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Knock in a Rotax-914 engine was modeled and investigated using an improved version of the KIVA-3V code with a G-equation combustion model, together with a reduced chemical kinetics model. The ERC-PRF mechanism with 47 species and 132 reactions [1] was adopted to model the end gas auto-ignition in front of the flame front. The model was validated by a Caterpillar SI engine and a Rotax-914 engine in different operating conditions. The simulation results agree well with available experimental results. A new engineering quantified knock criterion based on chemical mechanism was then proposed. Hydroperoxyl radical (HO2) shows obvious accumulation before auto-ignition and a sudden decrease after auto-ignition. These properties are considered to be a good capability for HO2 to investigate engine knock problems.

The infrared radiation method of compression and end-gas temperature measurement was applied to the problem of measuring gas temperatures up to the time of knock. Pressure data were taken for each run on a CFR engine with mixtures of isooctane and n-heptane under both knocking and nonknocking conditions. Main engine parameters studied were the intake pressure, intake temperature, and engine speed. The rate and extent of chemical energy release were calculated from the temperature and pressure histories using an energy balance. The computed rates of chemical energy release were correlated to a chain-type kinetic model

The results of both theoretical and experimental studies on the self-ignition of single pure hydrocarbon drops are described. In this work single drops were subjected to air streams heated to such degrees that self-ignition of the drops would occur. Experimental heat and mass transfer parameters, as well as ignition delay data for different fuels and at different operating conditions were obtained. The experimental data were then used in conjunction with boundary layer correlations to evaluate the extent of the ignition delay that is physical (vaporization) and chemical (molecular interaction).

THE PRESENT WORK uses both the hot-motored technique and a nitrogen technique to obtain three pressure-time records — one without either vaporization or chemical reaction, one with vaporization only, and one with both vaporization and chemical reaction. By comparison of these three records, rates of vaporization and rates of chemical reaction can be determined during the ignition delay period in an operating diesel engine. Such data are shown for different fuels and operating conditions. Estimations are made of the penetration and temperatures existing in the spray.*

AN analysis of phenomena occurring during the ignition delay period is presented. Vaporization of atomized fuel is shown to take place under conditions ranging between single droplet and adiabatic saturation from edge to center of the spray. Mechanisms of vaporization and combustible mixture formation are presented for both cases. Correlation of theoretical analysis with experimental data from both a combustion bomb and diesel engine is presented to establish actual conditions existing during vaporization. Estimates of physical and chemical delays for the engine and bomb are given.

THIS paper is a sequel of the paper, “Photo-Electric Combustion Analysis,” presented at the 1936 Semi-Annual Meeting of the Society. The indicator described in that paper has been used to study combustion of 28 fuels and chemicals. A complete table of information of the materials used as fuels is included. The results obtained from over 1000 oscillograms show a different shape of ignition-lag curve versus injection advance angle than it is ordinarily thought to have. Even though the cetane values for these 28 fuels varied from 24 to 100, they all had nearly the same ignition lag when injected near the dead-center position. This minimum value is shown to be about 1/1000 sec. The fuels of higher-cetane value reach this minimum at an earlier injection angle than do those of low-cetane value. The paper shows how a high-cetane fuel can be just as rough as a low-cetane fuel if the injection timing is too early.