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Technical Paper

Effect of Substituted Phenol Fuel Additives on Ignition Delay of a Toluene Reference Fuel

2022-03-29
2022-01-0516
Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine.
Technical Paper

A Qualitative Comparison of the Macroscopic Spray Characteristics of Gasoline Mixtures and their Multi-Component Surrogates Using a Rapid Compression Machine

2021-04-06
2021-01-0558
Rapid Compression Machines (RCM) offer the ability to easily change the compression ratio and the pressure/mixture composition/temperature to gather ignition delay data at various engine relevant conditions. Therefore, RCMs with optical access to the combustion chamber can provide an effective way to analyze macroscopic spray characteristics needed to understand the spray injection process and for spray model development, validation and calibration at conditions that are suitable for engines. Fuel surrogates can help control fuel parameters, develop models for spray and combustion, and perform laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of multicomponent gasoline surrogates in comparison to their gasoline counterparts, under gasoline direct injection (GDI) engine conditions.
Technical Paper

Effect of Changing Compression Ratio on Ignition Delay Times of Iso-Octane in a Rapid Compression Machine

2020-04-14
2020-01-0338
Previous studies have shown that several facility dependent factors can influence ignition delay times measured in a rapid compression machine. Compression ratio variation represents one such aspect of many facility-to facility differences in RCMs, and can have a major impact on measured ignition delay times due to changes in surface-area-to-volume ratio, initial conditions and compression duration even when the same compressed conditions are maintained. In this study, iso-octane, which exhibits two stage ignition delay and has a pronounced negative temperature coefficient (NTC) region, is used to investigate the effects of changing compression ratio on ignition delay. Resulting trends are also compared to previous results obtained with ethanol, which has very different combustion properties. Experiments were carried out for rich mixtures (ϕ = 1.3) of iso-octane and air over a compressed temperature range of 675-900 K at 20 bar compressed pressure.
Technical Paper

An Experimental Study on the Factors Affecting Ethanol Ignition Delay Times in a Rapid Compression Machine

2019-04-02
2019-01-0576
Ignition delay, using a rapid compression machine (RCM), is defined as the time period between the end of compression and the maximum rate of pressure rise due to combustion, at a given compressed condition of temperature and pressure. The same compressed conditions can be reached by a variety of combinations of compression ratio, initial temperature, initial pressure, diluent gas composition, etc. It has been assumed that the value of ignition delay, for a given fuel and at a given set of compressed conditions, would be the same, irrespective of the variety of the above-mentioned combinations that were used to achieve the compressed conditions. In this study, a range of initial conditions and compression ratios are studied to determine their effect on ignition delay time and to show how ignition delay time can differ even at the same compressed conditions.
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