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Three-way catalytic converters used on spark ignition engines have performance and durability characteristics which are effected by the thermal environment in which these operate. The design of the exhaust system and the location of the catalyst unit are important in controlling the range of thermal states the catalyst is exposed to. A model of system thermal behaviour has been developed to support studies of these. The exhaust system is modelled as connected pipe and junction elements with lumped thermal capacities. Heat transfer correlations for quasi-steady and transient conditions have been investigated. The catalytic converter is treated as elemental slices in series. Exothermic heat release and heat exchange between the monolith, mat, and shell are described in the model. A similar description is applied to lean NOx trap units.

Experimental studies of fuel utilisation during the early stages of engine warm-up after cold-starts are reported. The investigation has been carried out on a 1.81, 4 cylinder spark-ignition engine with port electronic fuel injection. The relationship between fuel supplied and fuel accounted for by the analysis of exhaust gas composition shows that a significant mass of fuel supplied is temporarily stored or permanently lost. An interpretation of data is made which allows time-dependent variations of these to be separately resolved and estimates of fuel quantities made. The data covers a range of cold-start conditions down to -5°C at which, on a per cylinder basis, fuel stored peaks typically at around 0.75g and a total of 1g is returned over 100 seconds of engine running. Fuel lost past the piston typically accounts for 2g over 200 to 300 seconds of running.