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The majority of today’s natural gas fired engines are applying a premixed combustion concept, which is commonly assumed to be based on the turbulence-enhanced propagation of a thin flame separating the burnt and unburnt fractions of the mixture volume. This concept has been confirmed by means of comprehensive experimental investigations on passenger car engines operating at air/fuel ratios close to stoichiometry; however, for larger industrial engines (4-stroke and 2-stroke) designed for ultra-lean (λ >1.8) operation in order to achieve highest efficiencies, this assumption is no longer valid, as will be shown in the following. On these engines, the combustion process is largely controlled by the reaction kinetics of the chemistry and hence exhibits more similarity to homogeneous charge or spark assisted compression ignition (HCCI or SACI) combustion concepts.