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Polymers are often blended to create compounds with new or enhanced properties in order to compensate for an individual polymer's weakness or lack of inherent properties. In the field of polymer foaming, polymer blends are also used to generate fine-cell structures via heterogeneous nucleation. Recently, an interest in physical blowing agents, such CO2 and N2, has increased because of their low impact on the environment. It has thus become additionally important to pursue research on the foaming of polymer blends employing these particular physical blowing agents in an effort to keep up with the demand for environmentally friendly products. In this study, thermoplastic polyolefin (TPO) blends were prepared with polypropylene (PP) and a metallocene-based polyolefin elastomer (POE) using twin-screw extruders and a batch mixer.

This research presents a fundamental study of the interaction between chemically modified wood fibers and high density polyethylene (HDPE) to develop wood fiber/HDPE composites with satisfactory performance. This paper investigates the effects of the interfacial properties of HDPE and wood fibers on the rheological properties and foaming behavior of the composites. The surface characteristics of wood fiber were modified by treating the fiber with trialkoxy silane. The effectiveness of chemical surface modifications of wood fiber was characterized using FT-IR. The effect of the interfacial interaction on the foaming behavior was studied via extrusion foaming with a physical blowing agent. The rheological property of the composites with a different interfacial structure were also evaluated by using dynamic oscillatory rheometer.

This study compared the mechanical properties of rice hull/high density polyethylene composites with those of maple wood-based counterparts. In addition, the effects of maleated polymers on the mechanical properties of rice hull and maple wood composites were investigated. Six types of maleated polymers (coupling agents) were used to improve mechanical properties, of the composites, especially notched Izod impact strength. The results suggested that the maple wood composites showed higher strength, modulus and impact strength than the rice hull composites. The results also indicated that maleated thermoplastic elastomers increased notched Izod impact strength of both composites dramatically. However, it was found that Maleated metallocene polyethylene was the most effective coupling agent that increased notched impact strength without sacrificing tensile and flexural strength.

Thermoplastic Vulcanizate (TPV) is a special class of Thermoplastic Elastomers (TPEs) made of a rubber/plastic polymer mixture in which the rubber phase is highly vulcanized. It is prepared by melt mixing a thermoplastic with an elastomer and by in-situ crosslinking of the rubber phase. Currently, TPV is replacing EPDM rubber dramatically because of the impressive advantages for automotive sealing applications. Some of the advantages of TPV compared to that of EPDM rubber are good gloss, recyclability, improved colorability, shorter cycle time and design flexibility. The development of TPV foaming technology is to fulfill the requirement of achieving lower cost, lighter weight and better fuel economy. Foaming of TPV has not been investigated extensively.

Foaming of a thermoplastic polyolefin (TPO) is gaining interests because of its superior mechanical properties of foamed automotive parts, such as lightweight and high performance to weight ratio, etc. In this context, understanding of the thermophysical properties of PP/gas and TPO/gas mixtures is critically important. This paper will present the newly developed experimental technique to accurately measure the swelling of PP and TPO due to gas dissolution at elevated temperatures and pressures. Our technique measures the geometry of the pendent drop accurately from the captured images to obtain the volume swelling data. It determines the boundary location of the polymer/gas sample accurately by magnifying the sample drop locally along its edge before capturing the image. The automated high-precision XY stage is chosen as the platform to control the motion of the CCD camera.

Determination of the solubility of a blowing agent, i.e. supercritical N2, in polypropylene (PP) and elastomer material is crucial for achieving high-quality thermoplastic polyolefin (TPO) foams in automotive industry. A magnetic suspension balance (MSB) was employed in the experiments to measure the apparent solubility, while the swollen volume predicted by the Sanchez-Lacombe (SL) equation of state (EOS) was used to account for the buoyancy effect. The volume swelling of the polymer/gas mixture and the gas solubilities for both PP and polyolefin elastomer were discussed.

Foaming of thermoplastic polyolefins (TPO) and thermoplastic elastomers (TPE) is gaining interest because of the lightweight and high performance to weight ratio of foamed automotive parts. Since foaming will occur mainly in the PP matrix in these PP-based automotive materials, understanding of the thermophysical properties of PP/gas mixtures is critically important. This paper will present a proposed methodology for measuring the swelling of polymer/gas mixtures. The preliminary experimental measurement of PP/N2 swelling at elevated temperatures and pressures will be discussed.

Determination of the solubility of a blowing agent, i.e. supercritical CO2 or N2, in polypropylene (PP) is crucial for achieving high-quality PP and thermoplastic polyolefin (TPO) foams. A magnetic suspension balance (MSB) was employed in the experiments to measure the apparent solubility, while the swollen volume predicted by the Sanchez-Lacombe (SL) equation of state (EOS) and Simha-Somcynsky (SS) EOS was used to account for the buoyancy effect. The gas solubilities for both linear and branched PP were calculated and the effects of branching on the swollen volume and gas solubility were discussed.