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This paper summarizes some of the research which has been carried out at Ford Motor Co. in the area of NOx traps. Results from a large body of experimental work are reviewed and used to provide insight into the fundamental processes which govern NOx trap performance. In particular, the key parameters which control thermal durability and sulfur poisoning of the NOx trap are discussed in detail. In addition, a theoretical model of the NOx trap is described and used in the analysis and interpretation of the experimental results.

The effect of MMT on the OBD-II catalyst efficiency monitor has been investigated. The results conclusively show that manganese which is deposited onto the catalyst during the combustion of MMT- containing fuel provides for an increased level of catalyst oxygen storage capacity. This added oxygen storage was found to result in a reduced rear EGO sensor response and caused malfunctioning catalysts to be incorrectly diagnosed by the OBD-II catalyst efficiency monitor.

Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.