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Technical Paper

Development of Mo-Free Ultra-High Strength 1.6-GPa Bolt with Delayed Fracture Resistance for Multi-Link Type Engine

2024-04-09
2024-01-2070
Mo-free 1.6-GPa bolt was developed for a Variable Compression Turbo (VC-Turbo) engine, which is environment friendly and improves fuel efficiency and output. Mo contributes to the improvement of delayed fracture resistance; therefore, the main objective is to achieve both high strength and delayed fracture resistance. Therefore, Si is added to the developed steel to achieve high strength and delayed fracture resistance. The delayed fracture tests were performed employing the Hc/He method. Hc is the limit of the diffusible hydrogen content without causing a delayed fracture under tightening, and He is the diffusible hydrogen content entering under a hydrogen-charging condition equivalent to the actual environment. The delayed fracture resistance is compared between the developed steel and the SCM440 utilized for 1.2-GPa class bolt as a representative of the current high-strength bolts.
Journal Article

Development of Resin Water Jacket Case for Traction Inverter Aiming to Downsizing and Light-Weighting

2022-03-29
2022-01-0719
The size and weight of the traction inverter needs to be reduced to ensure a sufficient cruising range of an electric vehicle. To this end, one approach involves changing materials of the inverter case from aluminum to resin. However, the resin in use of inverter case causes technical issues in terms of collision performance, electromagnetic compatibility (EMC), and cooling performance because of the difference in the material properties between the resin and the conventionally used aluminum. By solving the abovementioned issues, a resin water jacket case (hereinafter, resin water jacket) was successfully adopted with inverters designed for next-generation electric powertrain in mass production models for the first time. The resin-based structure had advantages to reduce the weight of the inverter case by ~35% and decrease the number of parts to ~3/5, compared to that for the conventional cases.
Technical Paper

A Novel Integrated Series Hybrid Electric Vehicle Model Reveals Possibilities for Reducing Fuel Consumption and Improving Exhaust Gas Purification Performance

2021-09-21
2021-01-1244
This paper describes the development of an integrated simulation model for evaluating the effects of electrically heating the three-way catalyst (TWC) in a series hybrid electric vehicle (s-HEV) on fuel economy and exhaust gas purification performance. Engine and TWC models were developed in GT-Power to predict exhaust emissions during transient operation. These models were validated against data from vehicle tests using a chassis dynamometer and integrated into an s-HEV model built in MATLAB/Simulink. The s-HEV model accurately reproduced the performance characteristics of the vehicle’s engine, motor, generator, and battery during WLTC mode operation. It can thus be used to predict the fuel consumption, emissions, and performance of individual powertrain components. The engine combustion characteristics were reproduced with reasonable accuracy for the first 50 combustion cycles, representing the cold-start condition of the driving mode.
Technical Paper

Reaction Analysis and Modeling of Fast SCR in a Cu-Chabazite SCR Catalyst Considering Generation and Decomposition of Ammonium Nitrate

2021-09-05
2021-24-0073
In this study, reaction path analysis and modeling of NOx reduction phenomena by fast SCR reaction on a Cu-chabazite catalyst were conducted, considering the formation and decomposition of ammonium nitrate (NH4NO3). White crystals of NH4NO3 decompose at temperatures < 200 °C. Thus, the reaction behavior changes at 200 °C under fast SCR reaction conditions. NH4NO3 formation can occur on both Cu sites and Brønsted acid sites, which are active sites for NOx reduction in the Cu-chabazite catalyst, but it is unclear where NH4NO3 accumulates on the catalyst. Analyses using catalyst test pieces with different active sites were performed to estimate this accumulation. The results suggested that NH4NO3 accumulation does not depend on the presence of either Cu sites or Brønsted acid sites. Therefore, it is assumed that NH4NO3 can be accumulated everywhere on the catalyst, including on the zeolite framework. This phenomenon was included in the model as formation/accumulation sites S'.
Technical Paper

Conversion Performance Prediction of Thermal-Deteriorated Three-Way Catalysts: Surface Reaction Model Development Considering Platinum Group Metals and Co-Catalyst

2021-09-05
2021-24-0077
Three-way catalyst (TWC) converters can purify harmful substances, such as carbon monoxide, nitrogen oxides, and hydrocarbons, from the exhaust gases of gasoline engines. However, large amounts of these substances may be emitted before the TWC reaches its light-off temperature during cold starts, and its performance may be impaired by thermal deterioration during high-load driving. In this work, a simulation model was developed using axisuite commercial software by Exothermia S.A to predict the light-off conversion performance of Pd/CeO2-ZrO2-Al2O3 catalysts with different degrees of thermal deterioration. The model considered detailed surface reactions and the main factor of the deterioration mechanism. In the detailed reaction mechanism, adsorption, desorption, and surface reactions of each gas species at active sites of the platinum group metal (PGM) particles were considered based on the Langmuir-Hinshelwood mechanism.
Technical Paper

Three-Way Catalytic Reaction in an Electric Field for Exhaust Emission Control Application

2021-04-06
2021-01-0573
To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.
Journal Article

Stainless Steel Thermal Spray Coating of Cylinder Bores for VC-Turbo Engine

2021-04-06
2021-01-0343
Nissan’s variable compression turbo (VC-Turbo) engine has a multilink mechanism that continuously adjusts the top and bottom dead centers of the piston to change the compression ratio and achieve both fuel economy and high power performance. Increasing the exhaust gas recirculation (EGR) rate is an effective way to further reduce the fuel consumption, although this increases the exhaust gas condensation in the cylinder bores, causing a more corrosive environment. When the EGR rate is increased in a VC-Turbo engine, the combined effect of piston sliding and exhaust gas condensation at the top dead center accelerates the corrosive wear of the thermal spray coating. Stainless steel coating is used to improve the corrosion resistance, but the adhesion strength between the coating and the cylinder bores is reduced.
Technical Paper

Reaction Path Analysis and Modeling of NOx Reduction in a Cu-chabazite SCR Catalyst Considering Cu Redox Chemistry and Reversible Hydrolysis of Cu Sites

2020-09-15
2020-01-2181
In this study, reaction path analysis and modeling of NOx reduction phenomena by selective catalytic reduction (SCR) with NH3 over a Cu-chabazite catalyst were conducted considering changes in the valence state of Cu sites and local structure due to differences in ligands to the Cu sites. The analysis showed that in the Cu-chabazite catalyst, NOx was mainly reduced by adsorbed NH3 on divalent Cu sites accompanied by a change in valence state of Cu from divalent to monovalent. It is known that the activation energy of NOx reduction on a Cu-chabazite catalyst changes between low temperatures ≤ 200 °C and mid to high temperatures ≥ 300 °C. To express this phenomenon, a reversible hydrolysis reaction based on the difference in coordination state of hydroxyl groups (OH−) to Cu sites at low and high temperatures was introduced into the model.
Technical Paper

Development of JASO GLV-1 0W-8 Low Viscosity Engine Oil for Improving Fuel Efficiency considering Oil Consumption and Engine Wear Performance

2020-04-14
2020-01-1423
Engine oil with viscosity lower than 0W-16 has been needed for improving fuel efficiency in the Japanese market. However, lower viscosity oil generally has negative aspects with regard to oil consumption and anti-wear performance. The technical challenges are to reduce viscosity while keeping anti-wear performance and volatility level the same as 0W-20 oil. They have been solved in developing a new engine oil by focusing on the molybdenum dithiocarbamate friction modifier and base oil properties. This paper describes the new oil that supports good fuel efficiency while reliably maintaining other necessary performance attributes.
Technical Paper

Effects of Using an Electrically Heated Catalyst on the State of Charge of the Battery Pack for Series Hybrid Electric Vehicles at Cold Start

2020-04-14
2020-01-0444
Battery models are being developed as a component of the powertrain systems of hybrid electric vehicles (HEVs) to predict the state of charge (SOC) accurately. Electrically heated catalysts (EHCs) can be employed in the powertrains of HEVs to reach the catalyst light off temperature in advance. However, EHCs draw power from the battery pack and hence sufficient energy needs to be stored to power auxiliary components. In series HEVs, the engine is primarily used to charge the battery pack. Therefore, it is important to develop a control strategy that triggers engine start/stop conditions and reduces the frequency of engine operation to minimize the equivalent fuel consumption. In this study, a battery pack model was constructed in MATLAB-Simulink to investigate the SOC variation of a high-power lithium ion battery during extreme engine cold start conditions (-7°C) with/without application of an EHC.
Technical Paper

Analysis of NH3 Diffusion Phenomena in a Selective Catalytic Reduction Coated Diesel Particulate Filter Catalyst Using a Simple One-Dimensional Core Model

2019-12-19
2019-01-2236
This paper describes a method for estimating constants related to NH3 gas diffusion phenomena to the active sites in a selective catalytic reduction diesel particulate filter (SCR/DPF) catalyst. A simple one-dimensional NH3 gas diffusion model based on the pore structure inside the catalyst was developed and used to estimate the intracrystalline diffusion coefficient. It was shown that the estimated value agreed well with experimental data.
Technical Paper

Design Methodology for Motor Thermal Management in Vehicle Electrification

2019-12-19
2019-01-2368
In order to improve the accuracy of the coil temperature prediction, detailed fundamental experiments have been conducted on thermal resistances that are caused by the void air gap and contact surfaces. The thermal resistance of the coil around the air gap can be calculated by an air gap distance and air heat conductivity. Contact surface thermal resistance between the core and the housing was constant regardless of the press-fitting state in this experiment. Prediction accuracy of the coil temperature is improved by including the heat resistance characteristics that is obtained by the basic experiment to conjugate heat transfer analysis model.
Technical Paper

Modeling Three-Way Catalyst Converters During Cold Starts And Potential Improvements

2019-12-19
2019-01-2326
Three-way catalyst (TWC) converters are often used to purify toxic substances contained in exhaust emissions from gasoline engines. However, a large amount of CO, NOx and THC may be emitted before the TWC reaches its light-off temperature during a cold start. In this work, a numerical model was developed for studying the purification performance of a close-coupled TWC converter during the cold start period. The TWC model was built using axisuite, commercial software by Exothermia S.A. Model gas experiments were designed for calibrating the chemical reaction scheme and corresponding reaction rate parameters in the TWC model. The TWC model was able to simulate the purification performance of CO, NOx and THC under both lean and rich air-fuel equivalence ratios (λ) for different conditions. The light-off temperature and oxygen storage capacity (OSC) behavior were also successfully validated in the model. Vehicle tests were conducted on a chassis dynamometer to verify the TWC model.
Technical Paper

Development of Plastic Region Tightening 1.6-GPa Ultra-High Strength Bolt with High Delayed Fracture Resistance

2019-04-02
2019-01-1116
A new variable compression turbo (VC-Turbo) engine, which has a multi-link system for controlling the compression ratio from 8:1 to 14:1, requires high axial force for fastening the multi-links because of high input loads and the downsizing requirement. Therefore, it was necessary to develop a 1.6-GPa tensile strength bolt with plastic region tightening. One of the biggest technical concerns is delayed fracture. In this study, quenched and tempered alloy steels were chosen for the 1.6-GPa tensile strength bolt.
Technical Paper

Validation of Wireless Power Transfer up to 11kW Based on SAE J2954 with Bench and Vehicle Testing

2019-04-02
2019-01-0868
Wireless Power Transfer (WPT) promises automated and highly efficient charging of electric and plug-in-hybrid vehicles. As commercial development proceeds forward, the technical challenges of efficiency, interoperability, interference and safety are a primary focus for this industry. The SAE Vehicle Wireless Power and Alignment Taskforce published the Recommended Practice J2954 to help harmonize the first phase of high-power WPT technology development. SAE J2954 uses a performance-based approach to standardizing WPT by specifying ground and vehicle assembly coils to be used in a test stand (per Z-class) to validate performance, interoperability and safety. The main goal of this SAE J2954 bench testing campaign was to prove interoperability between WPT systems utilizing different coil magnetic topologies. This type of testing had not been done before on such a scale with real automaker and supplier systems.
Technical Paper

Kinetic Modeling of Ammonia-SCR and Experimental Studies over Monolithic Cu-ZSM-5 Catalyst

2019-01-15
2019-01-0024
Ammonia-selective catalytic reduction (SCR) systems have been introduced commercially in diesel vehicles, however catalyst systems with higher conversion efficiency and better control characteristics are required to know the actual emissions during operation and the emissions in random test cycles. Computational fluid dynamics (CFD) is an effective approach when applied to SCR catalyst development, and many models have been proposed, but these models need experimental verification and are limited in the situations they apply to. Further, taking account of redox cycle is important to have better accuracy in transient operation, however there are few models considering the cycle. Model development considering the redox reactions in a zeolite catalyst, Cu-ZSM-5, is the object of the research here, and the effects of exhaust gas composition on the SCR reaction and NH3 oxidation at high temperatures are investigated.
Technical Paper

Effects of Soot Deposition on NOx Purification Reaction and Mass Transfer in a SCR/DPF Catalyst

2018-09-10
2018-01-1707
Experimental studies were carried out to investigate the effect of soot deposition on NOx purification phenomena in an ammonia selective catalytic reduction coated diesel particulate filter (SCR/DPF) catalyst. To study soot deposition effects on the chemical reactions and mass transfer, two types of testing device were used. A synthetic gas bench enabling tests to be conducted with temperature and flow rate ranges relevant to real driving conditions was used to investigate the soot influence on reduction of NOx to N2 (DeNOx). A micro-reactor that removed the effect of soot deposition on mass transfer in the catalyst layer was used to analyze chemical reactions on a soot surface and their interaction with the SCR catalyst. A filter test brick of a Cu-zeolite SCR/DPF catalyst and a powder catalyst were used for the synthetic gas bench and micro-reactor tests, respectively. Engine soot was sampled in all the tests.
Technical Paper

Development of High Accuracy Rear A/F Sensor

2017-03-28
2017-01-0949
New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.
Journal Article

Development of Low Viscosity API SN 0W-16 Fuel-Saving Engine Oil Considering Chain Wear Performance

2017-03-28
2017-01-0881
A low viscosity API SN 0W-16 engine oil was developed to achieve a 0.5% improvement in fuel efficiency over the current GF-5/API SN 0W-20 oil. Oil consumption and engine wear are the main roadblocks to the development of low viscosity engine oils. However, optimization of the base oil and additives successfully prevent oil consumption and wear. First, it was confirmed in engine tests that NOACK volatility is still an effective indicator of oil consumption even for a low viscosity grade like 0W-16. As a result of base oil volatility control, the newly developed oil achieves the same level of oil consumption as the current GF-5/API SN 0W-20 oil. Second, it was found that the base oil viscosity and molybdenum dithiocarbamate (MoDTC) had a significant effect on chain wear in rig testing that simulated silent chain wear. For the same base oil viscosity, the new oil maintains the same oil film thickness under high surface pressure.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
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