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The combustion and emission characteristics of dual-fuel combustion were investigated using dimethyl ether direct injection and premixed low-carbon fuels. Dimethyl ether was used as the direct injection fuel for its high reactivity and low propensity to form particulate matter. Ethanol and Propane, two fuels of low reactivity, were premixed in the intake port. An injection timing sweep of varying premixed energy shares and engine loads was tested. Combustion analysis was conducted based on in-cylinder pressure measurements while detailed speciation of engine-out emissions was performed via FTIR. The proper injection advance and premixed energy share can realize low NOx and high combustion efficiency. Ethanol showed stronger impact to DME ignition delay as compared with propane.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

Taking advantages of high speed RGB video cameras, the two-color method can be implemented with a relatively simple setup to obtain the temporal development of the two dimensional temperature and soot (KL) distributions in a reacting diesel jet. However, several issues such as the selection of the two wavelengths, the role of bandpass filters, and the proper optical settings, etc. should be known to obtain a reliable measurement. This paper, at first, discusses about the uncertainties in the measurement of temperature and KL distributions in the diesel flame by the two-color method using the high speed RGB video camera. Since n-butanol, as an alternative renewable fuel, has the potential application in diesel engines, the characteristic of spray combustion of diesel-butanol blends under the diesel-like ambient conditions in a pre-burning constant-volume combustion chamber is studied.

In this work, empirical investigations of the diesel-ethanol Premixed Pilot-Assisted Combustion (PPAC) are carried out on a high compression ratio (18.2:1) single-cylinder diesel engine. The tests focus on determining the minimum ethanol fraction for ultra-low NOx & soot emissions, effect of single-pilot vs. twin-pilot strategies on emissions and ignition controllability, reducing the EGR requirements, enabling clean combustion across the load range and achieving high efficiency full-load operation. The results show that both low NOx and almost zero soot emissions can be achieved but at the expense of higher unburned hydrocarbons. Compared to a single-pilot injection, a twin-pilot strategy reduces the soot emissions significantly and also lowers the NOx emissions, thereby reducing the requirements for EGR. The near-TDC pilot provides excellent control over the combustion phasing, further reducing the need of a higher EGR quantity for phasing control.

Diesel aided by gasoline low temperature combustion offers low NOx and low soot emissions, and further provides the potential to expand engine load range and improve engine efficiency. The diesel-gasoline operation however yields high unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions. This study aims to correlate the chemical origins of the key hydrocarbon species detected in the engine exhaust under diesel-gasoline operation. It further aims to help develop strategies to lower the hydrocarbon emissions while retaining the low NOx, low soot, and efficiency benefits. A single-cylinder research engine was used to conduct the engine experiments at a constant engine load of 10 bar nIMEP with a fixed engine speed of 1600 rpm. Engine exhaust was sampled with a FTIR analyzer for speciation investigation.

Extensive empirical work indicates that exhaust gas recirculation (EGR) is effective to lower the flame temperature and thus the oxides of nitrogen (NOx) production in-cylinder in diesel engines. Soot emissions are reduced in-cylinder by improved fuel/air mixing. As engine load increases, higher levels of intake boost and fuel injection pressure are required to suppress soot production. The high EGR and improved fuel/air mixing is then critical to enable low temperature combustion (LTC) processes. The paper explores the properties of the Fuels for Advanced Combustion Engines (FACE) Diesel, which are statistically designed to examine fuel effects, on a 0.75L single cylinder engine across the full range of load, spanning up to 15 bar IMEP. The lower cetane number (CN) of the diesel fuel improved the mixing process by prolonging the ignition delay and the mixing duration leading to substantial reduction of soot at low to medium loads, improving the trade-off between NOx and soot.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

Simultaneous low NOx (< 0.15 g/kWh) & soot (< 0.01 g/kWh) are attainable for enhanced premixed combustion that may lead to higher levels of hydrocarbons and carbon monoxide emissions as the engine cycles move to low temperature combustion, which is a departure from the ultra low hydrocarbon and carbon monoxide emissions, typical of the high compression ratio diesel engines. As a result, the fuel efficiency of such modes of combustion is also compromised (up to 5%). In this paper, advanced strategies for fuel injection are devised on a modern 4-cylinder common rail diesel engine modified for single cylinder research. Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles. The fuel injection strategies include single injection with heavy EGR, and early multi-pulse fuel injection under low or medium engine loads respectively.

As a research of low temperature regeneration of DPF, combustion mechanism of diesel particulate matter (PM) trapped in DPF was investigated. For the assumption of PM combustion mechanism, the relationship between PM combustion characteristics and the physical properties of PM particles was investigated by using thermal and spectroscopic analysis methods. Experimental PM samples were produced under typical engine operating conditions using three representative fuels, two commercial diesel fuels containing aromatics (JIS-2 and Class 1) and a paraffin fuel that was prepared in a gas-to-liquid (GTL) process and did not contain any aromatics. Based upon these characteristics and combustion test results of the PM samples, a mechanism of the PM combustion was assumed. And the crystallinity of PM particles and existence of some surface functional groups containing oxygen are thought to be the important factors to lower the temperature of PM combustion., independent of the fuel type.

Diesel Particulate Filters (DPF) are viable to reduce smoke from diesel engines. An oxidation process is usually required to remove the Particulate Matter (PM) loading from the DPF substrates. In cases when the engine exhaust temperature is insufficient to initiate a thermal regeneration, supplemental energy is commonly applied to raise the exhaust gas and/or the DPF substrate temperatures. A flow reversal (FR) mechanism that traps a high temperature region in the DPF substrate by periodically altering the gas flow directions has been identified to be capable of reducing the supplemental energy and thus to improve the overall thermal efficiency of the engine. However, extended operations with low exhaust temperature lowers the DPF boundary temperatures that defers the regeneration processes. Furthermore, the temperature fluctuations caused by the periodic FR operation also increase the thermal stress in the DPF.

Diesel engine exhausts commonly contain a high level of surplus oxygen and a significant amount of thermal energy. In this study the authors have theoretically investigated a way of utilizing the thermal energy and the surplus oxygen of exhaust gases to produce gaseous fuel in a rich combustor placed in an exhaust gas recirculation (EGR) loop. In the rich combustor, a small amount of diesel fuel will be catalytically reformed on a palladium/platinum based catalyst to produce hydrogen and carbon monoxide. Since the catalytic EGR reformer is incorporated in the EGR loop, it enables the partial recovery of exhaust heat. The gaseous fuel produced in the rich combustor can be brought back into the engine in a pre-mixed condition, potentially reducing soot formation. The preliminary energy efficiency analysis has been performed by using CHEMKIN and an in-house engine simulation software SAES.

The blending of dimethyl carbonate (DMC), which contains 53% of oxygen, in diesel fuel is very effective to suppress the formation of exhaust particulates, however, the mechanism of the suppression has not been made clear. In this study, the comparison on the performance of gas oil and DMC mixture was achieved. The effect of the oxygen in DMC molecule has to suppress the formation of particulates was monitored by way of using thermal cracking analyzer under various conditions.

Exhaust Particulate emitted from diesel engines is a serious problem form the point of view of the environment and energy saving. Exhaust particulate is consist of dry soot and SOF (soluble organic fraction). To clarify the formation process of SOF in the combustion chamber of diesel engines, first lower temperature column condensed method was investigated. The gas from combustion chamber was collected to the sampling column using this method, and the cracked as well as the condensation polymerized components were analyzed with gas chromatography. The sampling condition of the low temperature column condensation method are length of condensation column 600mm, cooling temperature 198K, and dilution ratio 5. The diesel fuel injected into the combustion chamber, first cracks into lower boiling point hydrocarbons, this is followed by dehydrogenation and formation of benzene ring compounds through condensation polymerization. This is followed by the formation of PAH.

To clarify the microcrystal structure of soot particulate in the combustion chamber, we examined sampling methods which freeze the reaction of sample specimens from the combustion chamber and collected the soot particulates on microgrids. We investigated the microcrystal structure with a high resolution transmission electron microscope. The results were: the particle size distribution and the microcrystal structure of the soot particulates is little different for the cooled freezing method and room temperature sampling. The typical layer plane structure which characterizes graphite carbon is not observed in the exhaust of diesel engines, but some particulates display a somewhat similar layer plane structure. The structure of soot particulate is a turbostratic structure as the electron diffraction patterns show polycrystals. The soot particulates in the combustion chamber is similar to exhaust soot particulates.

Exhaust particulate in diesel engines is affected by fuel properties, but the reason for this is not clear. Interest in using low-grade fuels in diesel engines has made it necessary to understand the particulate formation mechanism and factors to decrease it. Particulate formation has been reported to start with thermal cracking of the fuel to lower boiling point hydrocarbons followed by condensation polymerization and production of benzene ring compounds; the formation of particulate takes place via polycyclic aromatic hydrocarbons. This report investigates the amount and configuration of particulate with a fluid reaction tube and in a nitrogen atmosphere, and analyzes polycyclic aromatic hydrocarbons (PAH) of fuels with different molecular structure and carbon number.

Exhaust particulate in diesel engines are affected by fuel properties, especially the aromatic hydrocarbon content and distillation properties, but the reasons for this are not clear. The process of particulate formation has been reported to start with a thermal cracking of the fuel to lower boiling point hydrocarbons followed by condensation polymerization and production of benzene ring compounds; the formation of particulate takes place via polycyclic aromatic hydrocarbons. The fuel properties affect diesel engine particulate because the thermal cracking and condensation polymerization of various fuels are different.

To clarify the formation processes of soot particulates in the combustion chamber, we sampled the gas during combustion in a precombustion chamber and a main chamber using an electromagnetic sampling valve, and made a gas analysis by gas chromatography, examined the soot concentration, and size distribution and dispersion of soot particulates with a transmission electron microscope. The following results were obtained: (1) In the prechamber soot particulates form at the period of rapid combustion in the initial stage rather than the end of the diffusion combustion. (2) Soot particulates which were formed in the prechamber were introduced to the main chamber, and a part of the soot particulates were burned. (3) Soot particulates formed at the initial stage of the combustion process exhibited a tendency to become smaller by oxidation. (4) If the oxygen concentration in the combustion chamber is above 5%, the combustion of soot particulates take place.