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Technical Paper

Ignition Delay Time of a Toluene Reference Fuel with Substituted Phenol Additives

2023-04-11
2023-01-0321
Rapid compression machines can be used to measure a fuel’s ignition delay time and develop an understanding of its resistance to autoignition. Continuing developments in engine design demand higher octane fuels that are resistant to autoignition. Substituted phenols are members of the aromatic hydrocarbon family, and aromatics like toluene are often added to pump-grade gasoline to increase the fuel octane number. Previous numerical and experimental studies have found that substituted phenols included at additive levels in gasoline surrogates, such as the toluene reference fuel in this study, may have a lengthening effect on the ignition delay time of the base fuel they are added to.
Technical Paper

Laminar Burning Velocities of Diluted Stoichiometric Hydrogen/Air Mixtures

2023-04-11
2023-01-0331
Since its implementation, exhaust gas recirculation has proven to be a reliable technique to control NOx emissions by lowering combustion temperature. Dilution with exhaust gas recirculation, whether in internal combustion engines or sequential-staged gas turbine combustors, affects flame reactivity and stability, which are related to the heat release rate and engine power. Another way to control emissions is to use hydrogen as a carbon-free alternative fuel, which is considered a milestone in the energy-decarbonization journey. However, the high reactivity of hydrogen is one of its hurdles and understanding this effect on laminar burning velocity is important. Flame propagation and burning velocity control the mixture reactivity and exothermicity and are related to abnormal combustion phenomena, such as flashback and knock. Therefore, understanding the effect of exhaust gas addition on the laminar burning velocity of hydrogen/air mixtures is imperative for engine design.
Technical Paper

Effect of Substituted Phenol Fuel Additives on Ignition Delay of a Toluene Reference Fuel

2022-03-29
2022-01-0516
Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine.
Technical Paper

Impact of CO2 Dilution on Ignition Delay Times of Full Blend Gasolines in a Rapid Compression Machine

2021-09-21
2021-01-1199
Autoignition delay times of two full blend gasoline fuels (high and low RON) were explored in a rapid compression machine. CO2 dilution by mass was introduced at 0%, 15%, and 30% levels with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy is used to represent exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines by using CO2 as a surrogate for major EGR constituents(N2, CO2, H2O). Experiments were conducted over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. The full blend fuels were admitted directly into the combustion chamber for mixture preparation using the direct test chamber (DTC) approach. CO2 addition retarded the autoignition times for the fuels studied here. The retarding effect of the CO2 dilution was more pronounced in the NTC region when compared to the lower and higher temperature range.
Technical Paper

A Qualitative Comparison of the Macroscopic Spray Characteristics of Gasoline Mixtures and their Multi-Component Surrogates Using a Rapid Compression Machine

2021-04-06
2021-01-0558
Rapid Compression Machines (RCM) offer the ability to easily change the compression ratio and the pressure/mixture composition/temperature to gather ignition delay data at various engine relevant conditions. Therefore, RCMs with optical access to the combustion chamber can provide an effective way to analyze macroscopic spray characteristics needed to understand the spray injection process and for spray model development, validation and calibration at conditions that are suitable for engines. Fuel surrogates can help control fuel parameters, develop models for spray and combustion, and perform laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of multicomponent gasoline surrogates in comparison to their gasoline counterparts, under gasoline direct injection (GDI) engine conditions.
Technical Paper

A Rapid Compression Machine Study on Ignition Delay Times of Gasoline Mixtures and their Multicomponent Surrogate Fuels under Diluted and Undiluted Conditions

2021-04-06
2021-01-0554
In this work autoignition delay times of two multi-component surrogates (high and low RON) were experimentally compared with their target full blend gasoline fuels. The study was conducted in a rapid compression machine (RCM) test facility and a direct test chamber (DTC) charge preparation approach was used for mixture preparation. Experiments were carried over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. Dilution in the reactant mixture was varied from 0% to 30% CO2 (by mass), with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy emulates exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. The multicomponent surrogate captured the reactivity trends of the gasoline-air mixtures reasonably well in comparison to the single component (iso-octane) surrogate.
Technical Paper

Effect of Changing Compression Ratio on Ignition Delay Times of Iso-Octane in a Rapid Compression Machine

2020-04-14
2020-01-0338
Previous studies have shown that several facility dependent factors can influence ignition delay times measured in a rapid compression machine. Compression ratio variation represents one such aspect of many facility-to facility differences in RCMs, and can have a major impact on measured ignition delay times due to changes in surface-area-to-volume ratio, initial conditions and compression duration even when the same compressed conditions are maintained. In this study, iso-octane, which exhibits two stage ignition delay and has a pronounced negative temperature coefficient (NTC) region, is used to investigate the effects of changing compression ratio on ignition delay. Resulting trends are also compared to previous results obtained with ethanol, which has very different combustion properties. Experiments were carried out for rich mixtures (ϕ = 1.3) of iso-octane and air over a compressed temperature range of 675-900 K at 20 bar compressed pressure.
Technical Paper

An Experimental Study on the Factors Affecting Ethanol Ignition Delay Times in a Rapid Compression Machine

2019-04-02
2019-01-0576
Ignition delay, using a rapid compression machine (RCM), is defined as the time period between the end of compression and the maximum rate of pressure rise due to combustion, at a given compressed condition of temperature and pressure. The same compressed conditions can be reached by a variety of combinations of compression ratio, initial temperature, initial pressure, diluent gas composition, etc. It has been assumed that the value of ignition delay, for a given fuel and at a given set of compressed conditions, would be the same, irrespective of the variety of the above-mentioned combinations that were used to achieve the compressed conditions. In this study, a range of initial conditions and compression ratios are studied to determine their effect on ignition delay time and to show how ignition delay time can differ even at the same compressed conditions.
Technical Paper

Impact of CO2 Dilution on Ignition Delay Times of Iso-Octane at 15% and 30% Dilution Levels in a Rapid Compression Machine

2019-04-02
2019-01-0569
Iso-Octane (2,2,4-trimethlypentane) is an important gasoline primary reference fuel (PRF) surrogate. Auto ignition of iso-octane was examined using a rapid compression machine (RCM) with iso-octane, air and carbon dioxide (CO2) mixtures. Experiments were conducted over a temperature range of 650K-900K at 20bar and 10 bar compressed conditions for equivalence ratios (Φ =) 0.6, 0.8, 1.0 and 1.3. CO2 dilution by mass was introduced at 0%, 15% and 30% levels with the O2:N2 mole ratio fixed at 1:3.76 emulating the exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. In this study the direct test chamber (DTC) approach is used for introducing iso-octane directly into the RCM test chamber via a direct injector. The results using this approach are compared with other RCM data available in the literature at undiluted Φ = 1.0 and 20 bar compressed pressure and show good agreement.
Journal Article

Laminar Flame Speeds of Premixed Iso-Octane/Air Flames at High Temperatures with CO2 Dilution

2019-04-02
2019-01-0572
Spherically expanding flames are employed to measure the laminar flame speed of premixed iso-octane/air mixtures at elevated temperatures through both experiments and numerical simulations. Iso-octane (2,2,4-trimethlypentane) is an important gasoline primary reference fuel (PRF). While most studies on laminar burning velocity of iso-octane focus on low temperatures (less than 400 K), the experiments here were conducted in an optically accessible constant volume combustion chamber between 373 K-473 K, at a pressure of 1 bar, and from ϕ=0.8 to ϕ=1.6. The effect of diluent is investigated through the addition of 15% CO2 dilution in order to simulate the effect of exhaust gas recirculation. The decreased reactivity with diluent addition reduces mixture reactivity, which can reduce the propensity for knock in spark ignition engines. All laminar flame speeds were calculated using the constant pressure method enabled via schlieren visualization of the spherically propagating flame front.
Technical Paper

Performance Assessment of a Single Jet, Dual Diverging Jets, and Dual Converging Jets in an Auxiliary Fueled Turbulent Jet Ignition System

2018-04-03
2018-01-1135
An auxiliary fueled prechamber ignition system can be used in an IC engine environment to provide lean limit extension with minimal cyclic variability and low emissions. Geometry and distribution of the prechamber orifices form an important criterion for performance of these systems since they are responsible for transferring and distributing the ignition energy into the main chamber charge. Combustion performance of nozzles with a single jet, dual diverging jets and dual converging jets for a methane fueled prechamber ignition system is evaluated and compared in a rapid compression machine (RCM). Upon entering the main chamber, the dual diverging jets penetrate the main chamber in opposite directions creating two jet tips, while the dual converging jets, after exiting the orifices, converge into a single location within the main chamber. Both these configurations minimize jet-wall impingement compared to the single jet.
Technical Paper

CFD Modeling and Experimental Analysis of a Homogeneously Charged Turbulent Jet Ignition System in a Rapid Compression Machine

2017-03-28
2017-01-0557
Three dimensional numerical simulation of the transient turbulent jet and ignition processes of a premixed methane-air mixture of a turbulent jet ignition (TJI) system is performed using Converge computational software. The prechamber initiated combustion enhancement technique that is utilized in a TJI system enables low temperature combustion by increasing the flame propagation rate and therefore decreasing the burn duration. Two important components of the TJI system are the prechamber where the spark plug and injectors are located and the nozzle which connects the prechamber to the main chamber. In order to model the turbulent jet of the TJI system, RANS k-ε and LES turbulent models and the SAGE chemistry solver with a reduced mechanism for methane are used.
Journal Article

Experimental Studies of a Liquid Propane Auxiliary Fueled Turbulent Jet Igniter in a Rapid Compression Machine

2016-04-05
2016-01-0708
Lean combustion is a promising combustion technology that has the potential to improve engine efficiency while decreasing emissions. One reason why lean combustion has not been more widely implemented is that as the air-fuel ratio increases, the resulting flame propagation speed becomes slower and combustion becomes unstable. Turbulent jet ignition is a pre-chamber ignition enhancement concept that facilitates ultra-lean combustion by using a hot combusting jet as a distributed ignition source. The jet penetration allows for shorter flame travel distances, which decreases the overall burn duration and improves stability. By using a rich mixture in the pre-chamber, the pre-chamber mixture is easily ignitable and the transport of chemically active radical species and unburned fuel into the main-chamber charge improves ignition quality.
Technical Paper

A Computational Study of the Effects of Spark Location on the Performance of a Turbulent Jet Ignition System

2016-04-05
2016-01-0608
In this purely computational study, fluid dynamic simulations with active combustion are performed for a Turbulent Jet Ignition (TJI) system installed in a rapid compression machine. The simulations compare the effects that the location of the TJI system’s spark ignition source inside the TJI’s prechamber have on the combustion within the system through the use of four simulations, which are all identically setup with the same initial and boundary conditions except for the location of their respective ignition sources. The four ignition sources are located along the centerline of the axisymmetric prechamber and at varied distances from the orifice exit of the prechamber. Comparison of the simulations demonstrate that the locations furthest from the orifice produce better main chamber ignition as reflected in shorter 0-10% mass fraction burn times. Meanwhile all three of the test cases that were not closest to the orifice all produced similar 10-90% mass fraction burn times.
Technical Paper

CFD Modeling of an Auxiliary Fueled Turbulent Jet Ignition System in a Rapid Compression Machine

2016-04-05
2016-01-0599
Three-dimensional numerical simulation of the turbulent jet ignition combustion process of a premixed methane-air mixture in a Rapid Compression Machine (RCM) was performed using the Converge computational software. Turbulent jet ignition is a prechamber initiated combustion system that can replace the spark plug in a spark ignition engine. The prechamber is a small volume chamber where an injector and spark plug are located and is connected to the main combustion chamber via one or multiple small orifices. Turbulent jet ignition is capable of enabling low temperature combustion, through either lean or dilute combustion. A RANS model, which included a k-ε turbulence model to solve the mean flow and the SAGE chemistry solver with a reduced methane mechanism to solve the chemistry, was used to model the turbulent jet ignition system.
Journal Article

Combustion Visualization, Performance, and CFD Modeling of a Pre-Chamber Turbulent Jet Ignition System in a Rapid Compression Machine

2015-04-14
2015-01-0779
Turbulent jet ignition is a pre-chamber ignition enhancement method that produces a distributed ignition source through the use of a chemically active turbulent jet which can replace the spark plug in a conventional spark ignition engine. In this paper combustion visualization and characterization was performed for the combustion of a premixed propane/air mixture initiated by a pre-chamber turbulent jet ignition system with no auxiliary fuel injection, in a rapid compression machine. Three different single orifice nozzles with orifice diameters of 1.5 mm, 2 mm, and 3 mm were tested for the turbulent jet igniter pre-chamber over a range of air to fuel ratios. The performance of the turbulent jet ignition system based on nozzle orifice diameter was characterized by considering both the 0-10 % and the 10-90 % burn durations of the pressure rise due to combustion.
Journal Article

An Integrated Model of Energy Transport in a Reciprocating, Lean Burn, Spark Ignition Engine

2015-04-14
2015-01-1659
This paper presents a combined experimental and numerical method for analysing energy flows within a spark ignition engine. Engine dynamometer data is combined with physical models of in-cylinder convection and the engine's thermal impedances, allowing closure of the First Law of Thermodynamics over the entire engine system. In contrast to almost all previous works, the coolant and metal temperatures are not assumed constant, but rather are outputs from this approach. This method is therefore expected to be most useful for lean burn engines, whose temperatures should depart most from normal experience. As an example of this method, the effects of normalised air-fuel ratio (λ), compression ratio and combustion chamber geometry are examined using a hydrogen-fueled engine operating from λ = 1.5 to λ = 6. This shows large variations in the in-cylinder wall temperatures and heat transfer with respect to λ.
Technical Paper

Computational Study of a Turbulent Jet Ignition System for Lean Burn Operation in a Rapid Compression Machine

2015-04-14
2015-01-0396
Fully three-dimensional computational fluid dynamic simulations with detailed chemistry of a single-orifice turbulent jet ignition device installed in a rapid compression machine are presented. The simulations were performed using the computational fluid dynamics software CONVERGE and its RANS turbulence models. Simulations of propane fueled combustion are compared to data collected in the optically accessible rapid compression machine that the model's geometry is based on to establish the validity and limitations of the simulations and to compare the behavior of the different air-fuel ratios that are used in the simulations.
Journal Article

Visualization of Propane and Natural Gas Spark Ignition and Turbulent Jet Ignition Combustion

2012-10-23
2012-32-0002
This study focuses on the combustion visualization of spark ignition combustion in an optical single cylinder engine using natural gas and propane at several air to fuel ratios and speed-load operating points. Propane and natural gas fuels were compared as they are the most promising gaseous alternative fuels for reciprocating powertrains, with both fuels beginning to find wide market penetration on the fleet level across many regions of the world. Additionally, when compared to gasoline, these gaseous fuels are affordable, have high knock resistance and relatively low carbon content and they do not suffer from the complex re-fueling and storage problems associated with hydrogen.
Technical Paper

Performance of a Port Fuel Injected, Spark Ignition Engine Optimised for Hydrogen Fuel

2012-04-16
2012-01-0654
This paper presents a study of the performance of a 6-cylinder, spark-ignited, port-fuel-injected, production engine modified for hydrogen fueling. The engine modifications include turbo-charging, multiple fuel injectors per port and charge-dilution control techniques. Pumping losses are reduced through ultra-lean burn and throttle-less operation alongside high charge dilution ratio control achieved by twin independent variable cam timing without external EGR. Lean-burn combustion, engine-out emissions and brake thermal efficiency results are examined in detail. In particular, low NO emissions and brake thermal efficiencies near 38% are observed experimentally at the same operating conditions. The former is explained in terms of the usual thermal NOx pathway. Usage of throttle position, injection timings and cam timings for avoiding preignition and knock over the entire engine map are also discussed.
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