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Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.

This paper describes a numerical study on air/fuel preparation process in a direct-injected spark-ignition engine under partial load stratified conditions. The fuel is represented as a mixture of four components with a distillation curve similar to that of actual gasoline, and its vaporization processes are simulated by two recently formulated multicomponent vaporization models for droplet and film, respectively. The models include major mechanisms such as non-ideal behavior in high-pressure environments, preferential vaporization, internal circulation, surface regression, and finite diffusion in the liquid phase. A spray/wall impingement model with the effect of surface roughness is used to represent the interaction between the fuel spray and the solid wall. Computations of single droplet and film on a flat plate were first performed to study the impact of fuel representation and vaporization model on the droplet and film vaporization processes.

A 2.5L, V-6, port-injected, spark-ignition engine was modified for optical access by separating the head from the block and installing a Bowditch extended piston with a fused-silica top and a fused-silica liner in one of the cylinders. Two heads were employed in the study. One produced swirl and permitted modulation of the swirl level, and another produced a tumbling flow in the cylinder. Planar laser-induced exciplex fluorescence, which allows the simultaneous, but separate, imaging of liquid and vapor fuel, was extended to capture components of different volatilities in a model fuel designed to simulate the distillation curve of a typical gasoline. The exciplex fluorescence technique was calibrated in a separate cell where careful control of mixture composition, temperature and pressure was possible. The results show that large-scale motion induced during intake is critical for good mixing during the intake and compression strokes.

The presence and distribution of liquid fuel within an engine cylinder at cold start may adversely affect the hydrocarbon emissions from port-injected, spark ignition engines. Therefore, high speed videos of the liquid fuel entry into the cylinder of an optical engine were recorded in order to assess the effect of various engine operating parameters on the amount of liquid fuel inducted into the cylinder, the sizes of liquid drops present and the distribution of the fuel within the cylinder. A 2.5L, V-6, port-injected, spark ignition engine was modified so that optical access is available throughout the entire volume of one of the cylinders. A fused silica cylinder is sandwiched between the separated block and head of the engine and a “Bowditch-type” piston extension is mounted to the production piston. The Bowditch piston has a fused silica crown so that visualization is possible through the top of the piston as well as through the transparent cylinder.

Cylinder head combustion chamber and piston temperatures and heat fluxes were measured in a 2.2 L 4 cylinder spark ignition engine. Measurements for the combustion chamber were made at wide open throttle conditions, 1400 rpm to 5000 rpm at 600 rpm increments, additional measurements were made on the combustion chamber at part throttle conditions at 3200 RPM. Piston temperature and heat flux measurements were made at WOT conditions from 1400 to 3200 RPM in 600 RPM increments. Average combustion chamber surface temperatures ranged from 130 deg. C to 248 deg. C, while peak combustion chamber surface temperatures ranged from 142 deg. C to 258 deg. C for WOT conditions. Peak heat flus at the surface for WOT conditions in the combustion chamber ranged from 1.2 MW/m2to 5.0 MW/m2. Central region heat fluxes were 2.3 to 2.8 times greater than those in the end gas regions of the combustion chamber.

Combustion chamber deposits in spark ignition engines act as thermal insulators and can lead to octane requirement increase. The thermal properties of deposits are not well documented, the reported thermal diffusivity values vary by two orders of magnitude. Two thermal property measurement techniques were compared, the flash and steady illumination laser methods. The steady laser method was more suitable for deposit property measurement. A comparison was made of the thermal properties of deposits grown with a base fuel with the thermal properties of deposits grown with the base fuel doped with reformer bottoms. For the clean fuel the thermal diffusivity ranged from 3.5 to 3.9-7 m2/s, at various locations around the combustion chamber. For the fuel doped with reformer bottoms the thermal diffusivity ranged from 1.1 to 1.9-7 m2/s at different locations within the combustion chamber.