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This is the first part of a two-part study on how to define the anti-knock quality of practical fuels. Knock intensity is measured in two single-cylinder research engines using different fuels at different mixture strengths, throttle settings and two compression ratios. The anti-knock quality of a fuel in a given engine operating condition is defined by its octane index OI = RON - KS where K is a constant for that condition and S is the sensitivity, (RON-MON), and RON and MON are the Research and Motor Octane numbers respectively. The higher the octane index, the better the anti-knock quality of the fuel. K is often assumed to be 0.5 so that OI=(RON+MON)/2. However, it is found that K depends on engine operating conditions and in some cases, K is negative so that for a given RON, a fuel with higher sensitivity (lower MON) has better anti-knock quality. The value of K decreases as the engine becomes more prone to knock i.e. as its octane requirement increases.

An investigative group set up under the auspices of the CEC (Coordinating European Council) collected data on combustion chamber deposits (CCD), ASTM unwashed gum (UWG) results and the thermogravimetric analysis (TGA) of these gums for different fuels from many different sources. The analysis of this data shows that UWG cannot and does not predict CCD. It is not possible to use UWG or any aspect of its behaviour in the TGA to assess the CCD-forming tendency of randomly chosen fuels.