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Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

This research evaluates the capability of data-science models to classify the combustion events in Cooperative Fuel Research Engine (CFR) operated under Homogeneous Charge Compression Ignition (HCCI) conditions. A total of 10,395 experimental data from the CFR engine at the University of Michigan (UM), operated under different input conditions for 15 different fuel blends, were utilized for the study. The combustion events happening under HCCI conditions in the CFR engine are classified into four different modes depending on the combustion phasing and cyclic variability (COVimep). The classes are; no ignition/high COVimep, operable combustion, high MPRR, and early CA50. Two machine learning (ML) models, K-nearest neighbors (KNN) and Support Vector Machines (SVM), are compared for their classification capabilities of combustion events. Seven conditions are used as the input features for the ML models viz.