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Ethanol, used widely as a spark-ignition (SI) engine fuel, has seen minimal success as a compression ignition (CI) engine fuel. The lack of success of ethanol in CI engines is mainly due to ethanol's very low cetane number and its poor lubricity properties. Past researchers have utilized nearly pure ethanol in a CI engine by either increasing the compression ratio which requires extensive engine modification and/or using an expensive ignition improver. The objective of this work was to demonstrate the ability of a hydrogen port fuel injection (PFI) system to facilitate the combustion of ethanol in a CI engine. Non-denatured anhydrous ethanol, mixed with a lubricity additive, was used in a variable compression ratio CI engine. Testing was conducted by varying the amount of bottled hydrogen gas injected into the intake manifold via a PFI system. The hydrogen flowrates were varied from 0 - 10 slpm.

A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.

Diesel exhaust particle number concentrations and size distributions, as well as gaseous and particulate mass emissions, were measured during steady-state tests on a US heavy-duty engine and a European passenger car engine. Two fuels were compared, namely a Fischer-Tropsch diesel fuel manufactured from natural gas, and a US D2 on-highway diesel fuel. With both engines, the Fischer-Tropsch fuel showed a considerable reduction in the number of particles formed by nucleation, when compared with the D2 fuel. At most test modes, particle number emissions were dominated by nucleation mode particles. Consequently, there were generally large reductions (up to 93%) in the total particle number emissions with the Fischer-Tropsch fuel. It is thought that the most probable cause for the reduction in nucleation mode particles is the negligible sulphur content of the Fischer-Tropsch fuel. In general, there were also reductions in all the regulated emissions with the Fischer-Tropsch fuel.

Experiments were performed to measure the number-weighted particle size distributions emitted from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 15 - 100 km/hr. Dilution of the exhaust aerosol was carried out using a two-stage dilution system in which the first stage dilution occurs as a free jet. Particle size distributions were measured using a TSI 3934 scanning mobility particle sizer. Generally speaking, the presence of the additives did not have a strong, consistent influence on the particle emissions from this engine. The polyether amine demonstrated a reduction in particle number concentration as compared to unadditized base fuel.

Two types of in-cylinder optical probes were applied to a single cylinder CFR engine to detect knocking combustion. The first probe was integrated directly into the engine spark plug to monitor the radiation from burned gas in the combustion process. The second was built into a steel body and installed near the end gas region of the combustion chamber. It measured the radiant emission from the end gas in which knock originates. The measurements were centered in the near infrared region because thermal radiation from the combustion products was believed to be the main source of radiation from a spark ignition engine. As a result, ordinary photo detectors can be applied to the system to reduce its cost and complexity. It was found that the measured luminous intensity was strongly dependent upon the location of the optical sensor.

This report describes tests of a fuel additive in a medium-duty, high-swirl, direct-injection diesel engine. The additive was found to have little influence on general combustion performance or on NOx emissions. On the other hand, it had a profound effect on particulate emissions. This was most clear under high load where particle emissions are highest. Here, when the engine was switched from running on the base fuel to the additive treated fuel, particle emissions at first increased and then fell to levels about 40% lower (by particle volume) than those initially produced by the base fuel. The additive had a long lasting effect. After running with the additive for about 25 hours, emission levels with the base fuel were only slightly higher than those with the additive treated fuel. We believe that the additive action is associated with a combination of cleaning and surface conditioning. More work should be done to understand the relative importance of these two mechanisms.