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Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.

As part of efforts to address climate change and improve energy security, researchers have improved the thermal efficiency of engines by expanding the lean combustion limit. To further expand the lean combustion limit, the authors focused not only on engine technology but the chemical reactivity of various fuel molecules. Furan and anisole were among the fuel molecules selected, based on the idea that promising candidates should enhance the flame propagation speed and have good knocking resistance. Engine testing showed that the lean limit can be expanded by using fuels with the right molecular structures, resulting in higher thermal efficiency.

In recent years, improving the engine thermal efficiency is strongly required. To enhance the engine thermal efficiency, it is important to improve the engine anti-knock quality. Technologies for modifying engine cooling have been developed to improve anti-knocking quality of engines. However, excessive improvement of engine cooling leads to an increase in cooling heat loss. Therefore, it is necessary to clarify the effects of the temperature of each part of the engine such as engine head-cylinder, cylinder-liner, and piston on knocking and cooling heat loss. In this paper, computer aided engineering (CAE) is used to predict the effects of each part of the engine on engine knocking and cooling heat loss. Firstly, the amount of heat energy that air-fuel mixture receives from engine cylinder-head, cylinder-liner, and piston is calculated during the intake stroke. The result shows that the cylinder-liner contributes largest heat energy to air-fuel mixture, especially the exhaust side.