiments were carried out in a constant pressure vessel with wide optical access, at high pressure and temperature and controlled oxygen concentration. The flame structure analysis has been performed by measuring the formaldehyde and OH radical distributions using planar Laser-Induced Fluorescence (PLIF) techniques. To complement the analysis, this information was combined with that obtained with high-speed imaging of OH* chemiluminescence radiation in the UV. Formaldehyde molecules are excited with the 355-nm radiation from the third harmonic of a Nd:YAG laser, whilst OH is excited with a wavelength of 281.00-nm from a dye laser.

The increasingly stringent emissions regulations together with the demand of highly efficient vehicles from the customers, lead to rapid developments of distinct powertrain solutions, especially when the electrification is present in a certain degree. The combination of electric machines with conventional powertrains diversifies the powertrain architectures and brings the opportunity to save energy in greater extents. On the other hand, alternative combustion modes as reactivity controlled compression ignition (RCCI) have shown to provide simultaneous ultra-low NOx and soot emissions with similar or better thermal efficiency than conventional diesel combustion (CDC). In addition, it is necessary to introduce more renewable fuels as ethanol to reduce the total CO2 emitted to the atmosphere, also called well-to-wheel (WTW) emission, in the transport sector.

With demanding emissions legislations and the need for higher efficiency, new technologies for compression ignition engines are in development. One of them relies on reducing the heat losses of the engine during the combustion process as well as to devise injection strategies that reduce soot formation. Therefore, it is necessary a better comprehension about the turbulent kinetic energy (TKE) distribution inside the cylinder and how it is affected by the interaction between air flow motion and fuel spray. Furthermore, new diesel engines are characterized by massive decrease of NOx emissions. Therefore, considering the well-known NOx-soot trade-off, it is necessary a better comprehension and overall quantification of soot formation and how the different injection strategies can impact it.

A genetic algorithm (GA) optimization methodology is applied to the design of the combustion system of a heavy-duty (HD) Diesel engine fueled with dimethyl ether (DME). The study has two objectives, the optimization of a conventional diffusion-controlled combustion system aiming to achieve US2010 targets and the optimization of a stoichiometric combustion system coupled with a three way catalyst (TWC) to further control NOx emissions and achieve US2030 emission standards. These optimizations include the key combustion system related hardware, bowl geometry and injection nozzle design as input factors, together with the most relevant air management and injection settings. The GA was linked to the KIVA CFD code and an automated grid generation tool to perform a single-objective optimization. The target of the optimizations is to improve net indicated efficiency (NIE) while keeping NOx emissions, peak pressure and pressure rise rate under their corresponding target levels.

In the past few years’ various studies have shown how the application of a highly premixed dual fuel combustion for CI engines leads a strong reduction for both pollutant emissions and fuel consumption. In particular a drastic soot and NOx reduction were achieved. In spite of the most common strategy for dual fueling has been represented by using two different injection systems, various authors are considering the advantages of using a single injection system to directly inject blends in the chamber. In this scenario, a characterization of the behavior of such dual-fuel blend spray became necessary, both in terms of inert and reactive ambient conditions. In this work, a light extinction imaging (LEI) has been performed in order to obtain two-dimensional soot distribution information within a spray flame of different diesel/gasoline commercial fuel blends. All the measurements were conducted in an optically accessible two-stroke engine equipped with a single-hole injector.