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Gasoline Homogeneous Charge Compression Ignition (HCCI) combustion has been studied widely in the past decade. However, in HCCI engines using negative valve overlap (NVO), there is still uncertainty as to whether the effect of pilot injection during NVO on the start of combustion is primarily due to heat release of the pilot fuel during NVO or whether it is due to pilot fuel reformation. This paper presents data taken on a 4-cylinder gasoline direct injection, spark ignition/HCCI engine with a dual cam system, capable of recompressing residual gas. Engine in-cylinder samples are extracted at various points during the engine cycle through a high-speed sampling system and directly analysed with a gas chromatograph and flame ionisation detector. Engine parameter sweeps are performed for different pilot injection timings and quantities at a medium load point.

Partially premixed compression ignition (PPCI) engines operating with a low temperature highly homogeneous charge have been demonstrated previously using conventional diesel fuel. The short ignition delay of conventional diesel fuel requires high fuel injection pressures to achieve adequate premixing along with high levels of EGR (exhaust gas recirculation) to achieve low NOx emissions. Low load operating regions are typified by substantial emissions of CO and HC and there exists an upper operating load limitation due to very high rates of in-cylinder gas pressure rise. In this study mixtures of gasoline and diesel fuel were investigated using a multi-cylinder light duty diesel engine. It was found that an increased proportion of gasoline fuel reduced smoke emissions at higher operating loads through an increase in charge premixing resulting from an increase in ignition delay and higher fuel volatility.

Highly homogeneous compression ignition is difficult to achieve in a direct injection diesel engine. The difficulty of achieving adequate fuel vaporization and the problems of fuel spray wall impingement are the main factors. Limitation of the maximum operating load results from high rates of pressure rise that occur in this combustion regime. The levels of HC and CO emissions are raised substantially when compared with conventional combustion and remain a significant emission factor. In this study, two methods of achieving highly homogeneous combustion in a direct injection diesel engine were investigated, Nissan MK type and early injection. The effects of fuel injection pressure, injection timing, EGR level, EGR cooler efficiency and compression ratio were examined using a conventional 4 cylinder 2.0L common rail diesel engine with 18.4:1 and 14.4:1 compression ratios.

Particulate emissions from IC engines associated with transient engine conditions are very important (similar to the legislated gaseous emissions). This is true both during real-world and test cycle driving. This paper describes an instrument for measuring the number of particles, and their spectral weighting, in the 5nm to 1000nm size range, with a time response of 200ms. This is achieved via an electrostatic classification technique, consisting of a diffusion charger followed by a multi-element, constant voltage, classifier. Conversion of the data to other metrics, such as mass, is also described. Results are presented from artificial test aerosols and from light and heavy duty diesel engines on standard test cycles.

A fast response sensor for measuring carbon dioxide concentration has been developed for laboratory research and tested on a spark ignition engine. The sensor uses the well known infra-red absorption technique with a miniaturized detection system and short capillary sampling tubes, giving a time constant of approximately 5 milliseconds; this is sufficiently fast to observe changes in CO2 levels on a cycle-by-cycle basis under normal operating conditions. The sensor is easily located in the exhaust system and operates continuously. The sensor was tested on a standard production four cylinder spark-ignition engine to observe changes in CO2 concentration in exhaust gas under steady state and transient operating conditions. The processed sensor signal was compared to a standard air-to-fuel ratio (AFR) sensor in the exhaust stream and the results are presented here. The high frequency response CO2 measurements give new insights into both engine and catalyst transient operation.

A novel Fast Response Chemiluminescence Detector and a Fast Flame Ionization detector have been used to examine the instantaneous NO and unburnt hydrocarbon concentration in the cylinder and exhaust port of a DI Diesel engine. The in-cylinder results indicate very high levels of NO in the premixed phase of combustion, followed by generally lower levels during the diffusion burning phase. Hydrocarbon signals also indicate significant detail. The in-cylinder uHC signal is consistent with the probe location being between two of the fuel sprays. Both in-cylinder and exhaust results indicate rather high cyclic variability in the NO levels at steady conditions. Variations in the timing and structure of the exhaust uHC signal during the valve open period with load may give insight into the fuel spray/air motion.

Understanding mixture formation phenomena during the first few cycles of an engine cold start is extremely important for achieving the minimum engine-out emission levels at the time when the catalytic converter is not yet operational. Of special importance is the structure of the charge (film, droplets and vapour) which enters the cylinder during this time interval as well as its concentration profile. However, direct experimental studies of the fuel behaviour in the inlet port have so far been less than fully successful due to the brevity of the process and lack of a suitable experimental technique. We present measurements of the hydrocarbon (HC) concentration in the manifold and port of a production SI engine using the Fast Response Flame Ionisation Detector (FRFID).

Recent studies in the USA have revealed that the catalysts (which are universally fitted to gasoline automobiles) are failing in service to an unacceptable extent. Although the reasons for the failures are not completely clear, it seems that misfiring, leading to highly exothermic reaction in the catalyst, may be responsible for the damage. Legislation is to be enacted later in this decade to address this problem by requiring on board diagnostic (OBD) systems which can measure misfire, as well as catalyst hydrocarbon (HC) conversion efficiency. Although some ideas have been suggested for the OBD requirements, no fully satisfactory sensor technology has yet appeared. This paper describes a novel hydrocarbon sensor based on a surface catalysis principle. The fundamental studies reported here have been made with the automobile application in mind. A catalytic chemi-ionisation model is proposed in order to enhance our understanding of this surface ionisation.

Experiments to cyclically resolve the HC concentration emitted by an I.C. engine with improved sampling techniques are described. The results suggest that the technique is easy to use, and gives results which are comparable with those obtained by other methods.

This paper describes an examination of the origin of the response of a real-time exhaust particle sensor. The sensor works by detecting the net electrical charge carried by diesel exhaust particles emitted during exhaust blow-down. The distribution of charge on these particles has been measured using an electrical mobility analysis system. The results show that the exhaust particles are highly charged and that their charge distributions are nearly symmetrical. The sensor signal results from a slight departure from this symmetry. The results suggest that most of the charge on the exhaust particles results from bipolar charging by flame ions during combustion, but that the net charge detected by the sensor results from surface interactions which some of the larger particles undergo during exhaust blowdown.

This paper describes a system for real-time smoke detection in diesel engines. Preliminary results are presented from a very simple sensor which detects the net charge level on smoke particles. There appears to be a useful correlation between the peak charge level and the Bosch smoke number. The mechanism by which the particulates is discussed, though no firm conclusions are reached.