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Technical Paper

Exploring methanol and naphtha as alternative fuels for a hybrid-ICE battery-driven light-duty vehicle

2024-06-12
2024-37-0021
In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.
Technical Paper

Influence of Intake Charge Temperature and EGR Rate on the Combustion and Emission Characteristics of Ammonia/Diesel Dual-Fuel Engine

2024-06-12
2024-37-0025
Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.
Technical Paper

A Comparative Analysis of Thermal Runaway Propagation in Different Modular Lithium-Ion Battery Configuration

2024-05-06
2024-01-2901
Thermal runaway is a critical safety concern in lithium-ion battery systems, emphasising the necessity to comprehend its behaviour in various modular setups. This research compares thermal runaway propagation in different modular configurations of lithium-ion batteries by analysing parameters such as cell spacing and distribution, application of phase change materials (PCMs), and implementing insulating materials. The study at the module level includes experimental validation and employs a comprehensive model considering heat transfer due to electrical performance and thermal runaway phenomena. It aims to identify the most effective modular configuration for mitigating thermal runaway risks and enhancing battery safety. The findings provide valuable insights into the design and operation of modular lithium-ion battery systems, guiding engineers and researchers in implementing best practices to improve safety and performance across various applications.
Technical Paper

Numerical Approach for the Characterization of the Venting Process of Cylindrical Cells Under Thermal Runaway Conditions

2024-05-06
2024-01-2900
The increasing awareness on the harmful effects on the environment of traditional Internal Combustion Engines (ICE) is driving the industry toward cleaner powertrain technologies such as battery-driven Electric Vehicles. Nonetheless, the high energy density of Li-Ion batteries can cause strong exothermic reactions under certain conditions that can lead to catastrophic results, called Thermal Runaway (TR). Hence, a strong effort is being placed on understanding this phenomena and increase battery safety. Specifically, the vented gases and their ignition can cause the propagation of this phenomenon to adjancent batteries in a pack. In this work, Computational Fluid Dynamics (CFD) are employed to predict this venting process in a LG18650 cylindrical battery. The ejection of the generated gases was considered to analyze its dispersion in the surrounding volume through a Reynolds-Averaged Navier-Stokes (RANS) approach.
Technical Paper

Evaluation of closed-loop combustion phase optimization for varying fuel compensation and cylinder balancing in a HD SI-ICE

2024-04-09
2024-01-2837
Alternative fuels, such as natural and bio-gas, are attractive options for reducing greenhouse gas emissions from combustion engines. However, the naturally occurring variation in gas composition poses a challenge and may significantly impact engine performance. The gas composition affects fundamental fuel properties such as flame propagation speed and heat release rate. Deviations from the gas composition for which the engine was calibrated result in changes in the combustion phase, reducing engine efficiency and increasing fuel consumption and emissions. However, the efficiency loss can be limited by estimating the combustion phase and adapting the spark timing, which could be implemented favorably using a closed-loop control approach. In this paper, we evaluate the efficiency loss resulting from varying gas compositions and the benefits of using a closed-loop controller to adapt the spark timing to retain the nominal combustion phase.
Technical Paper

Investigation of Combustion Characteristics of a Fuel Blend Consisting of Methanol and Ignition Improver, Compared to Diesel Fuel and Pure Methanol

2024-04-09
2024-01-2122
The increasing need to reduce greenhouse gas emissions and shift away from fossil fuels has raised an interest for methanol. Methanol can be produced from renewable sources and can drastically lower soot emissions from compression ignition engines (CI). As a result, research and development efforts have intensified focusing on the use of methanol as a replacement for diesel in CI engines. The issue with methanol lies in the fact that methanol is challenging to ignite through compression alone, particularly at low-load and cold starts conditions. This challenge arises from methanol's high octane number, low heating value, and high heat of vaporization, all of which collectively demand a substantial amount of heat for methanol to ignite through compression.
Technical Paper

Experimental Investigation of Pilot Injection Strategies to Aid Low Load Compression Ignition of Neat Methanol

2024-04-09
2024-01-2119
The growing demand to lower greenhouse gas emissions and transition from fossil fuels, has put methanol in the spotlight. Methanol can be produced from renewable sources and has the property of burning almost soot-free in compression ignition (CI) engines. Consequently, there has been a notable increase in research and development activities directed towards exploring methanol as a viable substitute for diesel fuel in CI engines. The challenge with methanol lies in the fact that it is difficult to ignite through compression alone, particularly in low-load and cold start conditions. This difficulty arises from methanol's high octane number, relatively low heating value, and high heat of vaporization, collectively demanding a considerable amount of heat for methanol to ignite through compression. Previous studies have addressed the use of a pilot injection in conjunction with a larger main injection to lower the required intake air temperature for methanol to combust at low loads.
Technical Paper

CFD Modelling of Hydrogen-Fueled SI Engines for Light-Duty Applications

2023-08-28
2023-24-0017
The employment of hydrogen as energy carrier for transportation sector represents a significant challenge for powertrains. Spark-ignition (SI) engines are feasible and low-cost devices to convert the hydrogen chemical energy into mechanical work. However, significant efforts are needed to successfully retrofit the available configurations. The computational fluid dynamics (CFD) modelling represents a useful tool to support experiments, clarifying the impact of the engine characteristics on both the mixture preparation and the combustion development. In this work, a CFD investigation is carried out on typical light-duty SI engine configurations, exploring the two main strategies of hydrogen addition: port fuel injection (PFI) and direct injection (DI). The purpose is to assess the behaviour of widely-used numerical models and methodologies when hydrogen is employed instead of traditional carbon-based fuels.
Technical Paper

Numerical Modeling of Hydrogen Combustion Using Preferential Species Diffusion, Detailed Chemistry and Adaptive Mesh Refinement in Internal Combustion Engines

2023-08-28
2023-24-0062
Mitigating human-made climate change means cutting greenhouse gas (GHG) emissions, especially carbon dioxide (CO2), which causes climate change. One approach to achieving this is to move to a carbon-free economy where carbon emissions are offset by carbon removal or sequestration. Transportation is a significant contributor to CO2 emissions, so finding renewable alternatives to fossil fuels is crucial. Green hydrogen-fueled engines can reduce the carbon footprint of transportation and help achieve a carbon-free economy. However, hydrogen combustion is challenging in an internal combustion engine due to flame instabilities, pre-ignition, and backfire. Numerical modeling of hydrogen combustion is necessary to optimize engine performance and reduce emissions. In this work, a numerical methodology is proposed to model lean hydrogen combustion in a turbocharged port fuel injection (PFI) spark-ignition (SI) engine for automotive applications.
Technical Paper

ɸ-Sensitivity Evaluation of n-Butanol and Iso-Butanol Blends with Surrogate Gasoline

2023-08-28
2023-24-0089
Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.
Technical Paper

Evaluation of Neat Methanol as Fuel for a Light-Duty Compression Ignition Engine

2023-08-28
2023-24-0047
Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.
Technical Paper

Experimental Investigation of Glycerol Derivatives as Low-Concentration Additives for Diesel Fuel

2023-08-28
2023-24-0095
The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines.
Technical Paper

Sustainability of Future Shipping Fuels: Well-to-Wake Environmental and Techno-Economic Analysis of Ammonia and Methanol

2023-08-28
2023-24-0093
The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.
Technical Paper

Optical Diagnostic Study on Improving Performance and Emission in Heavy-Duty Diesel Engines Using a Wave-Shaped Piston Bowl Geometry and Post Injection Strategies

2023-08-28
2023-24-0048
This study explores the potential benefits of combining a wave-shaped piston geometry with post injection strategy in diesel engines. The wave piston design features evenly spaced protrusions around the piston bowl, which improve fuel-air mixing and combustion efficiency. The 'waves' direct the flames towards the bowl center, recirculating them and utilizing the momentum in the flame jets for more complete combustion. Post injection strategy, which involves a short injection after the main injection, is commonly used to reduce emissions and improve fuel efficiency. By combining post injections with the wave piston design, additional fuel injection can increase the momentum utilized by the flame jets, potentially further improving combustion efficiency. To understand the effects and potential of the wave piston design with post injection strategy, a single-cylinder heavy-duty compression-ignition optical engine with a quartz piston is used.
Technical Paper

Thermal Model for the analysis of the Thermal Runaway in Lithium-Ion Batteries using Accelerating Rate Calorimetry

2023-08-28
2023-24-0162
Accelerating rate calorimetry (ARC) has emerged as a powerful tool for evaluating the thermal behavior of Li-ion cells and identifying potential safety hazards. In this work, a new physical thermal model has been developed based on the first law of thermodynamics for analyzing heat and mass generated by Lithium-ion battery cells under thermal abuse conditions during EV-ARC tests. The analysis is based on the experimental data gathered from an ARC, including different temperatures and pressure inside a gas-tight canister located in the calorimeter chamber, as well as the gas composition at the end of the test. The energy balance of the battery cell includes: the energy released by the cell, the internal energy of the elements inside the canister, heat transfer between elements inside the canister, as well as the mass transfer between the cell and the gases inside the canister.
Technical Paper

A Fast and Reliable CFD Approach to Design Hydrogen SI Engines for Industrial Applications

2023-06-26
2023-01-1208
SI engines fueled with hydrogen represent a promising powertrain solution to meet the ambitious target of carbon-free emissions at the tailpipe. Therefore, fast and reliable numerical tools can significantly support the automotive industry in the optimization of such technology. In this work, a 1D-3D methodology is presented to simulate in detail the combustion process with minimal computational effort. First, a 1D analysis of the complete engine cycle is carried out on the user-defined powertrain configuration. The purpose is to achieve reliable boundary conditions for the combustion chamber, based on realistic engine parameters. Then, a 3D simulation of the power-cycle is performed to mimic the combustion process. The flow velocity and turbulence distributions are initialized without the need of simulating the gas exchange process, according to a validated technique.
Technical Paper

A Modeling Tool for Particulate Emissions in GDI Engines with Emphasis on the Injector Zone

2023-04-11
2023-01-0182
Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.
Technical Paper

Impact of the 2022 European Energy Crisis on its Transportation Decarbonization Ambition: Life Cycle Techno-Economic Analysis

2023-04-11
2023-01-0554
In several regions, such as Europe, California, among others, the switch to Electric Vehicles (EVs) has been heavily pushed by policymakers for their high powertrain efficiency and zero tailpipe emissions compared to conventional Internal Combustion Engine Vehicles (ICEVs). Consequently, only zero tailpipe emission vehicles will be sold in Europe from 2035 for the passenger cars and vans segment. But an EV does emit CO2 emissions across its life cycle, mainly during production, and the Well-to-Tank (WTT) phase, i.e., from the electricity generation used to charge the batteries. Nonetheless, due to the high efficiency of the electric powertrain, the energy consumption is significantly less, making the cost of operation significantly low for EVs. Thus, clean electricity grid and cheap energy costs can make EVs one of the best options for decarbonizing transportation systems.
Technical Paper

Challenges and Directions of Using Ammonia as an Alternative Fuel for Internal Combustion Engines

2023-04-11
2023-01-0324
In recent decades, the importance of emerging alternative fuels has increased significantly as a solution to the problems of global warming and air pollution from energy production. In this context, ammonia (NH3) is seen as a potential option and energy vector that may be able to overcome the technical challenges associated with the use of other carbon-free fuels such as hydrogen (H2) in internal combustion engines (ICE). In this research, a numerical methodology for evaluating the impact of using ammonia as a fuel for spark-ignition ICEs has been developed. A combination of a single-cylinder and multi-cylinder numerical experiments has been performed to identify the main challenges and determine correct engine configuration. In addition, the performance of the engine has been evaluated through standard homologation driving cycles, contrasting it with other alternative propulsion configurations.
Journal Article

Fresh and Aged Organic Aerosol Emissions from Renewable Diesel-Like Fuels HVO and RME in a Heavy-Duty Compression Ignition Engine

2023-04-11
2023-01-0392
A modern diesel engine is a reliable and efficient mean of producing power. A way to reduce harmful exhaust and greenhouse gas (GHG) emissions and secure the sources of energy is to develop technology for an efficient diesel engine operation independent of fossil fuels. Renewable diesel fuels are compatible with diesel engines without any major modifications. Rapeseed oil methyl esters (RME) and other fatty acid methyl esters (FAME) are commonly used in low level blends with diesel. Lately, hydrotreated vegetable oil (HVO) produced from vegetable oil and waste fat has found its way into the automotive market, being approved for use in diesel engines by several leading vehicle manufacturers, either in its pure form or in a mixture with the fossil diesel to improve the overall environmental footprint. There is a lack of data on how renewable fuels change the semi-volatile organic fraction of exhaust emissions.
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